公制轻型载重子午线轮胎带束层钢丝帘线的发展状况

介绍了公制轻型载重子午线轮胎带束层钢丝帘线存在的问题、发展趋势以及 2 +2× 0 30HT开放式结构高强度钢丝帘线的性能和应用。公制轻型载重子午线轮胎钢丝帘线由复杂排列紧密型结构向简单开放式结构 ,由单丝直径较小、根数较多向单丝直径较大、根数较少 ,由普通强度向超超高强度方向发展。与 1× 5× 0 2 5和 3+9×0 2 2传统紧密型结构钢丝帘线相比 ,2 +2× 0 30HT开放式结构高强度钢丝帘线的物理性能、挤出和压延工艺性能、轮胎成品性能好 ,价格低 ,适用于公制轻型载重子午线轮胎带束层。     

Mechanical and morphological properties of carbon fiber reinforced–modified epoxy composites

Epoxy, prepared through aminomethyl 3,5,5‐trimethylcyclohexylamine hardening of diglycidylether of bisphenol‐A (DGEBA) prepolymer, toughened with polycarbonate (PC) in different proportions, and reinforced with carbon fiber, was investigated by differential scanning calorimetry, tensile and interlaminar shear strength testing, and scanning electron microscopy (SEM). A single glass transition temperature was found in all compositions of the epoxy/PC blend system. The tensile properties of the blend were found to be better than that of the pure epoxy matrix. They increased with PC content up to 10%, beyond which they decreased. The influence of carbon fiber orientation on the mechanical properties of the composites was studied, where the fiber content was kept constant at 68 wt %. Composites with 45° fiber orientation were found to have very weak mechanical properties, and the mechanical properties of the blend matrix composites were found to be better than those of the pure epoxy matrix composites. The fracture and surface morphologies of the composite samples were characterized by SEM. Good bonding was observed between the fiber and matrix for the blend matrix composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3529–3536, 2006     

纳米环氧树脂复合涂层耐冲蚀磨损性能研究

研究了固化剂低分子聚酰胺、有机蒙脱土和纳米Al2O3的用量对环氧树脂胶粘涂层拉伸剪切强度和耐冲蚀磨损性能的影响。试验表明,有机蒙脱土和纳米Al2O3能有效提高涂层拉伸剪切强度和耐冲蚀磨损性能,在最佳配方下,涂层的耐冲蚀磨损性能是Q235钢的10.83倍。     

胶层厚度对拉伸试样应力分布影响的数值分析

运用弹塑性有限元法研究了胶层厚度对承受拉伸载荷的对接接头胶层内应力分布的影响．三维有限元法数值分析的结果表明，随胶层厚度减小，胶层中正应力SZ与剪应力SYZ的分布趋于均匀；而对正应力SY而言，胶层厚度为0．15mm时，其边缘峰值应力最低。     

铝系阻燃剂阻燃PP的力学性能研究

将用偶联剂处理的碱式碳酸铝镁加入到聚丙烯中，通过对体系阻燃性、力学性能等研究得出：碱式碳酸铝镁能够对聚丙烯起到良好的阻燃效果，碱式碳酸铝镁的加入提高了聚丙烯的冲击强度，当碱式碳酸铝镁质量分数为23％时，体系的冲击强度最高。研究了偶联荆的用量对体系力学性能的影响，结果表明，随偶联荆用量的增加，体系的拉伸强度降低，冲击强度先升高后降低，当偶联荆质量分数为1．0％时，体系的冲击强度最高。     

苎麻落麻纤维的PVC包覆处理研究

本文研究了PVC包覆处理对苎麻落麻纤维的吸水性、纤维表面状态、纤维单丝强度等的影响.与未处理的落麻纤维增强PP复合材料比较,包覆处理后落麻纤维增强PP复合材料的拉伸和弯曲强度较处理前提高了20%.     

