华龙一号活化腐蚀产物沉积源项评估

根据国内外核电厂主管道上沉积源项的运行经验数据,分析了两种主要核素Co-58和Co-60的沉积活度随电厂运行时间的变化趋势。在此基础上,采用一回路活化腐蚀产物源项计算软件预估了华龙一号的活化腐蚀产物沉积源项。在参考国内广泛运行的M310机型设计源项确定方法的基础上,分析给出了华龙一号活化腐蚀产物沉积源项的设计源项和现实源项,并与国内二代核电机组和国际三代核电机组进行对比,结果显示三者均处于同一量级水平,华龙一号与国际三代核电机组相差不大,且优于国内二代核电机组。分析结果显示本文预估的沉积源项具有一定的可靠性,华龙一号核电机组在活化腐蚀产物源项控制方面具有一定的先进性。     

内乡县李沟矽线石矿床地质特征及矿床成因

李沟矽线石矿床位于“豫西南高铝三石成矿带”中,受区域地层、构造及岩浆活动影响显著,属沉积变质矿床。该矿床赋存于古元古界雁岭沟组片岩内,矿床受地层和褶皱构造控制,矿体呈层状产出,成矿地质条件较好。本文在研究前人地质勘查资料的基础上,总结了该矿床的区域及矿区成矿地质条件,并对该地区矽线石矿的矿床成因、找矿标志进行了探讨。笔者认为李沟矽线石矿床及区域地层、构造、岩浆活动构成了“三位一体”的控矿机制,该矿床的周边地区内矽线石矿床(点)分布较多,李沟矽线石矿床及外围地区具有寻找矽线石矿的较好找矿前景。     

Transient and steady states of Gd2Zr2O7 and 2ZrO2∙Y2O3 (ss) interactions with calcium magnesium aluminium silicates

Reactions between calcium magnesium aluminium silicates (CMAS) and Gd₂Zr₂O₇ or 2ZrO₂?Y₂O₃ (ss) are investigated within a temperature range of 1200–1300 °C and for durations of 1 h–100 h. The evolution of CMAS penetration depth in Gd₂Zr₂O₇ and 2ZrO₂?Y₂O₃ (ss) pellets varies considerably depending on the interaction time. A quantitative analysis of the nature and composition of phases observed in stationary conditions (powder/powder interaction) is performed by SEM-FEG coupled with WDS analyses using micro-agglomerated nanoparticles of Gd₂Zr₂O₇ and 2ZrO₂?Y₂O₃. Faster kinetics of the gadolinium-based system are illustrated through an analysis of the morphology of the reaction area and of the resulting CMAS tightness of reaction products. The compositions and quantities of reaction products observed at equilibrium are very similar for the two systems, but transient states are significantly different.     

Experiments on mechanical properties of salt rocks under cyclic loading

The primary purpose of underground gas storages is to provide gas for seasonal consumptions or strategic reserve.The periodical operations of gas injection and extraction lead to cyclic loading on the walls and surrounding rocks of gas storages.To investigate the mechanical behaviors of different host rocks in bedded salt deposit,laboratory experiments were conducted on the samples of rock salt,thenardite,glauberite and gypsum.The mechanical properties of rock samples under monotonic and cyclic loadings were studied.Testing results show that,under monotonic loading,the uniaxial compressive stress(UCS) of glauberite is the largest(17.3 MPa),while that of rock salt is the smallest(14.0 MPa).The UCSs of thenardite and gypsum are 16.3 and 14.6 MPa,respectively.The maximum strain at the peak strength of rock salt(halite) is much greater than those of the other three rocks.The elastic moduli of halite,thenardite,glauberite and gypsum are 3.0,4.2,5.1 and 6.8 GPa,respectively.Under cyclic loading,the peak strengths of the rock specimens are deteriorated except for rock salt.The peak strengths of thenardite,glauberite and gypsum decrease by 33.7%,19.1% and 35.5%,respectively;and the strains of the three rocks at the peak strengths are almost the same.However,the strain of rock salt at the peak strength increases by 1.98%,twice more than that under monotonic loading.Under monotonic loading,deformation of the tested rock salt,thenardite and glauberite shows in an elastoplastic style.However,it changes to a ductile style under cyclic loading.Brittle deformation and failure are only observed for gypsum.The results should be helpful for engineering design and operation of gas storage in bedded salt deposit.     

