6-硝基-1,2-重氮氧基-4-萘磺酸及其杂质的高效液相色谱分析

本文以反相高效液相色谱对6-硝基-1，2-重氮氧基-4-茶磺酸及有机杂质进行了分析，选择了流动相、离子对、检测波长，研究了不同牌号ODS C18色谱柱的重现性，得到了6-硝基-1，2-重氮氧基-4-萘磺酸及杂质(1，2-重氮氧基-4-萘磺酸、8-硝基-1，2-重氮氧基-4-萘磺酸)的相关系数分别为：0.99956、0.99991、0.99317；标准偏差和变异系数分别为：0.214250％、0．016890％、0．564557％、0.012695%、0.488467％、0.014560％得到了准确度数据，确定了最小检出量。     

超临界CO2萃取技术在天然香料工业中的应用与研究进展

分析了我国天然香料工业发展的形势及其应用新技术的必要性 ,论述了超临界CO2 萃取技术在天然香料开发中应用的现状及优越性 ,提出了应用超临界CO2 萃取技术进行天然香料开发的对策。     

煤制甲醇和合成氨废气作为天然气生产甲醇补加CO2源

该公司30万t/a以天然气为原料生产甲醇产品的过程中,产生过剩的氢随弛放气排放,另一处装置20万t/a煤制甲醇和10万t/a合成氨排放二氧化碳,造成资源浪费.通过技术改造,将原先作为废气排放的二氧化碳作为甲醇生产装置的补充碳源,该装置由蒸汽转化工艺改造为蒸汽转化前补碳工艺,从而大幅度降低天然气消耗和生产成本.在提高甲醇产品市场竞争力的同时,实现CO2减排.     

STUDY ON PERMEATION OF ACETONE/NITROGEN MIXED GAS THROUGH AL2O3 MICROPOROUS MEMBRANES: MOLECULAR DYNAMICS

In this work, by applying Materials Studio 2.2 software package, molecular dynamics (MD) was performed to investigate the dynamic processes of 1:4 acetone/nitrogen mixed gas permeating through different Al₂O₃ microporous membranes. Three systems were modeled by considering different box lengths, microporous sizes, and textures of Al₂O₃ membranes to compare different permeation behaviors. In each system, initial mixed gas contained 20 acetone molecules and 80 nitrogen molecules, and its density was set to 0.1 g/cm³. Analysis on the concentration profiles of nitrogen molecules (N2) and acetone molecules (Ace) in each system at different sampling times was implemented to discuss the permeation behaviors of smaller N2 and larger Ace. The results showed that adsorption and diffusion occurred synchronously but adsorption was dominant for acetone molecules and that the adsorption on the floor surface of the feed gas region more easily reached equilibrium (local equilibrium) than the diffusion and the adsorption on the ceiling of the initially vacuum region. Furthermore, for nitrogen, adsorption followed diffusion. Higher temperature is in favor of the enrichment of acetone on the floor surface of the feed gas region but against the adsorption of nitrogen. The adsorptive layer was found to be a double-layer with COMPASS force field and to be a monolayer with PCFF force field.     

纳米Fe2O3的制备与气敏性质的研究

报道了纳米氧化铁的制备工艺，采用沉淀法、溶胶凝胶法制备了纳米α-Fe2O3、γ-Fe2O3粉体，用热重－差热分析（TG－DTA）、X射线衍射（XRD）、透射电镜（TEM）和二次粒度分布对粒子进行表征，并制作了气体敏感元件。讨论了纳米氧化铁的制备工艺对气敏性质的影响。     

Keggin结构三维有序大孔PMo_(12)-SiO_2材料的制备与表征

以三维有序大孔SiO2为载体,采用等体积浸渍法将Keggin结构的12-磷钼酸(PMo12)固载化,制备了三维有序大孔PMo12-SiO2材料,利用IR、TG-DTA、XRD、SEM及低温N2吸附等测试手段对制备的样品进行了表征。结果表明,负载后磷钼酸的热稳定性显著提高,经500℃焙烧后,其Keggin结构依然保持;负载后,样品具有三维有序的大孔结构;磷钼酸以微晶形式高度分散在载体的孔隙中,其对孔隙的填充作用使载体的比表面积由125.4 m2/g下降到24.4 m2/g。     

城市污水生物脱氮除磷技术的研究进展

评述了近年来城市污水生物脱氮除磷技术的研究进展,重点介绍了生物处理的新方法:ANAMMOX–SHARON组合法、好氧同步脱氮除磷法和倒置A2/O法,并比较了各种工艺的优缺点。指出反硝化聚磷技术在倒置A2/O工艺中的应用将成为城市污水同步脱氮除磷研究的一个重要发展方向。     

Further study on the one-pot synthesis of (E)-2-nonenal from castor oil

A one-step procedure is described for the synthesis of (E)-2-nonenal from commercial castor oil by ozonolysis in methanol, followed by reduction of the ozonide products with dimethyl sulfide and exposure of the resulting intermediate product to dilute sulfuric acid. The developed process allows the production of the aldehyde with a yield of 80% at a purity of 95%. The method has advantages over all those reported earlier, because of inexpensive raw material and reducing agent, recycling of the solvent and its unusual simplicity.     

Enhancement by SO2 of initial activity for selective catalytic reduction of NO with CH3OH over \gamma-alumina

The effect of SO₂ on catalytic activity for NO reduction to N₂ by methanol in excess oxygen over $\gamma$ -alumina has been investigated. SCR activity increased initially upon exposure of a fresh $\gamma$ -alumina catalyst to SO₂ which is attributed to formation of Brønsted acid sites. Longer exposure to SO₂ leads to a decline in catalytic activity to a lower steady-state NO_x reduction activity which is independent of the SO₂ content in the feed gas.     

单参数Wilson方程预测C_9-DMP体系汽液平衡

根据实测γ~∞_1用单参数Wilson方程预测均三甲苯-DMP和偏三甲苯-DMP二元体系汽液平衡,并推算均三甲苯-偏三甲苯-DMP三元体系的汽液平衡,与实测数据比较,均获得良好结果。