多媒体技术在化学教学中应用的探讨

文中介绍了多媒体教学的发展及多媒体课件、文献资料和仿真实验等教学的基本形式;分析了多媒体教学所具有的信息量丰富、表现力多样化、交互性较强和内容更新快的特点;讨论了多媒体教学可提高教学效率、提高学生理解能力、减轻教师负担和因材施教的优越性;提出了在教学中应用多媒体技术时,应以学生为主体,教师为主导,为学习者提供认知帮助是关键而有效策略的教学思想。     

未确知数学在化学实验中的应用

本文通过实验并运用未确知数学的方法确定气体常数Ｒ，此法不仅给出Ｒ所在的区间，而且可根据可信度密度确定最可靠的Ｒ值     

Lifetime and ageing management of nuclear power plants: A brief overview of some light water reactor component ageing degradation problems and ways of mitigation

The susceptibility and tendency for nuclear power plant (NPP) components to undergo changes in their mechanical and physical properties in the course of the NPP lifetime is generally termed as “ageing”. The light water reactor (LWR) nuclear environment is not a begnign one; it is characterized not only by fast neutrons, which can degrade metallic structures, but also relatively high temperatures of coolant water (around 300°C) which may contain impurities (e.g. sulphate, chloride, peroxides) which can cause corrosion. The hydrodynamical conditions of the coolant in steam generators, for example, can cause thermal fatigue, erosion and corrosion; suspended particulate matter can accelerate erosion processes which can lead to wall thinning and lowering of safety margins. Ageing is, therefore, a very complex mixture of factors concerned with materials, temperatures, times of exposure to environments which vary with time and with respect to chemical composition and flow charactertistics.

The paper describes a few ageing phenomena which can be considered important due to their impact on nuclear safety issues; their influence on economic aspects (availability) of NPP is outlined. Mitigation measures for NPP component ageing problems are given together with recommendations for addressing such issues in NPP now and in the future.     

Contact interaction of double titanium and chromium diboride with Fe-Cr alloys

The kinetics of wetting double titanium and chromium diboride by iron-based alloys with different chromium content is studied. It is shown that contact angles are formed in such systems over the range 0–10°. The energy parameters of wetting are calculated. It is established that chromium as a surface-active element promotes Fe-Cr alloy spreading on the diboride surface. The microstructure of the interaction area is studied. It is shown that terminal solid solutions and eutectics are formed in the TiCrB₂-(Fe-Cr) system. The optimum compositions of the metallic binder are determined for TiCrB₂-based composite materials. __________ Translated from Poroshkovaya Metallurgiya, Vol. 46, No. 1–2(453), pp. 109–115, 2007     

VNS反应合成LLM-116

以1,3-二硝基吡唑为原料,经热重排、氨气中和得到3,5-二硝基吡唑铵盐,然后酸化得到3,5-二硝基吡唑。以三甲基肼碘化物（TMHI）作为异常亲核取代氢（VNS）反应试剂,与3,5-二硝基吡唑在叔丁醇钾为催化剂,利用VNS反应合成4-氨基-3,5-二硝基吡唑（LLM-116）。采用红外分析、核磁共振、元素分析等仪器鉴定了其结构,讨论了VNS反应机理及影响因素。通过实验,得出最佳VNS反应试剂为TMHI,反应时间为4h,反应温度为25℃,收率达到60%。     

LiMn2O4纳米粉的湿化学合成与表征

采用湿化学方法，通过水溶液中的化学反应直接合成纳米级LiMn2O4化合物，其结构基本上为无定型，但XRD图谱中已出现LiMn2O4特征峰，说明在水溶液中已初步形成尖晶石结构，运用XRD，SEM，TG－DTA等现代检测手段对样品的性能进行进行了表征，XRD及SEM等分析结果表明，合成样品经简单热处理后，晶型结构完善，形貌规整，均匀，比表面积积显著减小，粒度明显变粗。TG－DTA热分析证明，样品在低于900℃的温度下进行热处理时，仅发生LiMn2O4的晶化过程，产物的化学组成稳定，该法合成锂离子电池正极材料LiMn2O4，具有工艺流程简单，产物的成分，结构及粒度均匀等特点。     

国有化工流通企业的现状分析与发展对策

通过对国有化工流通企业现状的分析。了解其在计划经济与市场经济中的不同表现，并试图找到阻碍其生存与发展的症结所在，提出国有化工企业生存与发展的对策。     

缺陷交互作用对陶瓷半导体导电性能的影响

本文借助于缺陷化学反应过程，分析了陶瓷半导体内缺陷间的交互作用，得到了陶瓷半导体实验研究的三个重要启示：（1）强还原（或氧化）或施主（或受主）掺杂对同一样品不能同时起到最佳效果；（2）本征原子空位对施主或受主的补偿导致电导率的非线性增长；（3）缺陷的缔合降低了半导化杂质的有效浓度，从而使电导性能发生异常变化。