Adhesion Mechanisms of Polyurethanes to Glass Surfaces I. Structure-Property Relationships in Polyurethanes and Their Effects on Adhesion to Glass

Polyurethanes were prepared from toluene diisocyanate (TDI), 1-4-butane diol (BDO) and polycaprolactone-based triols with varying molecular weights. Among each molecular weight triol-based urethane, hard segment content was varied from 20% to 70%. Differential scanning calorimetry, tensile testing, and Iosipescu shear testing were done on all the various urethanes prepared. Thermal characterization data revealed the dependence of phase separation on hard segment content as well as on the triol molecular weight. Tensile data and Iosipescu shear data further confirmed the observations made from the DSC data. The data further indicated that phase separation can greatly improve the modulus of cross-linked segmented urethanes. Adhesion of these urethanes to glass surface was evaluated using soda-lime float glass plate. Urethane samples were cast on the air side of the glass plates and adhesion was measured in shear mode. Adhesion data indicated that in addition to hard segment content, modulus, cross-link density, and molecular weight of the triols, phase separation seems to be a major factor in controlling adhesion. Surfaces of the failed adhesion samples were also analyzed and the failure mode was found to be cohesive, in varying degree, with the different urethane systems.     

Effects of Sr/Ti-ratio in SrTiO3-based SOFC anodes investigated by the use of cone-shaped electrodes

In this work the A-site deficiency limit for undoped SrTiO₃, calcined in air or reducing atmosphere, was investigated. XRD and SEM analyses showed that when using the solid-state synthesis route it was difficult to achieve any A-site deficiency. Even very small deviations from unity in the Sr/Ti-ratio resulted in impurity phases. The effects of Sr/Ti-ratio on the performance of SrTiO₃ anodes for solid oxide fuel cells (SOFCs) was investigated by impedance spectroscopy with cone-shaped electrodes. The electrocatalytic activity of the SrTiO₃ cone samples, with various amount of reduced titanium dioxide phases (Magnéli phases), was investigated for oxidation of H₂ at 700 °C. High temperature treatment at 1000 °C, between the measurements at 700 °C, showed that high content of Magnéli phases leads to faster degradation of the activity. The suitability for using cone-shaped electrodes as a tool for investigating electrode materials is discussed.     

软段含离子基团的阴离子型水性聚氨酯胶粘剂的研究(Ⅱ)——硬段结构的影响

以含有不同离子基团的聚酯多元醇为软段,采用丙酮法合成了一系列水性聚氨酯乳液。研究了不同硬段结构和硬段含量和扩链剂对其干膜物理机械性能和吸水率的影响。     

Li_20对AlN陶瓷低温烧结的影响

利用XRD,SEM和TEM研究了Li2O-CaF2-Y2O3体系在/AlN陶瓷低温烧结中的作用机理,研究发现,添加Li2O的/AlN陶瓷有着更低的收缩开始温度和更大的收缩率,这种收缩来自于含Li玻璃相与CaYAlO4液相的共同作用。在烧结过程中,Li2O不仅改变了AlN烧结过程中的相组成,而且改善了液相的性质。由于Li2O和Al2O3在l 100℃以下反应生成含Li玻璃相,使得AlN开始收缩的温度大为降低。在1 600℃以上,含Li玻璃相分解散失,有利于AlN晶界的纯化,同时,CaYAl3O7向CaYAlO4的转变以及液相CaYAlO4在烧结过程中稳定存在,保证了含Li玻璃相散失后AlN的持续收缩。     

PVC／FRP界面胶粘剂的研制

本文对ＰＶＣ／ＦＲＰ界面胶粘剂的粘接机理，材料选用及配方进行了探讨，最终给出了理想的粘接剂配方。     

影响聚氨酯弹性体紫外线稳定性的因素

介绍了聚氨酯弹性体在紫外线照射下发生光老化的反应机理及其软段、硬段种类和结构对弹性体紫外线稳定性的影响,探讨了光稳定剂、光屏蔽剂对弹性体耐紫外线稳定性的影响。     

基于虚拟磁盘的携带型操作系统加密方案

针对移动硬盘的加密系统分区无法被正确辨识而导致误格式化的问题,应用文件系统过滤驱动技术,结合硬盘主引导程序及分区表机理,对现有的基于虚拟磁盘的移动硬盘加解密方案进行了改进,在加密分区包含可运行操作系统的情况下,增加了盘符自动隐藏及恢复的功能。以开源加密软件Truecrypt为例,利用安装了视窗操作系统的固态移动硬盘进行测试。结果表明,在不影响加密操作系统正常运行的同时,盘符自动隐藏及恢复功能避免了用户的误格式化操作,从而提高了移动硬盘加密系统分区的安全性和隐蔽性。     

纤维素衍生化手性固定相的制备和对噻吗洛尔拆分

用超声方法合成了三(3,5-二硝基苯甲酰基)纤维素(CTNB)、三(4-溴苯甲酰基)纤维素(CTBB)、三(苯甲酰基)纤维素(CTB)、三(4-甲基苯甲酰基)纤维素(CTMB)、三(4-硝基苯甲酰基)纤维素(CTPB).将此类衍生化纤维素作为薄层色谱的手性固定相,结合展开剂的优化,对噻吗洛尔对映体进行拆分研究,并对衍生化取代基对拆分效果的影响以及对映体在手性固定相上的拆分机理进行了详细的探讨.     

热力学稳定纳米层状陶瓷——M_(N+1)AX_N三元化合物

本文概要地介绍了一种新型热稳定纳米层状陶瓷——MN+1AXN相的结构、性能和 应用前景。MN+1AXN相为层状六方结构,能导电、导热。其维氏硬度一般在2—5GPa之间,具 有良好的抗热震性和低摩擦系数,并且易于加工。温度较高时,在空气中会发生氧化。     

Application of the Stepwise-Regression Method in Calculating High-Temperature Ceramic Phases

Phase calculation for nonequilibrium multicomponent systems is attempted using the stepwise-regression method. The experimental data (the amount and composition of glassy phase in a system of Al₂O₃–SiO₂ ceramics as functions of the state of the original materials, the firing temperature, and the composition of the samples) are treated by the proposed method. The equations obtained are accurate in estimating the amount and composition of glassy phases in the system, showing that the stepwise-regression method is effective in phase calculation.