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《Journal of the European Ceramic Society》2020,40(1):103-107
Tunable and ultrabroadband mid-infrared (MIR) emissions in the range of 2.5–4.5 μm are firstly reported from Co2+-doped nano-chalcogenide (ChG) glass composites. The composites embedded with a variety of binary (ZnS, CdS, ZnSe) and ternary (ZnCdS, ZnSSe) ChG nanocrystals (NCs) can be readily obtained by a simple one-step thermal annealing method. They are highly transparent in the near- and mid-infrared wavelength region. Low-cost and commercially available Er3+-doped fiber lasers can be used as the excitation source. By crystal-field engineering of the embedded NCs through cation- or anion-substitution, the emission properties of Co2+ including its emission peak wavelength and bandwidth can be tailored in a broad spectral range. The phenomena can be accounted for by crystal-field theory. Such nano-ChG composites, perfectly filling the 3–4 μm spectral gap between the oscillations of Cr2+ and Fe2+ doped IIVI ChG crystals, may find important MIR photonic applications (e.g., gas sensing), or can be used directly as an efficient pump source for Fe2+: IIVI crystals which are suffering from lack of pump sources. 相似文献
13.
《Ceramics International》2020,46(8):12138-12144
A new mechanoluminescent phosphor was developed from a sodium (Na) superionic conductor (NASICON)-structured Na3Sc2(PO4)3:Eu2+ phosphor that is known for its self-healing properties. The compound that crystalized assuming monoclinic C2/c symmetry was found to be blue-emitting, with no noticeable persistent luminescence. Thermoluminescence analysis showed that the phosphor had two prominent distinct thermal emission bands corresponding to the high-temperature β- and γ-phases of the composition. The mechanoluminescence properties of the material that does not have any persistent luminescence at room temperature were investigated by imparting impulsive strain. The compound on charging with 365 nm radiation was found to have significant mechanoluminescent emission originating from shallow defects present in the β-phase of composition that formed by the stress-induced phase transition process. Its emission characteristics and temporal behavior were investigated by varying the impact velocity. 相似文献
14.
R. Dwaraka 《Machining Science and Technology》2020,24(4):638-662
AbstractThe performance of electrical discharge machining (EDM) primarily depends on the spark quality generated in the inter-electrode gap (IEG) between the tool and workpiece. A method for obtaining accurate information about the spark gap is required to effectively monitor the EDM process. The rise and fall of thermal energy in the discharge zone at a rapid rate during the dielectric breakdown produces high-pressure shock waves. This work explores the suitability of using acoustic emission (AE) generated from these shock waves and the elastic AE waves released on the workpiece due to the induced stress to monitor the performance and spark gap in EDM. The information content of the AE signals acquired at various machining conditions was extracted using AE RMS, spectral energy and peak amplitude. These features were able to well discriminate the machining condition, tool material, workpiece material, flushing pressure, current density, the initial surface roughness of the tool. Additionally, the AE signal features had a good and consistent correlation with the performance parameters, including material removal rate, surface roughness (Ra and Rq) and tool wear. The findings lay the groundwork to develop an effective, non-intrusive in-situ AE-monitoring system for performance and IEG condition in EDM. 相似文献
15.
本研究分析了钢铁企业焦化和烧结两个重点工序中烟气污染物排放现状和钢铁行业当前的环保政策。对焦化及烧结烟气污染物的排放特征进行了分析,并通过对比燃煤电厂烟气特点,提出可以综合电厂烟气治理模式和自身特点改进的技术路线。结合某大型国有钢铁企业的脱硫脱硝装备对其环保现状进行了分析。针对焦化和烧结工序的典型污染物硫、硝、尘现有的源头减排、过程控制及末端处理技术,分析其优缺点。进而提出了3条可实现烟气污染物超低排放的技术路线,即半干法脱硫耦合选择性催化还原脱硝、半干法/湿法耦合臭氧氧化脱硝、活性焦脱硫脱硝一体化技术,重点介绍了这些技术在某大型钢铁企业的应用实践及应用效果。并基于全过程耦合技术,分别在焦化和烧结工序中提出了多污染物协同去除技术及应用,即焦炉低氮燃烧技术耦合末端活性焦多污染物协同控制技术、烧结烟气循环技术耦合末端活性焦多污染物协同控制技术。最后结合几种技术路线的应用实践,对未来钢铁产业的烧结及焦化工序超低排放技术的选择提出合理化建议。 相似文献
16.
为研究高校既有建筑室内人群散发对室内VOCs的影响,对高校不同人群样本的教室及会议室两类典型人群密集房间,共82个人群样本对象进行了VOCs采样分析,得到不同实际场景下的人员相关的VOCs浓度水平,并对其潜在的影响因素进行分析。结果表明,共确认了29种与室内人员相关的高检出率且较高浓度值的物质,包括芳香族化合物9种,烷烯烃类9种,酮类和醛类8种,醇酯类以及卤化物3种,并得到主要VOCs物质的浓度水平和I/O比。对影响因素的统计分析表明,室内人员密度、季节和房间类型对不同VOCs物质存在显著性影响,其中季节性因素对目标VOCs污染物影响最为广泛,其次是房间类型与室内人员密度。该研究可为进一步了解人员密集室内VOCs污染现状及控制策略提供一定的科学参考。 相似文献
17.
Over the last decade, narrow-band emitters have been recognized as key enablers for light emitting diodes (LEDs) backlights in liquid-crystal displays (LCDs) by competing with other display technologies. Today, efforts have been devoted to the exploration of narrow-band green/red luminescent materials with high quantum efficiency and excellent stability to optimize the performance of LED backlights. This review first presents an overview of the significant progress made in the development of narrow-band emitters used in LED backlights for LCDs with the emphasis on the versatile materials databases from doped phosphors to luminescent II–VI, III-V semiconductor quantum dots, and the recent halide perovskites nanocrystals and bulk metal halides. Subsequently, the correlation of structure-luminescence properties, and the device performance optimization of these emitters have been analyzed. The focus is placed on summarizing and comparing the remarkable examples of outdated and new narrow-band luminescent materials as potential candidates in LED backlights. Finally, the outlooks and challenges in discovering new narrow-band emitters have been proposed. 相似文献
18.
本文在深入研究水声通信信道特性及多载波关键技术的基础上,设计并研制了基于M FSK的高速自适应多载波水声通信系统,并进行了湖上实验。理论分析、仿真及湖上试验结果表明:基于M FSK的多载波水声通信系统,多径抑制有效,对同步的精确度要求不高,性能稳健,更适合于恶劣水声通信环境下、中距离(10~30km)较高数据率多载波通信系统,易于工程实现,具有良好的应用前景。 相似文献
19.
20.
碳纳米管膜的场致发射电流密度仅由它表面的宏观电场决定,无论其表面形状是平的还是半球状的。对于理想的平行板电极系统,其表面电场强度均匀(UId),发射电流密度、总电流与发射面积成正比:对于半球一平面电极系统半球形的阴极存在一个宏观场增强因子ks,一个与两极距离和球半径之比(d/r)相关的函数,其表面的平均场强为ks U/d。对于d/r=0,ks=1,d≥r的情况,ks接近于常数。对于10〈d/r〈100的情况,存在一个经验的表达式:ks=1+0.15d/s=0.005(d/r)^2。在引入ks后,不同作者给出的平面电极系统和半球一平面电极系统碳纳米管膜的场致发射电流I与宏观表面电场强度E的关系都可以近似用-经验公式描述:I=a(E-Eo)^b,a,b为常数。该经验公式可为稳定生产的CNT膜片应用产品设计提供方便。 相似文献