Effects of apitong (Dipterocarpus spp.) extractives on bond strength development and curing rate of adhesives

Emulsion polymer isocyanate ( ), polyvinyl acetate ( ) and resorcinol-formaldehyde ( ) adhesives were used to produce single lap shear specimens using resinous and non-resinous apitong (Dipterocarpus spp.) timbers. Tests showed that joints made with highly resinous apitong were about 40% weaker than similar joints made with non-resinous apitong. The resinous apitong was treated with different solvents to yield five different extractives which were characterized by infra-red analysis. Apitong extractives were then added to and adhesives and joints made with buna (Fagus crenata), a timber known to be low in extractives and easy to bond. Joints prepared using extractive-containing adhesives were generally weaker than those made with the unmodified adhesives. RF adhesives containing extractives cured more slowly than unmodified . It is thought that the acidic nature of the extractives changes the pH of the system sufficiently to affect the curing mechanism     

Surface modification and physical properties of various UHMWPE‐fiber‐reinforced modified epoxy composites

Two surface modification methods—plasma surface treatment and chemical agent treatment—were used to investigate their effects on the surface properties of ultrahigh‐molecular‐weight polyethylene (UHMWPE) fibers. In the analyses, performed using electron spectroscopy for chemical analysis, changes in weight, and scanning electron microscope observations, demonstrated that the two fiber‐surface‐modified composites formed between UHMWPE fiber and epoxy matrix exhibited improved interfacial adhesion and slight improvements in tensile strengths, but notable decreases in elongation, relative to those properties of the composites reinforced with the untreated UHMWPE fibers. In addition, three kinds of epoxy resins—neat DGEBA, polyurethane‐crosslinked DGEBA, and BHHBP‐DGEBA—were used as resin matrices to examine the tensile and elongation properties of their UHMWPE fiber‐reinforced composites. From stress/strain measurements and scanning electron microscope observations, the resin matrix improved the tensile strength apparently, but did not affect the elongation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 655–665, 2007     

Studies on mechanical,thermal, and morphology of diglycidylether‐terminated polydimethylsiloxane‐modified epoxy–bismaleimide matrices

An epoxy matrix system modified by diglycidylether‐terminated polydimethylsiloxane (DGETPDMS) and bismaleimide (BMI) was developed. Epoxy systems modified with 4, 8, and 12% (by wt) of DGETPDMS were made using epoxy resin and DGETPDMS, with diaminodiphenylmethane as the curing agent. The DGETPDMS‐toughened epoxy systems were further modified with 4, 8, and 12% (by wt) of BMI, namely (N,N′‐bismaleimido‐4,4′‐diphenylmethane). DGETPDMS/BMI/epoxy matrices were characterized using differential scanning calorimetry, thermogravimetric analysis, and heat deflection temperature analysis. The matrices, in the form of castings, were characterized for their mechanical properties, viz. tensile strength, flexural strength, and impact test, as per ASTM methods. Mechanical studies indicate that the introduction of DGETPDMS into epoxy resin improves the impact strength, with reduction in tensile strength, flexural strength, and glass transition temperature, whereas the incorporation of BMI into epoxy resin enhances the mechanical and thermal properties according to its percentage content. However, the introduction of both DGETPDMS and BMI enhances the values of thermomechanical properties according to their percentage content. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 668–674, 2006     

Tensile deformation mechanisms of polypropylene/elastomer blends reinforced with short glass fiber

Polypropylene hybrid composites reinforced with short glass fiber (SGF) and toughened with styrene–ethylene butylenes–styrene (SEBS) elastomer were prepared using extrusion and injection‐molding techniques. Moreover, hybrids compatibilized with SEBS‐grafted maleic anhydride (SEBS‐g‐MA) and hybrid compatibilized with PP grafted with maleic anhydride (PP‐g‐MA) were also fabricated. The matrix of the latter hybrid was designated as mPP and consisted of 95% PP and 5% PP‐g‐MA. Tensile dilatometry was carried out to characterize the fracture mechanisms of hybrid composites. Dilatometric responses showed that the elastic deformation was the dominant deformation mechanism for the SGF/SEBS/PP and SGF/SEBS‐g‐MA/PP hybrids. However, cavitation deformation prevailed over shearing deformation for both hybrids at the higher strain regime. The cavitation strain resulted from the debonding of glass fibers and from the crazing of the matrix in the SGF/SEBS/PP hybrid. In contrast, the cavitation was caused by the debonding of SEBS particles from the matrix of the SGF/SEBS‐g‐MA/PP hybrid. The use of PP‐g‐MA resulting in elastic deformation was the main mode of deformation in the low‐strain region for the SGF/SEBS/mPP and SEBS/SEBS‐g‐MA/mPP hybrids; thereafter, shearing appeared to dominate at the higher strain regime. This was attributed to the MA functional group improving the bonding between the SGF and PP. The correlation between fracture morphology and dilatometric responses also is presented in the article. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 441–451, 2003