重介选煤厂自动化控制系统

介绍了重介选煤厂实现全自动控制的系统原理及所能实现的各项功能。     

Electro-copolymerisation of indene and styrene

Electroinitiated cationic copolymerisation of indene and styrene was investigated by constant potential electrolysis. Effects of copolymerisation potential and temperature on the copolymer composition and the reactivity ratios are discussed. The reactivity ratios of the monomers were calculated according to the integrated Lewis-Mayo equation.     

大掺量粉煤灰轻质墙体砌块的研制

大掺量粉煤灰轻质墙体砌块是以粉煤灰为主要原材料 ,普通硅酸盐水泥为胶凝材料 ,配以各种外加剂 ,经发泡剂发泡 ,在常温、常压条件下养护而成。具有重量轻、导热系数小、抗冻性高以及粉煤灰掺量大、成型方便、工艺简单、投资小、见效快等优点。     

影响掺矿渣的钢纤维砼强度的主要因素

研究结果表明 :水胶比、胶凝材料用量、钢纤维掺量、矿渣代水泥量对钢纤维砼强度影响显著。当矿渣取代水泥 10 %时 ,钢纤维砼强度最高。经试验选择出一个具有良好和易性和较高强度 (118MPa)的钢纤维砼配合比 ,为掺磨细矿渣的中含量超短异形钢纤维砼的设计和施工提供了试验依据     

Complex formation of montmorillonite clay with polymers. Part 2: The use of montmorillonite clay–vinyl monomer complex as a comonomer in the copolymerization reaction of styrene–acrylonitrile monomers

The bulk copolymerization of styrene–acrylonitrile monomers using styrene‐N⁺–montmorillonite complex as a comonomer in the polymerization was studied. The X‐ray diffraction (XRD) analysis showed that part of the styrene‐N⁺–montmorillonite complex remained non‐dispersed (immiscible) and the copolymer was excluded from the interlayer of the immiscible part of the clay. The successive chemical extraction process revealed that a reasonable amount of the styrene–acrylonitrile copolymer was directly attached to the styrene‐N⁺–montmorillonite complex and enveloped the clay. Highly exfoliated clay lamella and nanospheres (3–5 nm) were observed by transmission electron microscopy (TEM). The montmorillonite clay assume two different morphologies, immiscible and exfoliated, on the basis of the XRD and TEM data. A simple method of calculation of the ratio of the exfoliated/immiscible amounts of the clay indicated that the amount of the styrene‐N⁺–montmorillonite complex exfoliated into separate lamella was 40 % (w/w) of the amount of the clay samples containing 2 % of the (styrene‐N⁺–montmorillonite complex) clay. This amount of exfoliated clay decreases with the increase of the concentration of the clay. The presence of the styrene‐N⁺–montmorillonite clay in the copolymerization reaction had a minor effect on both the copolymer composition and the molecular weight. Modification of the clay with the derivatized styrene monomer can achieve a nanocomposite using a percentage no more than 4 % (w/w) of complex in the copolymer. Copyright © 2004 Society of Chemical Industry     

Effects of Surface Concentration on Drying Behavior of Carbohydrate Solutions

As the surface properties of the drying materials are very important not only for the drying rate but also for the quality change during drying, the effects of surface concentration on the drying behavior of liquid foods (sugar solutions) were investigated by isothermal drying experiments and by numerical calculation experiments. The isothermal drying experiments with gelled sugar solution systems (sucrose and maltodextrin) were carried out at various relative humidity (RH) values (RH = 0 to 84%). Separate experiments were carried out for determination of the desorption isotherms.

The isothermal drying curves of sugar solutions at RH = 0 to 51% were very similar. Numerical simulations also showed that the drying curves of these sugars at the surface concentration = 0 and 0.1 are almost the same, although the concentration distributions are different.

When a small amount of gelatin was added to sugar solutions, the drying rate decreased remarkably as the gelatin might form a thin film (skin) near the surface, and consequently the retention of ethanol increased.     

过氧化甲乙酮合成研究

论述了过氧化甲乙酮的合成方法，用阳离子交换树脂催化剂代替传统的无机酸催化剂。考察了离子交换树脂用量、反应温度对反应产率、活性氧含量的影响及溶剂对产品稳定性的影响。     

Peracetic acid pretreatment of sugarcane bagasse for enzymatic hydrolysis: a continued work

Previous work has shown that the enzymatic hydrolysis of sugarcane bagasse could be greatly enhanced by peracetic acid (PAA) pretreatment. There are several factors affecting the enzymatic digestibility of the biomass, including lignin and hemicelluloses content, cellulose crystallinity, acetyl group content, accessible surface area and so on. The objective of this work is to analyze the mechanism of the enhancement of enzymatic digestibility caused by PAA pretreatment. Delignification resulted in an increase of the surface area and reduction of the irreversible absorption of cellulase, which helped to increase the enzymatic digestibility. The Fourier transform infrared (FTIR) spectrum showed that the absorption peaks of aromatic skeletal vibrations were weakened or disappeared after PAA pretreatment. However, the infrared crystallization index (N.O'KI) was increased. X‐ray diffraction (XRD) analysis indicated that the crystallinity of PAA‐treated samples was increased owing to the partial removal of amorphous lignin and hemicelluloses and probable physical change of cellulose. The effect of acetyl group content on enzymatic digestibility is negligible compared with the degree of delignification and crystallinity. The results indicate that enhancement of enzymatic digestibility of sugarcane bagasse by PAA pretreatment is achieved mainly by delignification and an increase in the surface area and exposure of cellulose fibers. Copyright © 2008 Society of Chemical Industry     

光度法测定药品和食物中的微量VC

采用一种简单、快速的方法测定VC,该方法基于在室温下,抗坏血酸能快速地将Fe3 还原成Fe2 ,Fe2 与2,2’-联吡啶反应生成红色配合物,配合物的最大吸收峰位于520 nm波长处,VC的质量浓度在0.088~7.0 mg/L范围内符合比尔定律,该方法用于食品和药片中VC含量的测定,结果的相对标准偏差小于1.5%,回收率在96.3%~105.0%之间.     

The influence of raw material characteristics on the industrial pelletizing process and pellet quality

Industrial pelletizing of sawdust was carried out as a designed experiment in the factors: sawdust moisture content, fractions of fresh pine, stored pine and spruce. The process parameters and response variables were energy consumption, pellet flow rate, pellet bulk density, durability and moisture content. The final data consisted of twelve industrial scale runs. Because of the many response variables, data evaluation was by principal component analysis of a 12 × 9 data matrix. The two principal component model showed a clustering of samples, with a good reproducibility of the center points. It also showed a positive correlation of energy consumption, bulk density and durability all negatively correlated to flow rate and moisture content. The stored pine was more related to high durability and bulk density. The role of the spruce fraction was unclear. The design matrix, augmented with the process parameters was a 12 × 6 matrix. Partial least squares regression showed excellent results for pellet moisture content and bulk density. The model for durability was promising. A 12 × 21 data matrix of fatty- and resin acid concentrations measured by GC–MS showed the differences between fresh and stored pine very clearly. The influence of the spruce fraction was less clear. However, the influence of the fatty- and resin acids on the pelletizing process could not be confirmed, indicating that other differences between fresh and stored pine sawdust have to be investigated. This work shows that it is possible to design the pelletizing process for moderate energy consumption and high pellet quality.