Effect of Si addition to CrN coatings on the corrosion resistance of CrN/stainless steel coating/substrate system in a deaerated 3.5 wt.% NaCl solution

CrSiN coatings with different Si concentration (Si/(Cr + Si) ratio: 0, 3.7, 11.7, 20%) were deposited on stainless steel substrates using a closed field unbalanced magnetron sputtering (CFUBM) system. The variation in the microstructure of the films with the Si concentration was measured by XRD. The corrosion behavior of the CrSiN coatings in a deaerated 3.5% NaCl solution was investigated by potentiodynamic tests, electrochemical impedance spectroscopy (EIS) and surface analyses. The microstructure of the CrSiN film was found to depend on the Si concentration. The results of the potentiodynamic polarization tests showed that the corrosion current density and porosity decreased with increasing Si/(Cr + Si) ratio. The EIS measurements showed that the corrosion resistance of the Si-bearing CrN was improved by the phase transformation of the film, which led to an increase in the pore resistance and charge transfer resistance. The Si-bearing CrN possesses the best corrosion resistance at a Si/(Cr + Si) ratio of 20%, measured by the maximization of the pore resistance and charge transfer resistance.     

40CrNiMo钢轴开裂原因分析

通过对40CrNiMo钢轴取样进行化学成分分析、硬度检测和金相高低倍观察,结合钢轴断口形貌检验,分析讨论了钢轴产生开裂的原因,并针对原因提出了改进措施。结果表明:芯部存在较严重的带状组织偏析是导致钢轴开裂的主要原因,调质热处理过程中形成的上贝氏体进一步降低了材料性能,促进了裂纹形成和扩展。     

SEBF/SLF系列重防腐涂料的特性和分析

本文介绍2种SEBF熔融结合环氧粉末涂料和2种SLF双组份液体涂料,辽宁的物理和化学性能及部分测试和评价方法.     

The Structure Stability of Carbide-Free Bainite Wheel Steel

Metallographic structures of carbide-free bainite steel wheel rim are mainly composed of supersaturated lath ferrite and retained austenite film among bainitic ferrite laths. It is suspected that supersaturated ferrite and retained austenite are likely to decompose under the influence of temperature change and mechanical stress. Stability of wheel rim structure is studied by means of x-ray diffraction, dye microscopy, and micro-hardness test. When the samples are tempered in the range of 150-350 °C, the retained austenite films are at the state of relative stability. Fifty percent of retained austenite is decomposed when the sample is tempered at 400 °C. Microhardness increases when the sample is tempered at 150 °C. The decrease in hardness is mild when the samples are tempered from 200 to 500 °C. The mechanical stability of retained austenite film is studied with tensile sample under the effect of tensile stress. The retained austenite appears to be stable in low and middle degree of deformation, and decomposition occurs at great amount of deformation. Diffraction peak of carbide is not found in all above experiments. The steel enriched silicon prevents the carbide precipitation during the transformation. It indicates the carbide-free bainite wheel steels have an excellent thermal and mechanical stability.     

等离子喷涂参数对Ta／W／Sn复合涂层组织性能的影响

采用等离子喷涂方法在LY12铝上制备了Ta/W/Sn复合涂层。研究了各种工艺参数对涂层材料熔化程度和沉积效率的影响。采用扫描电子显微镜观察了复合涂层的表面及界面，精密机械天平称量涂层的增重，力学拉伸机测量涂层的抗拉结合强度，能谱和化学方法分析涂层的化学成分。结果表明，等离子喷涂工艺可以制作组织致密，厚度均匀的Ta/W/Sn复合涂层；喷涂功率和送粉速率对材料的熔化状态影响较大，在特定喷距范围内喷距的影响则较小。     

The application of thermal sprayed coatings for pig iron ingot molds

Molds made of gray cast iron for casting pig iron ingots are subjected to severe temperature fluctuations. The main life- limiting factor for mold damage is the formation of surface cracks arising from thermal fa-tigue. Various flame and plasma sprayed coatings were investigated to extend the life of these molds. Coating materials studied include plasma sprayed ceramic coatings with bond coats as well as flame sprayed oxidation- resistant alloy powders. The results of cyclic furnace tests from room temperature to 1100 °C in air, simulating the thermal cycle in casting, indicated that failure occurred along the interface between the bond coat and the gray iron substrate because of iron oxidation, and not at the interface between the ceramic top coat-ing and the bond coating for a superalloy substrate. The field test results indicated that plasma sprayed alumina coatings with 200 μm top coating thickness are the most promising materials for pig iron casting.     

High-temperature oxidation of aluminum electroplated Fe-Mn alloys

Austenitic Mn-Al alloys (20–32 W/O Mn, 7–10 Al, 2–3 Si, 1C) were found to have satisfactory oxidation resistance up to 950°C under isothermal conditions in air. Surface enrichment of aluminum is a necessary condition for obtaining an almost pure alumina scale for uses at higher temperatures. Four different Mn-steels were Al-coated by the Capuano electroplating process. In all the steels there was an increase in the hot-oxidation resistance. The best results were obtained with steels containing both Al and Si, and this for temperatures up to 1100°C. No spalling was noticed during rapid cooling of the test pieces. Silicon was found to act as a diffusion barrier to outward iron diffusion. It appears that there is formation of a pure, thin film of alumina from the matrix which interacts with the aluminum diffusing from the superimposed, coating for the formation of good bonds.     

涂层的感应重熔工艺

本采用磁性测试、差热分析、扫描电镜、Ｘ射线衍射等现代化测试手段，对国产自熔合金粉末Ｆｅ６０和Ｎｉ６０喷涂层的感应重熔工艺性进行了大量试验研究，得出试验采用的自熔合金粉末是顺磁性材料，喷涂层的磁性质是影响感应重熔工艺性的关键因素的结论，提出涂层感应重熔工艺性取决于试件上温度场分布，而试件上温度场分布主要取决于涂层材料磁性质的观点。     

舰船防腐涂料与涂装

根据舰船各部位的具体使用要求,确定了常用舰船配套体系和涂装方案,阐述了舰船涂料的主要发展趋势是向着高性能、易施工、经济、节能和环保的方向发展。     

高辐射耐热涂层的研制

阐述了一种具有高辐射和耐高温性能的涂层，它可用于铁路的红外轴温探测系统，以提高该系统红外线(红外热量)的辅出度。介绍了涂层的制备工艺及其指标数据的测定原理及方法，分析了影响涂层耐热性及热辐射性能的众多因素。