Al-Si合金的等离子电解氧化及膜层组织性能研究

为提高铝合金材料在高温下的使用性能,采用等离子电解法在锆盐体系和锆盐-钇盐复合体系中于铝硅合金表面制备了陶瓷层.分析了电解液浓度及成分对起弧电压、膜层厚度、组织及隔热温度的影响.研究结果表明:两种电解液体系中随电解液浓度的增大,起弧电压降低,陶瓷层厚度和隔热温度先增大后减小.与锆盐体系相比,锆盐-钇盐体系中起弧电压显著降低,膜层厚度与隔热温度提高.锆盐体系陶瓷层中生成了常温下稳定的t-ZrO2,锆盐-钇盐体系涂层中则生成了立方相的c-Y0.15Zr0.85O1.93.制备的两种陶瓷膜层与传统的硅酸盐膜层相比,其表面孔洞较少,锆盐-钇盐体系相对于锆盐体系其陶瓷层更加均匀、致密.     

TiO_2-SiO_2复合气凝胶涂层的制备和光催化性能

利用TiCl4和工业水玻璃为原料,通过溶胶凝胶法制备TiO2-SiO2复合凝胶,用三甲基氯硅烷(TMCS)/乙醇(EtOH)/正己烷(Hexane)混合溶液对湿凝胶进行改性,常压干燥制备了TiO2-SiO2气凝胶,经150℃干燥所得的气凝胶具有多孔结构,获得的气凝胶比表面积达到646～816m2/g,孔体积达到1.52～2.19cm3/g。用乙醇作为分散剂,将气凝胶块体研磨成具有一定黏度的浆料,采用丝网印刷法制成TiO2-SiO2复合气凝胶涂层。利用X射线衍射(XRD)、扫描电镜(SEM)和孔径及比表面积分析仪(BET)对复合气凝胶的结构、形貌和孔性质进行了研究,通过分光光度计法分析了TiO2-SiO2复合气凝胶涂层光催化降解罗丹明B的性能,在可见光下照射4h后降解率达到77%。     

钛基人工骨种植体表面改性研究进展

钛及钛合金以其良好的生物相容性、合适的机械性能和物理特性而被越来越多地应用于骨科移植,表面改性是将钛及其合金应用于骨组织工程最基本的技术．作者从化学处理改性、钛表面生成钙磷陶瓷涂层改性、生物化学方法改性三个方面总结了目前钛基人工骨表面改性技术的研究现状及进展．     

Al-C/Al-N/Al涂层膜基结合强度工艺试验研究

通过对Al-C/Al-N/Al太阳能选择性吸收涂层沉积工艺的研究,分析了该涂层膜基结合强度较差的原因,进行了不同沉积工艺条件下的涂层膜基结合强度、吸收率和热损试验,对试验结果进行了仔细的分析,优化确认在Al-C/Al-N/Al太阳能选择性吸收涂层沉积工艺基础上实施第N层充N2气体工艺,可以较好的提高涂层的膜基结合强度,同时保证涂层的吸收率和集热管的热损不发生明显的下降.     

Study of Thermal Radiation Properties of Pyrolytic Carbon Protective Coatings for Monocrystalline Silicon Furnace

The thermal radiation properties of pyrolytic carbon （PyC） protective coatings for monocrystalline silicon furnace prepared by different processes were tested. The changes of normal emissivity of carbon materials caused by PyC protective coatings were discussed, and the influence of phase structure and surface appearance on the thermal radiation properties was investigated. The results show that the thermal radiation properties of PyC protective coatings with the wave band of 5 -25 I~m are better than C/C substrate, further, normal spectral emissivity of CVD PyC coating remains basically at 0. 85 - 0. 90, and the normal total emissivity can reach 0. 89, which shows high thermal radiation performance. For resin PyC coating and CVD PyC coating, the degree of graphitization are 44. 53% and 16. 28% respectively, and the R value of Raman spectrum are 0. g64 and 1. 384 respectively. Relatively disorder graphite structure of the latter causes various vibration modes, and the spectral emissivity is better, so the thermal radiation property of CVD PyC coating is excellent. A lot of spherical particles exists on the surface of the CVD PyC coating, and the more interface and spacing of particles reduce the number of particles per unit volume. Therefore, the scattering of thermal radiation is strongly strengthened, and the spectral emissivity is higher.     

Tribological performance of TiAlSiN and TiAlCrN/TiAlN coating blades

A new laboratory evaluation method for the coating blade was developed, and the tribological properties of coating blades with different Ti-based coatings were studied by UMT-2 tribometer. Comparison between the areas of scratches before and after the cutting experiment was used to evaluate the cutting performance of the blades. Results showed that friction coefficient of TiAlCrN / TiAlN coating was significantly lower than that of TiAlSiN coating. Analysis of the worn surface revealed that the TiAlSiN and TiAlCrN / TiAlN coatings in the dry turning process exhibited sign of inhomogeneous adhesive wear and abrasive wear. TiAlCrN/TiAlN coating has a longer working life and better anti-wear property because of its duplex coating.     

900℃加热后热喷涂FeCrAl/AlSi复合涂层组织变化

为开发一种经济可靠的高温防护涂层,采用电弧喷涂方法在低碳钢表面制备FeCrAl/AlSi复合涂层,并对复合涂层试件进行900℃温度下的2400h加热,以考察其高温氧化表现和微观组织变化.实验结果表明：复合涂层中抗氧化元素的相互配合很好地保护了基体金属.900℃加热3h,防护涂层表面以及内部的氧化物以Al2O3为主,涂层/基体界面两侧形成Cr元素的扩散带.经过2400h加热后,复合涂层外表面氧化物层增厚,涂层/基体界面原位生成铬的氧化物,界面基体金属一侧存在约200μm宽的Cr元素扩散带.     

活性瓷釉涂层钢纤维混凝土板动、静力学特性研究

活性瓷釉涂层是近几年才开始系统研究的一项新型钢筋涂层技术.活性瓷釉涂层能够显著增强钢筋与混凝土黏结能力和钢筋的抗腐蚀能力,成本低廉,工艺简单,利于大范围使用.对活性瓷釉涂层钢筋的黏结强度和防腐蚀能力进行了论述,并通过钢纤维混凝土板的动、静力试验,验证了活性瓷釉涂层应用于钢筋混凝土结构防爆中的可行性.研究表明,活性瓷釉涂层能够提高钢筋、钢纤维与混凝土的黏结性能,从而改善结构的整体性,显著增强结构承载能力和抵御爆炸荷载的能力.     

电子元器件用紫外荧光敷型涂层材料的研制

以硅烷偶联剂、甲基丙烯酸甲酯、甲基丙烯酸、引发剂过氧化二苯甲酰(BPO)、环保型混合溶剂、荧光粉等为原料,采用溶剂聚合方法,合成了环保型紫外荧光三防保护涂料;考察了反应温度、引发反应诱导期、引发剂用量等因素对涂料性能的影响;介绍了环保型紫外荧光三防保护涂料的性能特点.