Thermal and thermoelastic properties of fast extrusion furnace (FEF) carbon black loaded SBR vulcanizates

The effect of FEF carbon black as filler on the thermal capacity c, diffusivity a, and thermal conductivity λ, of styrene butadiene rubber (SBR) composites in the temperature range 300–420 K was studied. The filler strongly increases the thermal diffusivity, whilst strongly decreasing the thermal capacity and the thermal conductivity (except at high FEF content ≥80 phr). The influence of the filler on the thermoelastic behaviour of the same composites was also investigated. It was found that the thermoelastic temperature change (ΔT) increased with carbon black concentration as well as the entropy change per unit extension.     

浅谈胶条接头与模具设计

简要地介绍了橡胶条常见接头工艺方法、应用特点及模具结构与设计方法。     

Monomer recycling for vulcanized silicone rubbers in the form of cyclosiloxane monomers. Role of acid buffers

The KOH-catalyzed depolymerization of vulcanized silicone rubbers to reproduce cyclosiloxane monomers was studied. First, the depolymerization was carried out in toluene with varying amounts of KOH to find that the yield of monomers first increased and then decreased with the increment of KOH, the highest yield was 65% at the molar ratio KOH/(Si–O) UNITS=0.08. At the molar ratio 0.13 in the absence of solvent, the monomers yield was 46%. However, when an acid buffer such as KH₂PO₄ and KCOOC₆H₄COOH was added after the KOH-catalyzed depolymerization was over, the product yield was increased remarkably to more than 80%.     

用瓦勃氏呼吸仪测定橡胶废水可生化性

本文介绍了利用瓦勃氏呼吸仪进行橡胶废水测定的过程和方法,并用配制的橡胶废水进行了二组实验,认为橡胶废水是易生化的,并对氧化率计算方法提出了修正,使之更接近于实际情况。     

MCS接枝共聚物的结构和形态

将甲基丙烯酸甲酯（ＭＭＡ）、苯乙烯（Ｓ）在氯化聚乙烯（ＣＰＥ）存在下进行悬浮接枝共聚，获得ＭＣＳ树脂。本文着重考察了ＭＣＳ树脂的化学结构及胶粒形态。结果表明，确实发生了接枝共聚。ＣＰＥ用量、ＲＳＨ含量、引发剂浓度、反应温度、溶胀时间及聚合转化率对ＭＣＳ树脂的接枝率、接枝效率均有影响。ＭＣＳ树脂是接枝共聚物、ＭＭＡ／Ｓ共聚物与ＭＭＡ均聚物的混合物，橡胶相ＣＰＥ在ＭＣＳ树脂中的分散情况为“海岛结构”，     

动态交联热塑性弹性体增韧聚丙烯合金

用动态交联方法制备聚烯烃热塑性弹性体（ＴＰＯ）增韧聚丙烯，制备了具有低温冲击性能良好、综合力学性能比较均衡的聚丙烯合金。同时，研究了ＴＰＯ组成、工艺及基体组成与ＴＰＯ增韧聚丙烯共混物力学性能的关系。并通过差热扫描量热计和扫描电镜考察了共混物的形态结构。     

高速列车浮式地板振动响应有限元分析

针对采用试验方法开发高速列车浮式地板耗时耗力,且试验规模小,不能反映整车的振动效果的问题,基于有限元法进行高速列车振动响应分析.对三明治夹芯理论、蜂窝板理论和等效板理论进行比较,确定采用等效板理论数值模拟某浮式地板中的蜂窝板;利用橡胶材料的超弹性理论拟合橡胶材料参数;建立完整模型模拟实际工况下浮式地板的振动响应,得到浮式地板的隔振效果.结果表明此浮式地板的隔振效果约为90%,满足设计要求.     

橡胶混凝土弯曲疲劳性能研究

为研究橡胶混凝土的弯曲疲劳性能,将粒径为0.54 mm的橡胶颗粒以不同掺量掺入混凝土中,制成橡胶混凝土试件进行轴压试验与轴拉试验,测其应力-应变曲线,计算出弹性模量和泊松比。进行四点弯曲静载试验及ABAQUS数值模拟,得到极限荷载、峰值挠度和荷载-挠度曲线,试验结果与数值模拟结果较接近,验证了数值模型的可靠性。使用疲劳软件Fe-safe分析等幅及变幅加载下橡胶混凝土弯曲疲劳寿命,结果表明:无论是普通混凝土还是橡胶混凝土,在等幅循环荷载下,应力水平越高,弯曲疲劳寿命越低;各掺量下橡胶混凝土的弯曲疲劳寿命都比普通混凝土的大,且橡胶掺量越多弯曲疲劳寿命越大;在变幅荷载作用下,随着橡胶掺量的增大,混凝土的弯曲疲劳寿命也越大;随着变幅等级增多,各掺量下橡胶混凝土的弯曲疲劳寿命均降低,且变幅等级越多,弯曲疲劳寿命越低。     

橡胶机械的现代控制技术及发展

近年来,通讯技术、大数据应用技术和网络技术都在飞速发展,已经从根本上改变了传统制造业企业的生产方式与发展模式,同时也对整个橡胶机械行业的发展提出了新的要求,本文将对橡胶机械的现代控制技术及发展从不同方向分别进行介绍。