甘肃省武都区塘坝金矿工程地质条件特征

塘坝金矿区位于甘肃省武都县,属琵琶乡管辖,气候为温暖带大陆性季风湿润气候,区内水系发育,属长江流域嘉陵江水系。塘坝金矿床是赋存在坚硬、半坚硬的碳酸盐岩和碎屑岩层中,灰岩和硅质角砾岩等硬性岩石一般为完整-较完整,岩体结构类型为块状结构,岩石稳定,工程地质条件较好,千枚岩等软弱岩石和断裂影响范围内的岩石一般稳定性差,岩石较破碎,岩体结构类型主要为层状碎裂结构和散体结构。矿区工程地质勘探属于第三类——层状岩类,工程地质勘探的复杂程度划分为中等型,属工程地质条件中等矿床。     

Model test of immersed tube tunnel foundation treated by sand-flow method

In order to explore the immersed tunnel foundation treated by sand-flow method, modeling principles for the full-scale model test of sand flow were put forward. In addition, a sand-flow test model was built, which consisted of model system, equipment system and measurement system. The situation of sand-deposit expanding and the water pressure in the foundation trench were evaluated through the model test. The results show that a semi-closed space was formed between the model board and the expanding sand deposit, which made the water pressure in it rising with little range of volatility. The sand deposit gradually became non-circular truncated cone which shaped with its expanding radius, and the difference of the water pressure increased at each direction. The water pressure in crater had a linear increase with the sand-deposit radius, with a maximal value of 0.015 2 MPa. The volatility of the water pressure under the tunnel board and the water pressure value in the crater could be used as bases of construction control.     

山西省娄烦县尖东铁矿地质特征及矿床成因

通过对山西省娄烦县尖东铁矿区域地质背景、矿区地质特征、矿体特征等的综合分析,阐述了该区铁矿的成因类型,总结其成矿规律,为铁矿的进一步勘查开发提供地质依据。     

Microstructure evolution of CMAS glass below melting temperature and its potential influence on thermal barrier coatings

CaO–MgO–Al₂O₃–SiO₂ (CMAS) deposition significantly degrades the performance of thermal barrier coatings (TBCs). In this study, the microstructure evolution of CMAS glass at temperatures below its melting point was investigated in order to study the potential influence of temperature on the applicability of CMAS glass in TBCs. The CMAS glass fabricated in this study had a melting point of 1240 °C, became opaque, and underwent self-crystallization when the temperature reached 1000 °C. After heat treatment at 1050 °C, diopside and anorthite phases precipitated from the glass; at a higher temperature (1150 °C), diopside, anorthite, and wollastonite were formed as the self-crystallization products. An increase in the dwelling time resulted in the transformation of diopside to wollastonite and anorthite. At 1250 °C, all products formed a eutectic microstructure and melted. The results indicate that even at low temperatures, CMAS glass underwent microstructure evolution, which could influence the coating surface and stress distribution when deposited on TBCs.     

CO2 sequestration in depleted methane hydrate deposits with excess water

The recent increase in atmospheric CO₂ concentration makes it necessary to investigate new ways to reduce CO₂ emissions. Simultaneously, natural gas hydrate mining technology is developing rapidly. The use of depleted methane hydrate (MH) deposits as potential sites for CO₂ storage is relatively safe and economical. This method can alleviate the shortage of hydrate displacement gas with CO₂. The purpose of this study was to investigate CO₂ hydrate formation characteristics during the seepage process—in reservoirs with excess water—and their effect on CO₂ storage. The experimental process can be divided into 5 parts: MH formation, water injection, MH dissociation, CO₂ hydrate formation, and CO₂ hydrate dissociation. Magnetic resonance imaging was employed to monitor the distribution of liquid water, and the effects of different parameters on the formation and dissociation of CO₂ hydrates were analyzed. It was found that a state of initial water saturation can effectively control hydrate saturation in artificial MH reservoirs for hydrate reservoirs with excess gas. In the process of CO₂ flow, initial water saturation was not the main controlling factor for CO₂ hydrate formation. Increasing the flow pressure and reducing the flow rate were beneficial for CO₂ hydrate formation. This study is of great significance for advancing the science of CO₂ geological storage in the form of deep‐sea hydrates.