Development and Commercial Application of a Novel Catalyst DVR—1 for Catalytic Cracking of Daqing Vacuum Residue

A newly developed catalyst type DVR-1 for catalytic cracking of Daqing vacuum resid was put into use in a commercial VRFCC unit,This catalyst features uniquely active matrix and modified ultra-stable zeolite.The commercial application results show that the DVR-1 type catalyst has the advantage of high heavy oil conversion,good metal tolerance nd gooed stability for catalyst regeneration,The FCC tests have shown Favorable product distribution,acceptable product quality and enormaous economic benefits whe processing the feedstock containin 75%-100% Daqing VR.     

乙炔在磁稳定床中的选择性加氢研究

 制备了一种磁性Pd/Al₂O₃催化剂，采用磁稳定床考察了活性组分负载量、反应条件及CO浓度对乙炔加氢反应性能的影响。结果表明，当反应温度80℃、反应压力1.5MPa、空速9000h－1、磁场强度（H）25kA/m时，乙炔转化率为100％，乙烯选择性可达81％，具有优良的乙炔加氢活性和乙烯选择性，优于相同反应条件下的进口催化剂；250h稳定性实验结果表明，磁性Pd/Al2O3催化剂具有良好的初活性和乙烯选择性，催化剂性能稳定。     

Poly-functional Catalyst Development for Benzene Production from Alkyl-aromatic Mixture via Hydrodealkylation

Development of a poly-functional catalyst that has higher hydrodealkylation activity based on 15% Cr/γ- Al₂ O₃ was researched for benzene production from an alkyl-aromatic mixture via hydrodealkylation. For this goal, the effects of the promoters like Fe, Co, or Ni and their concentrations on the activity of a Cr/Al₂ O₃ catalyst were investigated. Toluene + n-heptane + tetrahydrotiophene (89:10:1 w%) model mixture, which has the same content as industrial aromatics, was used as feedstock. The activities of catalysis in reactions of hydrodealkylation, hydrocracking, and hydrogenolize with respect to conversions of toluene, heptane, and tetrahydrotiophene were tested, respectively. As to the obtained results, the catalyst including 5% Fe has a higher hydrodealkylation activity, compared to the catalyst including Co, and especially to the alumocrom catalyst not including a promoter, while it has a lower coke formation and reduced activity to the catalyst including Ni.     

负载化非茂单活性中心催化剂乙烯聚合的研究

在硅胶上负载了双(N-环己基-3-叔丁基水杨醛亚胺基)二氯化锆配合物,得到负载化非茂单活性中心催化剂。该催化剂用于乙烯聚合,考察了配合物用量、共聚单体1-己烯用量、聚合温度、聚合压力、聚合时间、三乙基铝用量对乙烯聚合性能的影响及对聚合物的相对分子质量、相对分子质量分布、熔体流动指数和密度的影响。实验结果表明,负载化非茂单活性中心催化剂保持了原均相催化剂的乙烯聚合性能;该催化剂在淤浆聚合工艺中聚合平稳,所得聚合物的颗粒形态良好。     

催化裂化技术现状及发展趋势

详述了国内外最新渣油催化裂化、多产柴油催化裂化、低碳烯烃催化裂化、生产清洁燃料催化裂化及催化剂的技术进展，同时根据我国实际情况对今后催化裂化技术的发展提出了建议。     

磷铝杂原子固体酸催化剂催化合成乙酸异丙酯

以丙烯和乙酸为原料 ,自制的磷铝杂原子固体酸作催化剂催化合成了乙酸异丙酯 ,考察了反应温度、反应压力、反应空速 (LHSV)及催化剂用量对酯化反应的影响 ,同时考察了固体酸催化剂的重复使用性。确定了最佳合成条件 :反应压力 1 5MPa,反应温度 1 60℃ ,反应空速2 0h-1,催化剂用量 2 0g。在此条件下 ,酯化率可达 91 5 % ,乙酸异丙酯选择性达 99 0 % ,且催化剂的重复使用性良好。     

利用含钨废催化剂生产钨酸工艺实践

较为详细地阐述了利用含钨废催化剂生产钨酸的工艺流程、各工序反应原理及其操作实践、产品质量情况、原辅材料单耗等。实践证明 ,本工艺具有显著的经济效益和社会效益、环保效益     

合成直链烷基苯环境友好固体酸催化剂的研究 Ⅲ .催化剂失活原因分析

采用固定床反应器,对催化剂的稳定性进行了初步评价。在120℃、空速相同、液固反应条件下,高苯烯比时催化剂的稳定性明显高于低苯烯比时;在苯烯比和空速相同、液固反应条件下,相对低温反应时,催化剂的稳定性明显高于高温反应。IR分析结果表明,同新鲜和反应后未失活的催化剂相比,失活后催化剂的活性组分特征衍射峰消失,出现的新的特征衍射峰可能同—CH基的振动有关。TG分析结果表明,失活后催化剂在空气流中焙烧,失重幅度比新鲜催化剂大。     

改性Raney Cu催化一乙醇胺脱氢合成甘氨酸

一乙醇胺在氢氧化钠的水溶液中〔w(NaOH)=12%～18%〕,用含有铬和锗等贵金属改性的RaneyCu催化剂脱氢合成甘氨酸。反应温度150～180℃,反应压力0 8～1 2MPa,反应时间2～4h。实验结果表明:改性RaneyCu催化剂比普通RaneyCu有更好的活性和使用寿命,使一乙醇胺的平均转化率从92%提高到97%,有效使用寿命(一乙醇胺的转化率≥90%)从5次延长到15次以上。     

甲烷催化部分氧化催化剂研究进展

综述了国内外甲烷催化部分氧化催化剂在载体、助剂、活性组分及制备方法等方面的研究进展，以对改善催化剂的抗积碳性、提高催化剂的稳定性和选择性提供参考。