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《Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment》2013,30(2):173-179
Different techniques for the determination of total tin in beverages and canned foods by atomic spectrometry were compared. The performance characteristics of inductively coupled plasma-mass spectrometry (ICP-MS), hydride generation-inductively coupled plasma-atomic emission spectrometry (HG-ICP-AES), electrothermal atomisation-atomic absorption spectrometry (ETA-AAS) and inductively coupled plasma-atomic emission spectrometry (ICP-AES) were determined in terms of linearity, precision, recovery, limit of detection, decision limit (CCα) and detection capability (CCβ) (Decision 2002/657/EC). Calibration ranges were covered from ng?l?1 to mg?l?1 level. Limits of detection that ranged from 0.01, 0.05, 2.0 to 200?µg?l?1 were reached for ICP-MS; HG-ICP-AES; ETA-AAS and ICP-AES, respectively. Precision, calculated according to ISO 5725-2 for repeatability and within-laboratory reproducibility and expressed as relative standard deviation (RSD), ranged from 1.6% to 4.9%; and recovery, based on Decision 2002/657/EC, was found to be between 95% and 110%. Procedures for the mineralisation or extraction of total tin were compared. Wet digestion, sequentially, with nitric acid and hydrogen peroxide provided the best results. The influence of possible interferences present in canned food and beverage was studied, but no interference in the determination of tin was observed. Since maximum levels for tin established by European Union legislation vary from 50?mg?kg?1 in canned baby foods and infant foods up to 200?mg?kg?1 in canned food, ICP-AES was chosen as the preferred technique for routine analysis thanks to its good precision, reliability and ease of use. The accuracy of this routine method was confirmed by participation in six proficiency test schemes with z-scores ranging from ?1.9 to 0.6. Several canned foodstuffs and beverage samples from a local market were analysed with this technique. 相似文献
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The nitrate and nitrite content of leaf vegetables (Swiss chard, sea beet, spinach and cabbage), “inflorescence” vegetables (cauliflower) and fruit vegetables (eggplant and vegetable marrow) grown with organic fertilizers have been determined by a modified cadmium–Griess method. Samples were purchased from organic food stores as well as collected directly from an organic farm in Madrid (Spain). Nitrate levels were much higher in the leaf vegetables (especially Swiss chard species; average over the different samples and species of 2778.6 ± 1474.7 mg kg? 1) than in inflorescence or fruit products (mean values between 50.2 ± 52.6 and 183.9 ± 233.6 mg kg? 1). Following Swiss chard species, spinach (1349.8 ± 1045.5 mg kg? 1) showed the highest nitrate content, and nitrite was found above the limit of detection in some samples only (spinach, 4.6 ± 1.0 mg kg? 1; sea beet, 4.2 ± 0.7 mg kg? 1 and Swiss chard, 1.2 ± 0.4 mg kg? 1). Some vegetables (spinach, cabbage and eggplant) had lower nitrate content in the samples harvested in summer, showing the influence of climatic conditions on the nitrate levels in a plant. The samples taken directly from the organic farm, with the exception of eggplant, had higher or slightly higher average nitrate values than samples purchased in the organic food stores, ranging from 117 to 1077%. 相似文献
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采用火焰法、石墨炉法,样品消解后直接测定中药材丹参、白芍中重金属铜、铅、镉的含量。结果表明:重金属铜在0~0.8μg/mL、铅在0~80μg/L、镉在0~0.8μg/L范围线性关系良好,相关系数分别为0.995 6、0.996 3、0.999 4;丹参、白芍中所含铜、铅、镉均符合《中国药典》规定。本法简单、快速、灵敏,适用于中药材中微量重金属的测定,结果满意。 相似文献
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《分离科学与技术》2012,47(4):815-827
Abstract In the present paper a procedure for simultaneous preconcentration of Cd, Cu, and Pb using cloud point extraction (CPE) and multielemental sequential determination by thermospray flame furnace atomic absorption spectrometry (TS‐FF‐AAS) is proposed. This preconcentration procedure is based on the metals extraction into micellar media of octylphenoxypolythoxyethanol (Triton X‐114) after their reaction with 1‐(2‐pyridylazo)‐2‐naphtol (PAN). A Box‐Behnken design was used to optimize the variables (pH, buffer concentration and volume of NaCl) involved in the extraction procedure. Enrichment factors were calculated as the ratio between the slopes of calibration equations with and without the preconcentration procedure in the TS‐FF‐AAS, with values of 59, 25, and 21 respectively for Cd, Cu, and Pb. Limits of detection (LOD) (3sb, n=10) were also calculated as 0.025, 0.38, and 0.43 µg L?1 to Cd, Cu, and Pb, respectively. The precision (repeatability) expressed as relative standard deviation (RSD, n=10) for reference standards of 10.0 and 20.0 µg L?1 were 6.1 and 4.5% for Cd, 7.2 and 3.4% for Cu and 5.2 and 8.7% for Pb. The accuracy was confirmed through the analysis of certified reference material (NIST 1643d, Trace elements in water). The developed procedure was also applied to Cd, Cu, and Pb determinations in mineral water samples. 相似文献
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原子吸收光谱法测定食品中重金属含量的研究进展 总被引:4,自引:0,他引:4
原子吸收光谱近年来被广泛用于食品中重金属含量的测定,该方法与传统化学分析方法相比具有灵敏度更高、测定结果更准确等优点。本文综述使用原子吸收法测定蔬菜、粮食、海产品和饮品中的铅(Pb)、镉(Cd)、铬(Cr)、汞(Hg)和砷(As)等重金属元素的研究进展。对使用火焰原子吸收(FAAS)、石墨炉原子吸收(GFAAS)和氢化物发生原子吸收(HGAAS)等方法测定不同元素的准确性、灵敏度和回收率等进行评述,并对原子吸收法在食品重金属检测中的应用进行展望。 相似文献
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