致密油藏注天然气提高采收率研究现状

随着我国石油需求量不断增加,致密油藏的开发也愈发重要。如何高效开发致密油藏是一项重点难点,其中致密油藏注天然气提高采收率是一个极具潜力的研究方向。因此,本文着重介绍以天然气作为能量补充介质在国内外的研究现状和应用现状,并且从两相特征等方面总结了理论研究中的一些机理,对致密油藏注天然气提高采收率的发展前景进行了一定的展望。     

The use of bio-diesel based additive as rheology improver and pour point depressant of Nigerian waxy crude

The chemical method has proved to be the most effective mitigating method of wax deposition in petroleum system as it deals with the root cause of wax formation. Most of the commercial chemicals in the industry are very expensive and toxic. This paper aims the use of biodiesel based additives for improving the rheological behavior and pour points of waxy crude from Nigeria field. The biodiesels derived additives gave better performance than the commercial chemical and the seed oils as greatly improvement in rheology and pour point values of the waxy crude were observed     

Amine-containing olefin copolymer with CO2-switchable oil absorption and desorption

Global decrease in crude oil resources and frequent crude oil leaks cause the energy crisis and ecological pollution. The absorption and release of leaked crude oil through absorption materials are a necessary process for environmental protection and recycling. In this article, a CO₂-responsive olefin copolymer was obtained by copolymerization of styrene and an amine-containing olefin monomer. The structure of resultant copolymer was characterized by FTIR; thermal properties and CO₂-responsive morphology changes were determined by DSC/TGA and SEM, respectively. Copolymers had certain absorption capacity for toluene with absorption rate up to 180.0%. The absorbed toluene could be released upon CO₂ stimulation with desorption rate up to 84.6%. The CO₂-responsive copolymer could be regenerated through a simple heating process and showed stable absorption–desorption performance even after being recycled for 4 times. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47439.     

Influence of Bridgman solidification on microstructures and magnetic behaviors of a non-equiatomic FeCoNiAlSi high-entropy alloy

The non-equiatomic FeCoNiAlSi alloy is prepared by the Bridgman solidification (BS) technique at different withdrawal velocities (V = 30, 100, and 200 μm/s). Various characterization techniques have been used to study the microstructure and crystal orientation. The morphological evolutions accompanying the crystal growth of the alloy prepared at different withdrawal velocities are nearly the same, from equiaxed grains to columnar crystals. The transition of coercivity is closely related to the local microstructure, while the saturation magnetization changes little at different sites. The coercivity can be significantly reduced from the equiaxed grain area to the columnar crystal area when the applied magnetic field direction is parallel to the crystal growth direction, no matter what is the withdrawal velocity. In addition, the alloy possesses magnetic anisotropy when the applied magnetic field is in different directions.     

Impact sensitivities of energetic materials: Exploring the limitations of a model based only on structural formulas

Using a comprehensive set of drop weight impact test data (h₅₀) newly compiled from literature for 308 materials, a recent approach to predict impact sensitivities of nitro compounds is generalized to most explosive substances of interest. Compared to previous ones, this procedure is more thoroughly validated and exhibits a good predictive value. Furthermore, it yields new insight into the physical mechanisms involved, explaining for instance the unexpected desensitization of some oxygen-deficient triazoles upon nitration.     

Transparent niobate glass-ceramics for optical limiting

The construction of nonlinear optical materials featuring asymmetric transmission of light is of great technological importance for various applications, including optical switching and optical power limiting. A significant challenge is the scalable fabrication of material candidates with good photochemical stability, high optical transmittance, and excellent optical limiting performance. Here, we present a nanocrystallization avenue for constructing hybrid optical limiting materials that exhibit ultrafast and robust optical limiting performance. The experimental results show that the controllable relaxation of a niobate glass may lead to the clustering of Nb-O units and contracting of the bandgap. It results in the notable improvement in nonlinear optical properties, including the enhanced saturation irradiance (380 GW/cm²), doubly increased nonlinear coefficient, and decreased limiting threshold (200 GW/cm²). Our results suggest a promising material that exhibits promising applications for protecting eyes and sensitive components from laser-induced damage.     

注采比对“二三结合”开发模式渗流特征的影响

大庆油田的开发逐渐进入高含水阶段,厚油层动用程度低,"二三结合"开发模式是有效的提高厚油层动用程度,改善水驱开发效果,提高油田采收率的有效手段。在"二三结合"开发模式注聚阶段中注采比对井间压力、含水饱和度等变化有重要影响。为了探究注采比对开发层位的井间压力及饱和度的影响,利用油藏数值模拟方法,模拟了相同的开发模式不同注采比的生产情况,绘制了不同注采比情况下,不同层位的井间压力及含水饱和度变化情况,为维持地层压力平衡,保持油田稳定生产提供有力的依据。     

Research on Chromium Retrieval of Black Soil with Hyperspectral Imagery in Northeast of China#br#

According to the definition of spectral integral，a new spectral characteristic parameter，with the name Reversed Spectral Absorption Integral(RSAI)，is proposed and used to retrieve the chromium content based on the Partial Least Squares Regression(PLSR) model.The contrastive study with other traditional spectral characteristic parameters，including differential transformation，inverse transformation，absorption area，etc.indicates that(1) the first derivation of square root transformed model can predict the chromium content quantitatively in terms of spectral transformations.(2) the stability of the absorption area model is slightly poor，and the chromium content of samples can only be estimated roughly.(3) However，as to the inversed spectral absorption integral model，the adjustment determination coefficient(Ad-R²) of the modeling and verification is 0.73 and 0.77，while the Root Mean Squared Error(RMSE) is 2.63 mg/kg and 2.36 mg/kg respectively with Relative Percent Deviation(RPD) being 3.21，which shows that the RSAI model has excellent prediction ability.So，the inversed spectral absorption integral new model can improve the accuracy and stability used to retrieve the chromium content，which provides a new idea for monitoring the chromium contamination in soil.