合金元素对镁合金的性能影响研究

研究了新型镁铝锌合金的性能,分析了不同含量的Al、Zn、Pb等元素对镁合金性能的影响.结果表明,随着Al含量的增加,合金的冲击韧性下降而硬度提高;随着Zn含量的增加,冲击韧性和硬度都下降;而随着Pb含量的增加,合金的冲击韧性和硬度都提高.     

New high-temperature copper alloys

New high-strength, high-temperature Cu-Ni-Si alloys have been developed using additions of Cr, Zr, and/or Ti. These new alloys remain as precipitation hardenable as the base alloy, but the main strengthening phase may be different than Ni₂Si (e.g., Cr₂Ti). Substantial increases in mechanical strength were observed at both room and high temperature (773 K) when additions of Cr+Zr+Ti and Cr+Zr were made. Industrial testing of these alloys indicated a sevenfold increase in the lifetime of lateral blocks in continuous casting equipment of copper alloys.     

20SiMn2MoV合金结构钢的低温冲击性能

针对石油钻采设备的服役条件，考察了20SiMn2MoV合金结构钢在-60℃-20℃内的冲击性能以及热处理工艺、毛坯尺寸等因素的影响。试验结果表明，20SiMn2MoV钢的冲击性能在试验温度范围内随温度降低而逐渐下降。在低温（略高于Ac3）淬火＋高温回火时，毛坯尺寸对冲击性能的温度依赖性有显著影响，毛坯尺寸越大，冲击性能随温度下降而降低的变化率越高。在高温淬火＋低温回火时，20SiMn2MoV钢表现出较低的冲击性能，但温度对冲击性能的影响相对较小。适当降低淬火温度，提高回火温度有利于改善20SiMn2MoV钢的冲击性能。冲击断口分析表明，断口上存在着团簇状的碳化物和氧化物颗粒及其脱落后而形成的孔洞，对于钢的冲击性能产生不利影响。     

Effects of CeF3 on properties of self-shielded flux cored wire

0 IntroductionSelf-shielded flux cored wire is a newly developedwelding material used without gas protection. Use of suchcored wires has grown rapidly in developed countriesbecause of the following advantages: simple use, goodwind resistance ability, lower cost resulted from highproductivity and strong desulfurization ability[1]. Self-shielded flux cored wires are preferred for on-site weldingsuch as ship and barge building, storage tank, bridge,offshore oil platform buildings and so on[2 -3].…     

淬火工艺对Fe-V-W-Mo合金组织和性能的影响

在测试了Fe-5％V-5％W-5％Mo-5％Cr-3％Nb-2％Co-2％c（Fe-V-W-Mo）合金的临界点和CCT曲线基础上，研究了淬火温度、淬火冷却方式对该合金组织和性能的影响。研究结果表明，Fe-V-W-Mo合金油冷淬火温度低于1025℃。随淬火温度升高硬度升高，超过1050℃，硬度反而降低。雾冷和空冷淬火时，淬火温度对硬度影响结果相似，获得最高硬度的淬火温度高于油冷时的淬火温度。Fe-V-W-Mo合金油冷淬火淬透性最好，雾冷次之，空冷最差，但是油冷和雾冷差别不大。Fe-V-W-Mo合金红硬性和韧性随淬火温度升高而提高，超过1150℃时，韧性反而降低。最后讨论了Fe-V—W—Mo合金在不同淬火冷却条件下组织和性能变化的原因。     

Carboxyl‐terminated butadiene–acrylonitrile rubber modified cyanate ester resin

The carboxyl‐terminated butadiene‐a‐acrylonitrile rubber (CTBN) has been proved to be the most effective toughener for cyanate ester (CE) resin. This work mainly focuses on the different modification effects caused by the addition of CTBN with different acrylonitrile content. The phase separation, morphology of fracture surface, and physical properties of the blends are studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), dynamic mechanic analysis (DMA), and thermogravimetric analysis (TGA). It is testified that the compatibility and toughness between CE and CTBN had a positive correlation with the acrylonitrile content of CTBN. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

A study on the effect of new cyanate and phenoxy polymer on TGDDM/DDS/GMP formulations

An attempt was made on the modification of the tetraglycidyl‐4,4′‐diaminodiphenyl methane/diaminodiphenyl sulfone (TGDDM/DDS) system to improve properties for several industrial applications. Epoxy resins [TGDDM and 1‐glycidyloxy‐4‐methoxy phenol (GMP)] were synthesized in the laboratory. Also, a new cyanate ester and phenoxy polymer were synthesized and characterized by FTIR, ¹H‐/¹³C‐NMR, and thermal studies. GMP was added as a diluent and a new cyanate ester (DCDPT) was introduced to reduce the tight crosslinking density. Further, a new phenoxy polymer was added to improve the toughness property. A variety of neat resin casts using different compositions of the blends were made and their physical, chemical, thermal, and mechanical properties were evaluated to study the effect of GMP as a diluent, cyanate ester as a comonomer, and phenoxy polymer as a toughener. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2963–2973, 2003     

有机硅改性三聚氰胺甲醛树脂的研究

合成了有机硅改性的三聚氰胺甲醛树脂。采用正交实验方法研究了有机硅添加量、聚乙烯醇添加量、三聚氰胺/甲醛比例3种因素对树脂断裂伸长率的影响;采用红外光谱和热失重分析法对试样进行了测试。结果表明,有机硅的加入确使树脂的韧性有所提高,但是对树脂的耐热性能有一定不良影响。     

The effect of specific β‐nucleation on morphology and mechanical behavior of isotactic polypropylene

The commercial grade of isotactic polypropylene was modified by a specific β‐nucleating agent in a broad concentration range. The supermolecular structure of the specimens prepared by injection molding was characterized by X‐ray scattering and correlated with mechanical behavior. It was found that at a critical nucleant concentration of 0.03 wt % the content of the β‐modification virtually reaches a saturation level. With further addition of the nucleant, the β‐phase content increases only slightly. The long period passes through a distinct maximum at the same nucleant concentration. This singularity in structure remarkably correlates with a minimum of the yield stress and maxima of strain at break and fracture toughness. Such general behavior is also reflected in the correlation between the β‐phase concentration and fracture toughness profiles along the injection‐molded bars. It is suggested that in the critically nucleated material an optimum thickness of the amorphous interlayer with connecting chains between the β‐crystallites is established, rendering the material the highest possible ductility and toughness. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1174–1184, 2002     

On Modulus and Fracture Toughness of Rigid Particulate Filled High Density Polyethylene

A Kaolin-filled, high-density polyethylene (HDPE) system was used to illustrate the influence of particulates on modulus and toughness of the bulk material. A variation of filler content, particulate size and coupling quality for two HDPE-matrix systems with different viscosity led to a strong dependency of elastic modulus and fracture toughness under various testing conditions, e.g. static loading, fatigue and impact.

A stiffness improvement with increasing filler content was achieved by all coupling qualities. The developed Kaolin reinforcement of HDPE with optimised coupling offers an improvement of the stiffness and toughness under all investigated loading conditions. The degree of improvement depends on the particulate size and matrix viscosity. The energy dissipation mechanisms were investigated by fractographic analysis.