顶空气相色谱法测定氯甲烷工业废水中挥发性卤代烃

以角鲨烷为固定液,氢火焰检测器检测,医用100 mL输液瓶为气液平衡瓶的顶空气相色谱法分离分析了氯甲烷工业废水中的二氯甲烷、三氯甲烷和四氯化碳。在选定的条件下,结果重现性好、准确度高,方法简便易行。     

油水相对渗透率曲线在特高含水油藏中的应用

运用相对渗透率曲线计算了纵向砂体的剩余油饱和度分布,结果表明,当油田综合含水率为98%时,水驱剩余油饱和度为40.13%,可动油饱和度为13.41%,油层存在非均质性,在剩余油饱和度相对高的部位仍有一定潜力;濮南沙二上2 3油藏平均油水相对渗透率曲线具有较好的代表性,可以在特高含水油藏中应用。     

Preparation of fluoroacrylate nanocopolymer by miniemulsion polymerization used in textile finishing

Latex based on fluoroacrylate (TAN) and other comonomers was prepared via miniemulsion polymerization in the presence of stearyl trimethyl ammonium chloride (STAC) and 2, 2′‐azobis (2‐amidinopropane) dihydrochloride (ABAP) as a water soluble initiator. Light transmittance studies demonstrated that the light transmittance of prepared emulsions increases with the amount of TAN, STAC, cosolvent DPM, and hydrophobe DM. Given suitable reaction temperature and quantities of TAN, STAC, DPM, and DM, a copolymer emulsion of fluoroacylate with a particle size of 50 nm was produced. The water repellency tested on polyester fabrics displayed greater effectiveness than that of commercial products with higher fluorine content. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1466–1472, 2004     

饮用水中氯化消毒副产物的研究进展

自Rook首次报道饮用水中存在三氯甲烷，有关氯化消毒副产物（CDBPs）的研究一直受到广泛关注。该文介绍了CDBPs的研究进展，包括形成机理与影响因素、浓度水平、健康风险及控制技术。指出除天然有机化合物外．应关注水源水中的有毒有害有机物在氯化消毒过程中的变化。     

Simulation studies on the fuel electrode of a H2---O2 polymer electrolyte fuel cell

The macro-homogeneous porous electrode theory is used to develop a model which describes the catalyst layer of the hydrogen electrode formed by catalyst particles that are bonded to the membrane. The water transport in the catalyst layer and polymer electrolyte membrane is considered. The effects of catalyst layer structure parameters such as polymer volume fraction, catalyst layer thickness, platinum loading and reactant gas humidity as well as CO poison on the hydrogen electrode behavior are examined. The results show that the catalyst layer thickness has a significant effect on the electrode performance. A thicker catalyst layer will result in a larger ohmic voltage loss and higher catalyst cost. The optimal polymer volume fraction and catalyst layer thickness are 0.5 and 1.5–4 μm, respectively, for this electrode. An optimal platinum surface coverage on carbon need not exceed 20% (20 wt% Pt/C). Larger platinum coverage will increase the cost, but only slightly enhance the electrode performance.     

Lead recovery from aqueous environment by using porous carbon of citrus fruits waste: equilibrium,kinetics and thermodynamic studies

ABSTRACT

The mixture of citrus fruits (orange, grapefruit, mandarin, and lemon) wastes was utilized to obtain high surface area activated carbon (AC) by H₃PO₄ activation. The production conditions were optimized and the optimum conditions were determined. The optimal-activated carbon (CFWAC) was characterized by various physicochemical techniques. CFWAC was also used as a sorbent for Pb (II) ions from water. Batch experiments were performed to explore the adsorption capacity and mechanism. The Langmuir isotherm and pseudo-second-order kinetic model showed good fitness to the experimental data. The maximum Pb (II) adsorption capacity of CFWAC was found to be 163.93 mg/g.     

工业循环冷却水成套节水新技术在天津石化乙烯厂的应用

为解决天津地区水资源短缺的现状，通过应用先进的水处理药剂及自动监控技术，在天津石化公司乙烯厂成功地建成了高浓缩倍率冷却水处理技术示范工程，系统浓缩倍率从3倍提高到5倍以上，年节水量超过60万t。     

建筑供排水用聚丙烯管道(PP-R)特性简析

PP -R管道具有质轻、连接方便、良好耐热性和较小导热系数、耐腐蚀且管道阻力小等优点 ,属绿色产品 ,本文对施工过程中就PP -R管与混凝土的粘结不密、抗紫外性能差等问题提出了相应的处理措施     

莫莱石－堇青石滤料滤池在生产上的应用

本文对景德镇市黄泥头水厂进行了单层莫－堇滤料滤池和双层莫－堇－煤滤料滤池的生产性试验。试验结果表明：单层莫－堇滤池和双层莫－堇－煤滤池的周期产水量分别是单层砂滤池和双层砂－煤滤池的１．４倍和１．５倍，而且前两种滤池的出水水质优于后两种滤池。     

超临界技术处理铁泥制取铁红

铁泥是染料中间体生产中排出的废弃物,其主要物相为Fe3O4.本文以铁泥为原料,运用超临界水氧化法研究了制取氧化铁红的方法.研究表明,经超临界法处理铁泥,通过高温煅烧,可使Fe3O4转化为α-Fe2O3,处理过程中的压力对产品的品质基本没有影响,其品质远远好于铁泥直接煅烧.超临界法处理铁泥制取铁红是一种可行的非常有潜力的技术方法.