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81.
LIU Guangzhen MA Zhanfang SHEN Jianquan 《武汉理工大学学报(材料科学英文版)》2006,21(4):16-18
1 IntroductionGold nanoparticles have attracted considerable atten-tionin manyfields duetotheir some special properties al-though goldis very popularfor beingchemicallyinert[1-3].For example ,gold nanoparticles as amplificationtags havebeenthe subject of research directed at gene analysis[4]and antibody or antigen detection[5-7]due to the large di-electric constant ,ease of preparation,andits biocompati-bility[8].Nanoparticles in the range of 1-10 nmin diameterwould display electronic structur… 相似文献
82.
研究了18种具有不同孔结构参数的粒状铜基甲醇合成催化剂孔隙率对有效扩散系数的影响。结果发现,催化剂微孔孔隙率增大,曲节因子亦增大,扩散阻力增加。将孔隙率与催化剂曲节因子关联,得到了半经验方程,用它可估算催化剂的曲节因子。 相似文献
83.
B. Van de Moortéle 《材料科学技术学报》2003,19(6)
The homogeneous plastic flow of fully amorphous and partially crystallized Zr(41.2)Ti(13.8)Cu(12.5)Ni(10)Be(22.5) bulk metallic glass (Vitl) has been investigated by compression tests at high temperatures in supercooled liquid region. Experimental results show that at sufficiently low strain rates, the supercooled liquid of the fully amorphous alloy reveals Newtonian flow with a linear relationship between the flow stress and strain rate. As the strain rate is increased, a transition from linear Newtonian to nonlinear flow is detected, which can be explained by the transition state theory. Over the entire strain rate interval investigated, however, only nonlinear flow is present in the partially crystallized alloy, and the flow stress for each strain rate is much higher. It is found that the strain rate-stress relationship for the partially crystaltized alloy at the given temperature of 646 K also obeys the sinh law derived from the transition state theory, similar to that of the initial homogeneous amo 相似文献
84.
In this paper, the microstructure of a 1 wt.% Cu/γ-Al2O3 catalyst that was reduced in a 4% hydrogen/argon atmosphere at temperatures of 523, 773 and 1073 K, is studied by Z-contrast imaging and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Results show that the copper species are well dispersed when the catalyst is reduced below 523 K. At 773 K, separated Cu(I) and Cu(0) species are found existing as ring-like and bulk-like particles. This appears to indicate that the copper has not been reduced to its metallic form due to the interaction between the copper oxide and the support. Large spherical particles having core-shell structures with Cu(I) in the shells and Cu(0) in the cores are generated when the catalyst is reduced at 1073 K. The formation of partially oxidized copper species upon reduction at 1073 K is attributed to the metallic copper interaction with the alumina support. This study also demonstrates that high-spatial resolution Z-contrast imaging and EELS performed simultaneously can provide unique information on the morphology and chemistry of metal species in supported metal catalysts. 相似文献
85.
86.
87.
T. D. Dzhafarov S. S. Yesilkaya N. Yilmaz Canli M. Caliskan 《Solar Energy Materials & Solar Cells》2005,85(3):371-383
The effective diffusion coefficients of Cu for thermal and photodiffusion in the CdTe films have been estimated from resistivity versus duration of thermal or photoannealing curves. In the temperature range 60–200°C the effective coefficient of thermal diffusion (Dt) and photodiffusion (Dph) are described as Dt=7.3×10−7exp(−0.33/kT) and Dph=4.7×10−8exp(−0.20/kT).It is found that the diffusion doping of CdTe thin films by Cu at 400°C results in a sharp decrease of resistivity up to 7 orders of magnitude of p-type material, depending on thickness of Cu film. The comparative study of performance of CdTe(Cu)/CdS and CdTe/CdS cells has been studied. It is shown that the diffusion doping of CdTe film by Cu increases efficiency of CdTe(Cu)/CdS cells from 0.9% to 6.8%. The degradation of photovoltaic parameters of CdTe(Cu)/CdS cell, during testing under forward and reverse bias at room temperature, proceeds at a larger rate than those of CdTe/CdS cell without Cu. The degradation of performance of CdTe(Cu)/CdS cells is tentatively assigned to electrodiffusion of Cu in CdTe, resulting in redistribution of concentration of Cu-related centers in CdTe film and heterojunction region. 相似文献
88.
分析了钼精矿Cu、Pb含量高的主要原因 ,通过实施一系列措施 ,达到了降低钼精矿中Cu、Pb含量的目的 相似文献
89.
Benedetto Bozzini Bertrand Busson Claudio Mele Abderrahmane Tadjeddine 《Journal of Applied Electrochemistry》2008,38(7):897-906
We report on potential-dependent in situ SFG and DFG spectroscopy carried out at Au(111), Au(210), polycrystalline Au, Au–Cu
and Au–Ag–Cu electrodes in contact with aqueous solutions containing CN− and 4-cyanopyridine (4CP). Spectroelectrochemical work was complemented by cyclic voltammetry. The chief stress has been
placed on systematising and quantifying the interaction between 4CP and CN− and the attending effects on the vibrational and electronic structures of the interface. The voltammetric behaviour of the
investigated electrodes, modified by the addition of 4CP to the CN− electrolyte, denote changes in the CN− adsorption characteristics and effects of the adsorbed CN− layer on the electrodic reactivity of 4CP. The differences among the investigated electrodes can be explained in terms of
their respective degrees of atomic packing or with alloying effects on the stability of adsorbed CN−. The potential-dependent spectra have been analysed quantitatively with a model for the second order non linear susceptibility
accounting for vibrational and electronic effects. The spectral changes induced by addition of 4CP denote interaction of the
aromatic with the electrode through the CN− monolayer. The non-resonant contribution yields information on the effects of 4CP on the fine structure of the bound electron
density of states. 相似文献
90.
Bionanoparticles of starch obtained by submitting native potato starch granules to acid hydrolysis conditions. The resulted starch nanoparticles were used as core or macro initiator for polymerization of ε‐caprolactone (CL). Starch nanoparticle‐g‐polycaprolactone was synthesized through ring‐opening polymerization (ROP) of CL in the presence of Sn(Oct)2 as initiator. The detailed microstructure of the resulted copolymer was characterized with NMR spectroscopy. Thermal characteristic of the copolymer was investigated using DSC and TGA. By introducing PCL, the range of melting temperature for starch was increased and degradation of copolymer occurred in a broader region. X‐ray diffraction and TEM micrographs confirmed that there was no alteration of starch crystalline structure and morphology of nanoparticles, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献