H62/Cu同基合金磁控电弧离子镀镀层显微组织

用扫描电子显微镜和能谱仪对H62/Cu同基合金磁控电弧离子镀镀层进行了研究.结果表明,电弧离子镀电流对镀层晶粒尺寸有较大影响,弧电流较小时镀层晶粒较细,而弧电流较大时镀层的晶粒粗大.镀层主要由3部分组成:过渡层(伪扩散层 真扩散层)、细晶层和蘑菇状晶粒层.镀层中铜、锌元素分布不均匀,造成这种现象的原因与铜、锌的熔点及其离子的电离能有关.     

"KQDL系列冲天炉"成果研讨

针对冲天炉,冷风炉、热风炉、水冷却炉存在的问题试制出了"KQDL系列冲天炉".论述了"KQDL系列冲天炉"采用空气冷却、强化预热、单排龙卷风供风原理和特点.通过生产实践与传统冲天炉的比较,认为这种新型冲天炉可给企业带来明显的经济效益,同时可使铁水质量明显提高,这种新型冲天炉有很高的性价比,可使冲天炉的设计更上一层楼.     

INTERFACIAL REACTIONS OF METAL FILMS WITH AlN SUBSTRATE

ＩＮＴＥＲＦＡＣＩＡＬＲＥＡＣＴＩＯＮＳＯＦＭＥＴＡＬＦＩＬＭＳＷＩＴＨＡｌＮＳＵＢＳＴＲＡＴＥＨｅＸｉａｎｇｊｕｎ；ＴａｏＫｕｎ；ＦａｎＹｕｄｉａｎ（ＤｅｐａｒｔｍｅｎｔｏｆＭａｔｅｒｉａｌｓＳｃｉｅｎｃｅａｎｄＥｎｇｉｎｅｅｒｉｎｇ，Ｔｓｉｎｇｈ...     

不锈钢基厚膜PTC热敏电阻浆料的制备与性能研究

以二氧化钌和氧化铜的混合物为功能相制备出不锈钢基厚膜PTC热敏电阻浆料.研究了功能相与玻璃相的配比、功能相的粒度对厚膜电阻方阻及电阻温度系数(TCR)的影响规律.结果表明:固定浆料中玻璃相的成分与含量(30wt%),控制功能相中RuO2的比例(45.4wt%～88.9wt%)或功能相的粒度(0.30～1.0μm),可制得具有不同方阻(1.5～12.8Ω/□)和TCR(2100～2900×10-6/℃)的厚膜PTC热敏电阻.     

基板温度对PVD薄膜分维的影响

采用动态蒙特卡罗（KMC）方法研究物理气相沉积（PVD）制备薄膜过程中基板温度对薄膜微观结构的影响，并用分维理论研究薄膜表面的复杂程度。该KMC模型中既包括入射原子与表面之间的碰撞，又包括被吸附原子的扩散。模拟中用动量机制确定被吸附原子在表面上的初始构型，用分子稳态计算（MS）方法计算扩散模型中跃迁原子的激活能，用红黑树选择跃迁路径并更新系统跃迁机率。研究结果表明：基板温度大于500K时，薄膜表面分维均小于2．04，表面光滑，而当基板温度小于500K时薄膜分维随基板温度降低而增大，表面随基板温度升高变得越来越粗糙，直到基板温度降到250K时，分维达到最大的稳定值2．32，表面情况非常复杂，具有细致的皱褶和缺陷。分维与基板温度之间的关系说明高基板温度有利于分维小、表面光滑薄膜的制备，而低基板温度使薄膜分维增大、表面结构更加复杂。该研究结果与基板温度对PVD薄膜表面粗糙度影响的研究结果趋势上一致，分维能更细致地评价薄膜表面的复杂程度。     

Numerical simulation of temperature field during gas preheating and start-up of drained aluminum reduction cell

1 Introduction The drained aluminum reduction cell is a new type cell and it is predicted that it can reduce the voltage of the cell 0.6 V and save the consumption of direct current 2400 kW?h/t, compared with the general cells[1,2]. Therefore, more and m…     

Au-Ni-Kovar合金系统基底元素表面偏聚的SAM和XPS研究SCIEI

本文采用SAM和XPS对实用Au-Ni-Kovar合金系统热处理样品(250—350℃,0.5—1.5h)进行了基底元素穿透Au层的表面偏聚研究,给出了这一复杂系统中Ni,Co表面偏聚机理的直观证据,即Ni,Co主要是通过晶界扩散穿透Au层而后以表面扩散覆盖镀Au表面的;表面偏聚元素化学态的研究则不仅表明,氧的吸附和氧化反应是Ni,Co表面偏聚的驱动力,而且发现,上述偏聚会引起样品表面吸水的现象。     

Quenching stress in plasma sprayed coatings and its correlation with the deposit microstructure

Quenching stress arises within a thermally sprayed splat as its thermal contraction after solidification is constrained by the underlying solid. Dependence of the quenching stress in plasma-sprayed deposits of Ni-20Cr alloy and alumina on the substrate temperature during spraying was discussed in conjunction with the change in the nature of the interlamellar contact between splats. It was found by mercury intrusion porosimetry and observation of cross sections of impregnated deposits that the interlamellar contact is improved significantly by raising the substrate temperature during deposition from 200 to 600 °C. The positive dependence of the quenching stress on the substrate temperature in this temperature range was attributed to a stronger constraint against thermal contraction of sprayed splats after solidification due to the improved contact.     

Splash Splat to Disk Splat Transition Behavior in Plasma-Sprayed Metallic Materials

A variety of metallic powder particles were thermally sprayed onto the mirror polished metallic substrate surface and the effect of both substrate temperature and ambient pressure on the flattening behavior of the particle was systematically investigated. In the flattening behavior of the sprayed particle onto the substrate surface, critical conditions were recognized both in the substrate temperature and ambient pressure. That is, the flattening behavior changed transitionally on that critical temperature and pressure range, respectively. A transition temperature, T _t, and transition pressure, P _t, were defined and introduced, respectively for those critical conditions. The fact that the dependence of both transition temperature and transition pressure on the sprayed particle material had similar tendency indicated that the wetting of the substrate by the molten particles seemed to be a domination in the flattening. Three-dimensional transition curvature by combining both transition temperature and transition pressure dependence was proposed as a practical and effective controlling principle of the thermal spray process. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.     

Flame-Sprayed Glaze Coatings: Effects of Operating Parameters and Feedstock Characteristics Onto Coating Structures

Many substrates do not sustain the conventional glazing process (i.e., vitreous glazing) due to the relatively high temperature required by this treatment (i.e., up to 1400 °C in some cases) to fuse glazes after their application on the surface to be covered. Flame spraying could appear as a solution to circumvent this limitation and to avoid thermal decomposition of substrates. This contribution describes some structural attributes of glaze coatings manufactured by flame spraying. It also discusses the influence of the feedstock powder morphology and some of its physical properties on coating characteristics. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.