钻井泥浆抑制剂JFT的实验研究

针对钻井过程中泥页岩的水化膨胀导致井壁不稳定和泥浆性能恶化这一严重问题 ,通过室内试验研制了一种阳离子型聚合物抑制剂———JFT ,并进行了性能评价。结果表明 ,该抑制剂具有好的水溶性、时间稳定性和热稳定性 ,其适应温度范围广 (在 30～ 95℃下不生成絮状沉淀 ) ,有效浓度为 1 %的JFT比 5 %KCl的抑制性好。     

Insolubilization of sodium chondroitin sulfate by forming a semi‐interpenetrating polymer network with acrylic acid: A potential carrier for colon‐specific drug delivery

To reduce the highly hydrophilic property of chondroitin sulfate (ChS), a semi‐interpenetrating polymer network (semi‐IPN) of chondroitin sulfate/polyacrylic acid (PAA) was prepared as a drug carrier by crosslinking acrylic acid with diethyleneglycol diacrylate. The swelling properties of the semi‐IPNs with different concentrations of crosslinking agent were correlated. The moisture sorption profiles were evaluated using differential thermal analysis. Ketoprofen was used as a drug probe to evaluate the performance of the drug released from the semi‐IPN matrices. The prepared semi‐IPNs demonstrated significant swelling reduction properties with both gastric and intestinal fluids compared with those of both the pure ChS and the ChSAA blend without the crosslinking agent. The amount of accumulated drug released from the semi‐IPNs was less than 30 wt % at pH 1.2 and up to 80 wt % at pH 7.4. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 114–122, 2002     

中空聚合物微球的制备Ⅲ.种子扩径的影响

以预乳化液连续滴加进料的三段乳液聚合结合碱酸溶胀处理制备了单分散性良好、大粒径的聚(甲基丙烯酸-甲基丙烯酸甲酯-丙烯酸丁酯)/聚(甲基丙烯酸-苯乙烯)中空聚合物微球。实验发现,在二段乳液聚合种子扩径中,种子乳胶粒数目、乳化剂用量、预乳化液滴加时间等对避免新乳胶粒的生成、扩大种子乳胶粒的粒径有影响,并找到了各自的较优值;扩径单体中的丙烯酸丁酯含量显著影响扩径乳胶粒聚合物的玻璃化温度,进而决定碱酸处理温度。     

Diffusion of two associated solvents in various compositions through a swelling polymer material,EVAc

The particular sorption by a swelling polymer with the transfer of hydrocarbons was studied in order to evaluate some barrier properties of this material. The transfer of two types of solvents through two varieties of ethylene vinyl acetate was investigated: absorption of pure toluene and pure n‐hexane and absorption of a toluene/hexane mixture in various compositions. A comparison between the two processes showed that these transfers were very different and depended on two factors: vinyl acetate content and composition of the mixture. The kinetics of absorption were calculated for various compositions. The profiles of concentration as well as the kinetics of swelling were evaluated using a numerical model deduced from the general theory of radial diffusion of a substance with change in dimensions. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2099–2106, 2007     

N-异丙基丙烯酰胺凝胶在NaCl水溶液中溶胀行为的预测研究

In this paper, a model is presented to correlate and predict the swelling behavior of hydrogels in aqueous solutions of electrolytes. The model is a combination of VERS-model, “phantom network“ theory and “free-volume“ contribution. The VERS-model is used to calculate Gibbs excess energy; “phantom network“ theory to describe the elastic properties of polymer network, and “free-volume“ contribution to account for additional difference in the size of the species. To test the model, a series of N-isopropylacrylamide based hydrogels are synthesized by free radical polymerization in oxygen-free, deionized water at 25~C under nitrogen atmosphere. Then, the degree of swelling of all investigated gels as well as the partition of the solute between the gel phase and the surrounding coexisting liquid phase are measured in aqueous solution of sodium chloride. The model test demonstrates that the swelling behavior correlated and predicted by the model agrees with the experimental data within the experimental uncertainty. The phase transition appeared in the experiment, and the influences of the total mass fraction of polymerizable materials ξgel as well as the mole fraction of the crosslinking agent YCR on the swelling behavior of IPAAm-gels can also be predicted correctly. All these show the potential of such model for correlation and prediction of the swelling behavior of hydrogels in aqueous solutions of electrolytes.     

