高合金钢铸造用涂料的试制与开发

介绍了炉爪用合金钢1Cr25Ni20Si2Re,导板用合金钢2Cr32Ni5采用串箱铸造过程中，有关镁砂粉涂料和石英粉涂料的试制。结果表明：镁砂粉涂料为不透气涂料，不太适用，而合理配方的石英粉涂料使用性能良好。     

热处理对Ti-25V-15Cr-2Al-2Mo-0.2C合金组织稳定性的影响

研究了热处理对Ti-25V-15Cr-2A1-2Mo-0.2C阻燃β钛合金组织稳定性的影响。结果表明，高温固溶并直接时效处理导致合金β基体上析出较多的α相沉淀，尤其在随后的热暴露组织中形成了恶化合金塑性的连续晶界α膜。然而，若在时效前再进行一次低温固溶处理则可明显减少α相的析出数量，合金的热稳定性因此而得到显著改善。     

Al_(10)Zn_(2.9)Mg_(1.7)Cu超高强铝合金的喷射成形制备研究

采用喷射成形技术制备了Al1 0 Zn2 .9Mg1 .7Cu高强高韧铝合金沉积坯件 ,研究了喷射成形制备过程中各工艺参数对沉积坯件的成形性、显微组织、致密度的影响 ,确定了适当的工艺参数 ,研究了沉积坯件的热挤压及热处理工艺 ,对材料的组织进行了分析并对不同状态的材料性能进行了比较。研究结果表明 :当喷射成形工艺参数合理时 ,沉积坯件具有良好的成形性与致密度 ,在随后的热挤压过程中 ,通过较低的挤压比即可使材料达到全致密 ;通过对合金进行适当的热处理 ,材料的极限抗拉强度达到 810MPa ,同时延伸率保持在 8%～ 11% ,该材料是一种理想的轻质高强结构材料。     

Experimental Study on Polymer Artificial Bone with HA Coated and Fiber Liners

1Introduction HA(hydroxyapatite)wasakindofbioactiveceram ics,whichhadexcellentbiocompatibilityandtissueaffin ityinthatitscomponentsweresimilartothoseofhuman bone[1].Soitwasthebestknownhumanbonesubstitute,andunprecedentedeffecthadbeenharvestedinrecenttwo d…     

Plasma Sprayed Hydroxyapatite Coatings with Nano-hydroxyapatite Prepared by Ultrasonic Precipitation Process

Nano-particle hydroxyapatite （ HA ） was prepared with a novel ultrasonic precipitation process and the as-prepared nanopowder was used to produce hydroxyapatite （ HA ） coatings on titanium substrate via plasma spraying. The phase and the microstructare of the coating were characterized by X- ray diffraction （XRD） and scanning electron microscopy （SEM）. Results showed that spherical particles could be prepared by ultrasonic precipitation process; and a corresponding dense HA coating with molten surface and low-porosity cross-section structure was acquired. During the plasma spraying process, new phases of Ca3 （ PO4 ）2 and Ca2 P2O7 were generated. After heat-treating at 800℃ for 1 h, the contents of Ca3 （ PO4 ）2 and Ca2 P2O7 decreased while HA content increased. Tensile adhesion tests showed that the plasma sprayed coating prepared with the spherical nanoparticles exhibited high tensile bond strength.     

Water‐Stable,Magnetic Silica–Cobalt/Cobalt Oxide–Silica Multishell Submicrometer Spheres

A method to produce monodisperse magnetic composite spheres with diameters from less than 100 nm to more than 1 μm in water solution is reported. The spheres consist of a dielectric silica core and a cobalt/cobalt oxide shell which can be protected from further oxidation with an outer shell of silica or, alternatively, they can be covered with the polymer polyvinylpyrrolidone as a stabilizer. The formation of a uniform magnetic shell proceeds with the adsorption of metallic cobalt seeds, produced by the reduction of cobalt chloride with sodium borohydride, on a self‐assembled layer of polyelectrolytes on the silica core. In the second step, an outer silica shell can be formed by the hydrolysis and condensation of (3‐aminopropyl)trimethoxysilane and tetraethoxysilane. The double‐shell composite spheres show excellent sphericity, monodispersity, and a magnetic hysteresis loop at room temperature.     

Exchange and oxidation of CO on O-predosed Rh---Al2O3 and Rh---CeO2 catalysts

Exchange and oxidation of C¹⁶O were investigated at 450°C on ¹⁸O-predosed Rh and Pt catalysts supported on A1₂O₃, CeO₂ and CeO₂-Al₂O₃. In all cases, a rapid exchange of C¹⁶O with the surface can be observed. CO oxidation leads to C¹⁶O₂, C¹⁶O¹⁸O and C¹⁸O₂. Significant formation of C¹⁶O₂ is due to the relatively high ¹⁶O coverage in reaction resulting from the C¹⁶O exchange and from an exchange between O surface species and ¹⁶O internal atoms. Hydrogen is also formed via a water-gas shift reaction (CO + surface OH) in higher proportion on CeO₂-containing catalysts than on A1₂O₃. Chlorine inhibits all the reactions (exchange, oxidation and WGS) and particularly the internal exchange.     

硼／铝复合材料管构件的界面特性EI

主要研究带钛合金连接头硼／铝复合材料管构件中Ｂ－Ａｌ－Ｔｉ间的界面结构与性质。研究表明，在复合工艺条件下，硼－铝界面附近没有检测到任何铝－硼化合物，而钛－铝间形成ＴｉＡｌ有序金属间化合物相。实验证明，硼／铝复合材料与铝合金端环之间采用的固结方法是有效的，且可按照受载类型随意调整斜面搭接长度，达到承受不同载荷的目的。     

激光辐照制备搪瓷涂层

激光辐照制备的搪瓷涂层表面粗糙,与金属基材结合牢固。一般由 Si,Al,Na,K,B,F,O等元素组成。在激光辐照过程中 K,Na 明显地挥发,从而在涂层中的含量明显减少;Co,Ni,主要分布在界面附近;Fe 元素也由基材进入涂层,呈梯度状分布,在界面过渡区含量很高,在涂层内含量很低。搪瓷涂层的形成与激光辐照参数,特别与激光功率间存在极为密切的关系;只有选用合理的参数,才能制得搪瓷涂层。     

防腐涂料及涂装技术(Ⅷ)

防腐涂料及涂装技术讲座系列介绍防腐蚀涂料的品种和各类应用及最新产品研究进展。本讲主要介绍涂装前的表面预处理方法及表面处理质量的评定等