镁合金表面热喷铝工艺及防腐性研究

简述了在镁合金上的热喷铝工艺，并对表面喷铝层的耐腐蚀性进行了分析研究。对腐蚀后的表面进行了形貌观察及成分分析。结果表明，经热喷铝处理后，镁合金的耐腐蚀性能得到了极大的提高。     

Effect of temperature on mechanical behavior of AZ31 magnesium alloy

Strain rate sensitivity and tension/compression asymmetry of AZ31 magnesium alloy at different temperatures and strainrates were investigated.Both of mechanical behaviors are temperature dependent.Strain rate sensitivity increases with increasingtemperature.Thermally activated slip is the source of strain rate sensitivity.At the temperature below or near 373 K,strain ratesensitivity is very little.Tension/compression asymmetry in yielding decreases with increasing temperature.Twinning is the reasonof tension/compression asymmetry.At the temperature above or near 573 K,the material shows little tension/compressionasymmetry of the flow stress.     

半固态镁合金流变成形技术及装备

研究了镁合金半固态流变成形技术及装备，结果表明，多功能螺纹元件组合的双螺杆制浆装置制备的浆料晶粒细小（10～50μm)，固相率可在5%～50%范围内调整，封闭式加热保温，快开快关控制的浆料存储与输送装置，较好地解决了浆料连续制备与间歇压铸的配套；生产的半固态压铸件，强度提高了20%以上。     

Thermodynamic database of the phase diagrams in the Mg-Al-Zn-Y-Ce system

The Mg-Al-Zn-Y-Ce system is one of the key systems for designing high-strength Mg alloys. The purpose of the present article is to develop a thermodynamic database for the Mg-Al-Zn-Y-Ce multicomponent system to design Mg alloys using the calculation of phase diagrams （CALPHAD） method, where the Gibbs energies of solution phases such as liquid, fcc, bcc, and hcp phases were described by the subregular solution model, whereas those of all the compounds were described by the sublattice model. The thermodynamic parameters describing Gibbs energies of the different phases in this database were evaluated by fitting the experimental data for phase equilibria and thermodynamic properties. On the basis of this database, a lot of information concerning stable and metastable phase equilibria of isothermal and vertical sections, molar fractions of constituent phases, the liquidus projection, etc., can be predicted. This database is expected to play an important role in the design of Mg alloys.     

Wear resistance of ceramic coating on AZ91 magnesium alloy by micro-arc oxidation

The ceramic coating formed on AZ91 magnesium alloy by micro-arc oxidation （MAO） was characterized. The results show that the ceramic coating （3.4-23 μm in thickness）on the surface ofAZ91 alloy was attained under different micro-arc oxidation treatment conditions, which consist mainly of MgO, Mg2SiO4 and MgSiO3 phases. Nano-hardness in a cross-sectional specimen was determined by nano-indentation experiment. The MAO coatings exhibit higher hardness than the substrate. Dry sliding wear tests for the MAO coatings and AZ91 alloy were also carded out using an oscillating friction and wear tester in a ball-on-disc contact configuration. The wear resistance of the MAO coatings is improved respectively under different treatment time as a result of different structures of ceramic coatings formed on AZ91 alloy.     

MnCl2对镁合金废旧料组织性能的影响

利用等离子发射光谱仪、金相分析、电镜、万能电子材料试验机、腐蚀试验等方法研究了含有不同量的MnCl2熔剂对镁合金废旧料的力学性能、组织、断口形貌以及腐蚀行为的影响。研究表明,MnCl2可以降低镁合金废旧料中的Fe含量,同时会增加镁合金的Mn量,使用含MnCl2的熔剂可将镁废旧料中的Fe含量降到0 0072%以下。采用含MnCl2的熔剂可以提高试样的σb和δ。当合金中的Mn量超过一定程度后,对镁合金的力学性能会产生不利的影响。金相观察表明,净化处理对断口形貌无明显的影响,不改变AZ91镁合金的断裂机理,断口均成准解理断裂。腐蚀试验表明,采用含30%MnCl2的熔剂可以使试样的腐蚀速率从20 9mg/(cm2·d)降到6 4mg/(cm2·d)。     

Na2B4O7对镁合金旧料组织和性能的影响

利用等离子发射光谱仪、电镜、X衍射、万能材料试验机、腐蚀试验等手段研究了不同Na2B4O7含量的熔剂对镁合金废旧料的力学性能、相组成、断口形貌以及腐蚀行为的影响.研究表明,使用含Na2B4O7的熔剂可以使镁合金旧料中Fe的质量分数降低到0.004%以下,同时提高材料的抗拉强度和伸长率.腐蚀试验表明含Na2B4O7的质量分数为20%的熔剂可以使材料的腐蚀速率从15.1 mg*cm-2*d-1降低到0.4 mg*cm-2*d-1.电镜观察和X衍射表明,净化处理对断口形貌和相组成没有明显影响.最后分析了Na2B4O7除铁的机理,认为Fe与B形成某种化合物沉淀下来是主要原因.     

定向凝固AZ31镁合金晶粒取向及力学性能研究

采用自行设计的定向凝固装置制备了AZ31镁合金铸件,通过金相观察、XRD分析和室温压缩试验,研究定向凝固工艺对AZ31镁合金晶粒取向和常温力学性能的影响。结果表明:定向凝固制备的AZ31镁合金铸件具有柱状晶组织,第二相呈球状弥散分布于晶粒内部。由于温度梯度的影响,晶体规律性地定向生长,呈现较明显的[1010]择优取向。该铸件在常温力学性能和塑性成形性能上表现出各向异性的特点。     

快速凝固Mg94.6Zn4.8Y0.6合金薄带微观结构及显微偏析

采用单辊快速凝固技术制备了Mg94．6 Zn4．8 Y0.6合金快速凝固薄带，并通过扫描电镜的背散射及线扫描研究了快速凝固Mg94．6 Zn4．8 Y0.6合金薄带的显微偏析。结菜表明，由于溶质截流，单辊快速凝固Mg94．6 Zn4．8 Y0.6合金薄带为过饱和单相α—Mg固溶体的蜂窝状组织，Mg、Zn和Y宏观分布比较均匀。但在薄带厚度方向上存在偏析，在晶内也存在显微偏析，偏析形成是由于从辊面到自由面凝固速度的差异及溶质传输和晶格结构造成的，其中Zn元素偏析最大，Y元素次之，Mg元素最小。     

《材料保护》2007年第11期

变形铜合金在盐雾和二氧化硫环境中的耐蚀性研究；45钢上Ni-W-Co-B4C复合镀层的制备及其摩擦学性能；稀土Ce和Nd对AZ31镁合金耐蚀性能的影响；Al2O3粒子对双脉冲电沉积NiAl2O3镀层组织与性能的影响；MB8镁合金化学转化膜的耐蚀性能。[第一段]