铝基金刚石磨轮在陶瓷加工中的应用

Fe基、Cu基、Co基金刚石工具已有大量研究,Al基金刚石工具未见报道.本文采用整体烧结法制备了结合剂组成分别为Al-Sn-Ti、Al-Sn-Ti-Ni-Co、Al-Sn-Ti-Ni、Al-Sn-Ni-Co的铝基金刚石磨轮,分析了铝基金刚石磨轮磨削陶瓷后的显微组织,对比了铝基金刚石磨轮、树脂金刚石磨轮、斜齿金刚石磨轮对不同种类陶瓷砖的修整效果.结果表明:采用A1-Sn-Ti-Ni-Co作结合剂在300℃烧结制备的金刚石磨轮,金刚石出刃高,对陶瓷砖修整效果好,适用砖质广;铝基金刚石磨轮与树脂基磨轮生产成本基本相当,但使用寿命比树脂金刚石磨轮提高3倍以上.     

叶蜡石的矿物成分对合成金刚石的影响

通过对闽东矿区五种不同类型叶蜡石所做的化学分析及DTA、TG分析，计算出了其相应的矿物成分。将这几种叶蜡石分别制成传压介质进行了合成金刚石的实验并与北京门头沟叶蜡石作了比较，结果表明：(1)含有一定量石英(20％左右)的叶蜡石做传压介质有利于降低金刚石合成压力，提高金刚石质量；(2)结晶水含量较低的叶蜡石合成出的金刚石质量更好。作者对实验结果进行了分析并指出：在选择作为传压介质的叶蜡石时，不能只要求其硬度低、叶蜡石成分高，而应全面考虑其中所含矿物成分及其在高温高压下可能发生的变化。     

CoCrPtNb／CrTi／C多层膜记录介质的制备和性能研究

采用CoCrPtNb四元合金作磁记录介质，并采用多层膜结构（CoCrPt）100-Nbx/CrTi／C／Glass制备玻璃盘基硬盘。实验结果表明：采用适宜厚度的籽晶层与合适组分的底层和磁性层的多层膜结构，即使在室温下溅射，此种薄膜磁记录介质也可得到高达260kA／m的矫顽力；在550℃高温下，经过30min真空退火后，其矫顽力有较大幅度提高，并在Nb含量为2．4％（原子分数）时达到极大值386kA／m，适用于高密度磁记录。同时，也详细分析了磁性层和底层组分、籽晶层厚度以及真空退火对磁记录介质磁性能和微结构的影响。     

金刚石颗粒在锯切石材过程中磨损形态的研究

本文分析和归纳了锯切花岗石过程中金刚石颗粒的五种磨损形态和三个磨损阶段，探讨了金铡石颗粒磨损形态对金刚石锯片锯切性能的影响。     

Surface Pretreatments of Silicon Nitride for CVD Diamond Deposition

The efficiency of different surface pretreatments (four standard chemical etchings and four diamond powder abrasive procedures) on silicon nitride (Si₃N₄) substrates for chemical vapor deposition (CVD) of diamond has been systematically investigated. Blank Si₃N₄ samples were polished with colloidal silica (∼0.25 μm). Diamond nucleation and growth runs were conducted in a microwave plasma chemical vapor deposition apparatus for 10 min and 6 h, respectively. Superior results concerning nucleation density ( N _d∼ 10¹⁰ cm⁻² after 10 min), film uniformity, and grain size (below 2 μm after 6 h) were obtained for the mechanically microflawed samples, revealing that chemical etchings (hot and cold strong acids, molten base or CF₄ plasma) are not crucial for good CVD diamond quality on Si₃N₄.     

镀SiO2膜玻璃基片上化学气相沉积法制备SnO2:Sb薄膜

采用化学气相沉积法在镀有SiO2膜的钠钙硅玻璃基片上制备了Sb掺杂SnO2(antimony-doped tin oxide,ATO)薄膜.研究了基板温度、基板输送速度和氮气流量对ATO薄膜结构和性能的影响.用X射线衍射仪、扫描电镜、X射线光电子能谱仪、紫外-可见光谱仪、双光束红外分光光度计对薄膜的结构、形貌和成分进行了表征.结果表明:沉积温度为490 ℃以上时,薄膜主要以四方相金红石结构存在.随着基板输送速度的提高,薄膜择优取向由(110)转变为(200).薄膜中掺杂的Sb以Sb5 的形式存在;当基板温度为530 ℃时,薄膜表面的C没有完全燃尽,以C-O形式存在于薄膜中.薄膜的可见光透过率随基板温度的升高而增大.具有(110)择优取向的薄膜的红外反射性能较好.     

Electrochemical characteristics for redox systems at nano-honeycomb diamond

Electrochemical characteristics for several redox systems at diamond films with highly ordered nanometer-scale cylindrical pores (‘nano-honeycombs’) were examined with cyclic voltammetry (CV) and electrochemical impedance measurements. The cyclic voltammetric anodic-cathodic peak separations for these nano-honeycomb electrodes were in the same range as those for polished polycrystalline diamond films, indicating that the involvement of the oxygen-terminated surface of the nano-pore walls, which should give rise to large peak separations for certain redox couples was only slight. Moreover, the peak currents in the CV were not enhanced to the extent expected on the basis of the roughness factors of the nano-honeycomb films. Ac impedance plots results indicated the existence of a concentration gradient of the reactant in the nano-pores, which is in agreement with theoretical predictions for charge transfer reactions in porous electrodes. The average concentration of the reactant (Fe^2+/3+) inside the nano-pores was a factor of ca. 80 lower than that in the bulk electrolyte. The results of the impedance analysis also indicated an increase in the reaction resistances with decreasing pore diameters.     

人工湿地不同填料去污性能比较

选取页岩、粗砾石、铁矿石、麦饭石及其组合作为人工湿地填料，进行不同基质室内小试污水净化效果研究。结果表明：在相同进水水质和水力负荷运行条件下，单一填料页岩COD、TN、TP去除效果最好，去除率最高分别可达40％、88，9％、87．5％；组合填料COD去除率差别不大，页岩与粗砾石组合TN、TP去除率较高，分别可达到81．7％、71．9％。考虑到填料物理特性及长期稳定运行的需要，可选择页岩与粗砾石组合作为人工湿地去污填料。     

Band Gap Modification of Diamond Photonic Crystals by Changing the Volume Fraction of the Dielectric Lattice

Photonic crystals with a diamond structure of epoxy lattices in which TiO₂-based ceramic particles are dispersed were fabricated by stereolithography. The periodicity of the lattice was designed to reflect electromagnetic waves in the gigahertz range. The volume fraction (β) of the dielectric lattice medium was modified from 14% to 33% by changing the rod diameter of the lattice. The photonic band gap was observed along Γ-L 〈111〉, Γ-X 〈100〉, and Γ-K 〈110〉 directions and the complete photonic band gap was formed at over β= 20%. The width of the forbidden gap increased gradually when the β increased over 14%, and reached 2.4 GHz at β= 33%. These results agreed with the band calculation using the plane wave expansion method.     

PKA国家参考品的制备

本文应用 PKA 微量滴定板方法,用 WHO1984年建立的 PKA 国际标准品进行标定,制备了我国第一批 PKA 国家参考品。