Relation of swelling and Tg depression to the apparent free volume of a particle‐filled,epoxy‐based adhesive

The effect of hygrothermal aging on a particle‐filled, epoxy‐based adhesive was studied using a gravimetric sorption technique. This study has explored moisture sorption characteristics as well as the associated behaviors of swelling and the depression of the glass transition temperature (T_g). We observed that the diffusion of water in this adhesive has a non‐Fickian behavior, and the depression of T_g proceeds to a definite value that is independent of the final equilibrium water content of the system. Our observations suggest that water diffuses into the polymer in a dual‐sorption mode, in which water resides in two populations. In one population, water is considered to occupy apparent free volume of the adhesive, and the second population water infiltrates polymer structure and forms hydrogen‐bonded clusters. Our results show that hygrothermal aging temperature and swelling do not alter the apparent free volume of this adhesive. We conclude that the constant value of T_g depression at saturation implies that only water in the apparent free volume is responsible for the T_g depression, whereas the swelling proceeds through the formation of hydrogen bonds in the adhesive. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1436–1444, 2003     

Fast online acquisition and analysis for parison swell and sag in blow molding

It is critical to quantitatively and reliably characterize the effects of swell and sag phenomena on the final parison dimensions in extrusion blow molding. To achieve this goal, an online image acquisition and analysis technique was developed. The successive images of parison were automatically taken using the online acquisition apparatus. These images were then analyzed by the combined use of the conventional digital image processing method and the new one developed by the authors. So the development of parison diameter and thickness swells with the extrusion time could be determined online. On the basis of the online obtained actual swell values, the pure swell and sag components were quantitatively determined. The developed technique was tested through a series of experiments using several resins under different processing parameters and die types. Shown in the present article were the results for a converging die under three different die gaps and a high‐density polyethylene. Some new phenomena were observed using the proposed technique. The results showed that the technique yields fast and accurate determination of the evolution of diameter, thickness, and length of parison during its extrusion. The technique can be employed as a part of the closed loop control for blow molded part thickness. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2399–2406, 2006     

Experimental studies on extrudate swell behavior of PS and LLDPE melts in single and dual capillary dies

Extrudate swell behavior of polystyrene (PS) and linear low‐density polyethylene (LLDPE) melts was investigated using a constant shear rate capillary rheometer. Two capillary dies with different design configurations were used, one being a single flow channel and the other being a dual flow channel. A number of extrudate swell related parameters were examined, and used to explain the discrepancies in the extrudate swell results obtained from the single and dual flow channel dies, the parameters including output rate and output rate ratio, power law index, wall shear rate, wall shear stress, melt residence time, pressure drop induced temperature rise, flow channel position relative to the barrel centerline, and the flow patterns. It was found in this work that the power law index (n value) was the main parameter to determine the output rate ratio and the extrudate swell between the large and small holes for the dual flow channel die: the greater the n value the lower the output rate ratio and thus decreased extrudate swell ratio. The differences in the extrudate swell ratio and flow properties for PS and LLDPE melts resulted from the output rate ratio and the molecular chain structure, respectively. The extrudate swell was observed to increase with wall shear rate. The discrepancies in the extrudate swell results from single and dual dies for a given shear rate were caused by differences in the flow patterns in the barrel and die, and the change in the melt velocities flowing from the barrel and in the die to the die exit. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1713–1722, 2003     

Determination of swelling behavior and morphological properties of poly(acrylamide‐co‐itaconic acid) and poly(acrylic acid‐co‐itaconic acid) copolymeric hydrogels

Poly(acrylamide‐co‐itaconic acid) (PAAmIA) and poly(acrylic acid‐co‐itaconic acid) (PAAIA) copolymeric hydrogels were prepared with different compositions via free‐radical polymerization. Ethylene glycol dimethacrylate (EGDMA) was used as an original crosslinker for these monomers. Gelation percentages of the monomers were studied in detail and it was found that addition of IA into the monomer mixture decreased the gelation percentage. The variation in swelling values (%) with time, temperature, and pH was determined for all hydrogels. PAA, which is the most swollen hydrogel, has the swelling percentage value of 2000% at pH = 7.4, 37°C. Swelling behaviors were explained with detailed SEM micrographs, which show the morphologic differences between dry and swollen hydrogels. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5994–5999, 2006     

Preparation and swelling behavior of biodegradable hydrogels based on α,β‐poly(N‐2‐hydroxyethyl‐DL‐aspartamide)

Biodegradable polymers and the hydrogels have been increasingly applied in a variety of biomedical fields and pharmaceutics. α,β‐Poly(N‐2‐hydroxyethyl‐DL ‐aspartamide), PHEA, one of poly(amino acid)s with hydroxyethyl pendants, are known to be biodegradable and biocompatible, and has been studied as an useful biomaterial, especially for drug delivery, via appropriate structural modification. In this work, hydrogels based on PHEA were prepared by two‐step reaction, that is, the crosslinking of polysuccinimide, the precursor polymer, with oligomeric PEG or PEI‐diamines and the following nucleophilic ring‐opening reaction by ethanolamine. Soft hydrogels possessing varying degrees of gel strength could be prepared easily, depending on the amount of different crosslinking reagents. The swelling degrees, which were in the range of 10–40 g–water/dry gel, increased somewhat at higher temperature, and also at alkaline pH of aqueous solution. A typical hydrogel remained almost unchanged for 1 week, at 37°C in phosphate buffer of pH 7.4, and then seemed to degrade slowly as time. A porous scaffold could be fabricated by the freeze drying of water‐swollen gel. The PHEA‐based hydrogels have potential for useful biomaterial applications including current drug delivery system. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3741–3746, 2003