Effect of ultrasound on thermoset polyurethane: NMR relaxation and diffusion measurements

Recycling of rubber-based materials is of increasing industrial environmental importance. In order to characterize the effect of ultrasound on polymer networks, nuclear magnetic resonance (NMR) relaxation and pulsed-gradient diffusion measurements were made at 70.5 °C in polyurethane rubber (PUR) and foam after subsequent treatment by intense ultrasound. The proton transverse relaxation decay was analyzed in terms of molecular and segmental mobilities of all motional species, a chemical and physical network as well as diffusing sol. The diffusivity spectrum, measurable in foams, reflected the changing molecular weight distribution of low-molecular weight sol and oligomers. It was observed that the effect of ultrasound was less pronounced in PUR than rubbers like SBR, PDMS and BR owing to its low degree of unsaturation. The investigation on the foams is the first of its kind to be reported.     

Werkstoffliche Aufbereitung von Wärmedämmverbundsystemen

Due to increasing energy requirements for buildings, thermal insulation composite systems (TICS) have been used to insulate building facades since the 1970s. In view of the longevity of these composite materials, there has been an increased amount of TICS waste in recent years. Since there is no current recycling concept for these systems, an enormous resource efficiency potential remains unused. Due to the complexity of composite materials this study focuses on the pretreatment and discusses different processing steps in detail.     

Recycling von marinen Sekundärrohstoffen

As a waste product, oyster shells pose a major environmental pollution problem and the reuse of the material is becoming increasingly important. Since the comminution process in the recycling of secondary raw materials defines the properties of the material, oyster shells were grinded using a planetary ball mill and an impact mill and the fractions obtained were analyzed in terms of size and shape and compared with each other. A comminuted material from the impact mill was used for a series of wetting experiments, which helped to demonstrate the surface free energy of the material.     

Potenziale und Grenzen der Sekundärrohstoffgewinnung – Ergebnisse der r4-Begleitforschung

The socio-economic and ecological impacts of selected projects of the BMBF funding program “r⁴ – Innovative Technologies for Resource Efficiency – Research for the Provision of Raw Materials of Strategic Economic Importance” are presented. Many, but not all, research projects indicate a potential improvement of the supply situation in Germany. In some cases, the provision of secondary raw materials is unprofitable or ecologically detrimental. These cases require a balancing between security of supply and other economic and ecological objectives.     

Klärschlammverbrennung in einer stationären Wirbelschicht mit integrierter Phosphor-Rückgewinnung

Currently, wet-chemical and thermochemical processes in particular are being discussed for the future obligatory recovery of phosphorus from sewage sludge. The coupling of phosphorus recovery with incineration in stationary fluidized bed incinerators, the dominant mono-incineration technology, offers potential advantages in terms of aftertreatment costs and economic efficiency. Tests have shown that by adjusting the incineration conditions and adding additives, an ash could be produced that corresponds to the fertilizer ordinance (DüMV) and can, therefore, potentially be used as phosphorus recyclate.     

Preliminary study of the use of spent diatomaceous earth from the brewing industry in clay matrix bricks

In this work the effect of spent diatomaceous earth (SDE), as pore forming or silica carrier, on the properties of clay ceramic bricks was investigated. Mixtures of clay and SDE waste were, compacted, dried and fired at 950°C during 6?h. The technological properties of waste-clay bricks were analysed to evaluate the influence of the waste incorporation. The SDE (1–5?wt-%) addition in the clay matrix causes a reduction between 6 and 12% of the bulk density compared with the control samples (only clay) which implies good insulating characteristics. In addition, the waste incorporation increases the water absorption within the range 4–31% and decreases the compressive strength between 12 and 26%. However, the incorporation of the waste is beneficial as no remarkable changes in the technological properties are observed. These results indicate that the waste has a predominant pore forming effect over a pore filling effect.     

转炉出钢用均质挡渣球的研制与应用

研制开发出一种转炉出钢用均质挡渣球。选用转炉喷溅渣经过磁选之后的粒钢和高铝矾土等为原料,铝酸钙水泥作为结合剂,三聚磷酸钠作为减水剂。该均质挡渣球在钢水中定位准确,具有良好的挡渣效果,不仅可以降低冶炼成本,还能为钢渣循环利用开辟新的途径。该均质挡渣球已应用于实际生产中,效果良好。     

城乡规划空间理念在县域循环经济规划中的应用探讨——以永济市为例

循环经济规划在空间研究方面尚存在不足,城乡规划空间理念可弥补其不足。以永济市为例,从微观、中观和宏观三个层面探讨城乡规划空间理念在县域循环经济规划中的应用。将城乡规划空间理念引入县域循环经济规划,可为政府实施规划提供指引,有利于生态产业体系的构建,确保规划的实施和经济、社会目标的实现。