电渗模型电阻测量技术

本文对电渗模型中电阻测量方法进行了改良,提出串联法代替当前的电势测针法和夹具法,并提出了适用于测量EKG电极电阻的走线法。串联不同长度的电渗土体测量电极与土体间的接触电阻消除了电势测针法中测针与电极之间一段土体电阻值的误差影响,同时避免了电势测针插入土壤对土壤电流分布的影响;串联不同长度的电渗电极测量电极电阻率时消除了夹具法测量时夹具和电极之间接触电阻的误差影响。经试验结果表明：电势测针法所得的接触电阻与串联法得到的接触电阻比值大多在1.3~1.4之间,验证了电势测针法将测针与电极间的一段土体值计入了接触电阻造成所测得的接触电阻偏大,该值的大小取决于该段土体电阻值;串联法对于当前应用广泛的EKG电极并不适用,提出了走线法来测量EKG电极电阻率消除电极板内因嵌入铜制导线电流分布不均的影响,走线法测量结果基本不受电极长度的影响,具有良好的可靠性和稳定性,走线法测量便捷,方便应用于EKG电极生产工艺中,有比较广阔的应用前景;走线法测量EKG电极所得的电阻率与夹具法得到电阻率的比值大多在8%~10%之间,该比值主要与夹具电极板间的接触电阻相关,夹具和电极板之间的接触电阻仅取决于夹具和电极板,故可利用该比值对先前使用夹具法的测量结果进行修正,在许多室内试验和工程中均用到了EKG电极,考虑EKG电极电阻率对整个试验和工程的能耗影响时可参考电阻率比值0.08~0.1进行修正。     

Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater

The dye industry produces a large amount of hazardous wastewater every day worldwide, which brings potential threaten to the global environment. As an excellent method for removal of water chroma and chemical oxygen demand, electrocatalytic methods are currently widely used in the treatment of dye wastewater. The selection and preparation of electrode materials and electrocatalysts play an important role on the electrocatalytic treatment. The aim of this paper is to introduce the most excellent high-efficiency electrode materials and electrocatalysts in the field of dye wastewater treatment. Many electrode materials such as metal electrode materials, boron-doped diamond anode materials and three-dimensional electrode are introduced in detail. Besides, the mechanism of electrocatalytic oxidation is summarized. The composite treatment of active electrode and electrocatalyst are extensively examined. Finally, the progress of photo-assisted electrocatalytic methods of dye wastewater and the catalysts are described.     

多级结构MoS2/C复合材料的储锂性能

利用二硫化钼和葡萄糖为原料,采用一锅乙醇/水复合溶剂热-后热处理法制备了绣球花状结构MoS₂/C复合材料。考查了乙醇/水复合溶剂的合理组成和MoS₂/C复合材料中碳的合理含量,分别采用SEM和TEM表征了MoS₂/C材料的形貌结构,通过TGA测试和计算了材料中的碳含量。采用循环伏安、恒流充放电和交流阻抗等测试了MoS₂/C复合电极的电化学性能。结果表明,MoS₂/C复合材料拥有多级花球状结构,缓解了MoS₂的团聚,使电极材料的利用率和电化学稳定性显著提高。当V（乙醇）：V（水）为1：2,碳含量为50%时,MoS₂/C复合电极在200 mA·g^-1的电流密度下,充放电循环100次后,可逆容量达到762 mA·h·g^-1。     

A panoramic view of Li7P3S11 solid electrolytes synthesis,structural aspects and practical challenges for all-solid-state lithium batteries

The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm^-1, and deformability, the sulfide-based Li₇P₃S₁₁ solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li₇P₃S₁₁ could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li₇P₃S₁₁-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries.     

基于有限元方法的CeCl3和NdCl3在LiCl-KCl熔盐中的电极动力学模拟

充分理解锕系元素和镧系元素在熔盐中的行为和性质是实现反应堆乏燃料熔盐电解后处理的关键,然而熔盐电解实验所需的高温环境、腐蚀性熔盐甚至放射性物质等条件限制了实验的广泛开展。为寻求一种低成本且可靠的获取元素在熔盐中性质的途径,采用有限元方法在不同温度下模拟了不同浓度的三氯化铈和三氯化钕在LiCl-KCl熔盐中的循环伏安曲线,并与实验数据做了对比。结果表明,有限元方法能够较为准确地反映实际电化学过程,继而为乏燃料熔盐电解后处理提供数据支持。     

Effect of Ca2+ and Mg2+ ions on the sintering and spectroscopic properties of cr-doped yttrium aluminum garnet ceramics

In this work, we investigated the effects of Ca²⁺ and Mg²⁺ ions and annealing temperature on the spectroscopic parameters of chromium-doped yttrium aluminum garnet ceramics (Cr:YAG). Samples were obtained with either a separate or a simultaneous addition of calcium and magnesium oxides. To achieve this, aqueous suspensions were prepared using Y₂O₃, Al₂O₃, Cr₂O₃, MgO, and CaO high-purity powders as raw materials. The obtained suspensions were freeze-granulated, pressed into pellets, debinded, and subjected to reactive sintering in vacuum at 1715°C for 6 h. Each material was annealed in air with temperatures between 1300 and 1700°C. Samples were also compared to Cr:YAG ceramics with the addition of silica as a sintering aid. All the materials obtained were then exposed to 445 nm excitation, and emission spectra in the visible and infrared wavelengths were recorded. The results showed that the emission spectra of Cr:YAG ceramics varied according to the annealing conditions: as-sintered samples exhibited strong emissions of around 680 nm and, after air annealing, of around 1400 nm. This phenomenon is attributed to the Cr³⁺→Cr⁴⁺ transition. Samples doped solely with MgO exhibited the highest emission intensity in the infrared region. Thus, Mg²⁺ ions provided the best conversion efficiency of chromium ions.     

用丝束电极研究混凝土中钢筋腐蚀的不均匀性

用8×8阵列丝束电极模拟研究了混凝土中钢筋的腐蚀.将混凝土试样浸泡在10 %NaCl溶液中,通过测量铁丝束电极的自腐蚀电位和极化电阻,获得了在相同埋置深度和不同埋置深度时,铁丝腐蚀的电位、极化电阻和腐蚀速度分布等信息,研究了混凝土结构和氯离子浓度对它们的影响.结果表明,混凝土中铁丝腐蚀不均匀.自腐蚀电位和极化电阻较分散,电位随时间负移、极化电阻变小,丝束之间的电位差增大.随铁丝埋入深度增加,电位负移量、氯离子浓度和腐蚀速度都减小、极化电阻增加     

人血清白蛋白对模拟宫腔液中铜的光电响应特性的影响

用动电位伏安法，动电位光电流测量，表面膜的阴极还原和XRD分析等手段研究了铜在含或不含人血清白蛋白的模拟宫腔液（pH=7)中的电化学和光电化学行为，在不含白蛋白的模拟宫腔液中，铜电极表面生成的Cu2O呈n型光响应；一定量白蛋白存在时使Cu2O的光响应从n型转为p型，Cu2O在模拟宫腔液中呈n型光响应可归因于氯离子对Cu2O的掺杂，白蛋白排斥氯离子对Cu2O的掺杂，使其光响应从n型转为p型。     

微小电极夹持送进机构设计

设计实现了一种微小电极丝送进机构，使电极丝在随主轴旋转并在轴向高精度的伺服进给控制下，可实现电极丝长距离的送进及损耗自动补偿。其中电极丝的夹紧切换由一个常闭夹丝机构和一个常开夹丝机结构执行，常闭和常开夹丝机构可由电磁或形状记忆合金致动控制。     

海洋平台大厚度焊接接头断裂韧度

依据BS7448断裂韧度试验标准(ISO／TC164／SC4-N400)，对采用埋弧焊(SAW)工艺施焊的、板厚为54mm的海洋石油平台大厚度对接接头试样进行了低温裂纹尖端张开位移(CTOD)试验。分别测试了-15℃下单丝和双丝埋弧焊工艺下焊缝金属和热影响区的CTOD值。试验表明，除双丝埋弧焊热影响区试件外，其余试件均满足挪威船级社DNV规定的最小特征CTOD为0．15mm的要求，为指导海洋平台的施工建造提供了科学依据。