多孔挡板流化床还原UO3反应器模型的研究

针对ＵＯ＿３的Ｎ＿２还原反应建立了多孔挡板流化床反应器模型。将多孔挡板床的每一级视为具有相似的流动状态，每一级的上、下段称为稀、密相段，分别用鼓泡床和活塞流模型描述。该模型的计算值与￠６３ｍｍ的多孔挡板床Ｈ＿２还原ＵＯ＿３的热态实验值能较好的吻合。还预计了还原温度、操作气速和挡板结构参数对固相转化率的影响，为该类反应器的工业设计、放大和优化提供了依据。     

Treatment of Humic Waters By Ozone

Two different generators for ozone were tested, a traditional electrical discharge generator and a generator based upon UV–irradiation of air at 150–180 nm. It was demonstrated that the traditional generator gave slightly higher reductions in levels of color for equivalent ozone dosages. Both gases affected the molecular weight distribution in the way that the bigger molecules were broken down to smaller ones. No significant difference between the molecular weight reduction efficiency of the gases was found.     

聚合物泥浆降粘剂PT－1降粘作用研究

ＰＴ－１降粘剂是顺丁烯二酸（酐）与乙烯基单体的共聚物。本文通过扫描电镜、粒度分析、Ｘ射线衍射等分析测定，研究了ＰＴ－１在膨润土泥浆和聚合物泥浆中的降粘作用，探讨了ＰＴ－１的降粘机理。     

The Effect of Ozone Gas-Liquid Contacting Conditions in a Static Mixer on Microorganism Reduction

The effect of gas-liquid contacting conditions in a static mixer on ozone transfer efficiency and reduction of Bacillus subtilis spores was studied in an experimental ozone contactor. An empirical mathematical model was developed that related the transfer efficiency in the experimental system to the superficial liquid velocity in the mixer, the gas-liquid flow rate ratio and the height of the down-stream bubble column. Spore reduction was determined primarily by the dissolved ozone concentration-time (C_avgt_m) product in the reactive flow segment and was independent of the gas-liquid contacting conditions in the static mixer. In an integrated ozone contacting system, the static mixer should be designed to maximize ozone mass transfer while the reactive flow segment should be designed for efficient microorganism reduction.     

Direct atomic scale analysis of the distribution of Cu valence states in Cu/γ-Al2O3 catalysts

In this paper, the microstructure of a 1 wt.% Cu/γ-Al₂O₃ catalyst that was reduced in a 4% hydrogen/argon atmosphere at temperatures of 523, 773 and 1073 K, is studied by Z-contrast imaging and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Results show that the copper species are well dispersed when the catalyst is reduced below 523 K. At 773 K, separated Cu(I) and Cu(0) species are found existing as ring-like and bulk-like particles. This appears to indicate that the copper has not been reduced to its metallic form due to the interaction between the copper oxide and the support. Large spherical particles having core-shell structures with Cu(I) in the shells and Cu(0) in the cores are generated when the catalyst is reduced at 1073 K. The formation of partially oxidized copper species upon reduction at 1073 K is attributed to the metallic copper interaction with the alumina support. This study also demonstrates that high-spatial resolution Z-contrast imaging and EELS performed simultaneously can provide unique information on the morphology and chemistry of metal species in supported metal catalysts.     

Reduction of low-frequency pressure fluctuations in wind tunnels

The determination of dynamic wind loads on buildings, i.e. pressure and deflection, has gained increasing interest (European Prestandard ENV 1991-2-4, Eurocode 1: basis of design and actions on structures—Part 2-4: actions on structures—wind actions, European Committe for Standardization, Brussels, 1995; DIN 1055 Teil 4 Lastannahmen für Bauten, Verkehrslasten, Windlasten bei nicht schwingungsanfälligen Bauwerken, 1991; N. Hölscher, M. Hortmanns, J. Sahlem, Praxisnahe Erfassung von Windwirkung an Industrie- und Hochbauten, Windwirkung im Bauwesen, Braunschweig, 7, Dreiländertagung D-A-CH 2001, Windtechnologische Gesselschaft, 2001 [1], [2] and [3]). Therefore, the spectral distributions of velocity and pressure fluctuations in wind tunnels are an important quality aspect. While velocity fluctuations can be manipulated by the obstacles used to create the turbulence, pressure fluctuations are influenced by acoustic noise as well. Especially, the first eigenfrequency of the longitudinal mode of the wind tunnel tends to disturb the pressure spectrum.In this paper, a solution for the reduction of low-frequency acoustic pressure fluctuation is presented and its application in the atmospheric boundary layer wind tunnel at the IAG is shown.     

柴油添加剂功效影响因素的灰色关联分析

提出了一种柴油添加剂非台架实验的功效判断方法——灰色关联分析法。应用这个方法分析待测功效的柴油添加剂，可通过测定加入它后的柴油样品的物理性质和加入已知功效较好的柴油添加剂的柴油样品的物理性质，再作灰色关联分析，综合关联顺序以评定其功效好坏。应用这个方法还可推断柴油样品的表面张力是影响燃烧好坏的主要因素，其次是粘度、十六烷值和燃点。     

我国家具快速发展的因素

加入WTO后,我国家具业飞速发展,获得前所未有的企业规模、商业契机和发展趋势。本文从低廉的成本、稳定的政局、先进的设备、技术、设计理念及管理方式等诸方面探讨中国家具快速发展的因素。     

Cathodic processes in the leaching and electrochemistry of covellite in mixed sulfate–chloride media

The cathodic processes that occur on a covellite (CuS) surface in mixed sulfate–chloride solutions in the absence and presence of copper(II) ions have been studied using potentiostatic transients and cyclic voltammetry at rotating disk electrodes in the potential range 0.3–0.7 V (versus SHE). This range is relevant to the oxidative leaching of this copper mineral in sulfate and chloride lixiviants. Variations in the concentrations of sulfate and chloride ions had a small effect on the cathodic reduction of covellite in the potential range of 0.5–0.3 V, although the presence of chloride ion resulted in a significant increase in the anodic current on the reverse sweep. On the other hand, addition of copper(II) ions resulted in enhanced cathodic currents and subsequent anodic currents in both sulfate and chloride solutions due to reduction of covellite to an undefined reduced copper sulfide species. Reduction of copper(II) to copper(I) ions becomes the preferred cathodic reaction as the concentration of chloride ions increases, becoming mass transport controlled at a rotating disc electrode at potentials below about 0.4 V. Potentiostatic measurements at potentials negative to the mixed potential in acidic chloride solutions have shown that reduction of copper(II) ions is reversible and have been used to estimate the rate of oxidative dissolution of the mineral which value agrees reasonably well with previously reported leaching rates under similar conditions. Reduction of dissolved oxygen has been found to be very much slower that that of copper(II) ions under ambient conditions.     

An Investigation of the Reduction and Reoxidation of Isolated Vanadate Sites Supported on MCM-48

The reduction and subsequent reoxidation of isolated vanadate species supported on silica was investigated using temperature-programmed reduction and oxidation, along with in-situ XANES and Raman spectroscopy. Approximately 70–80% of the vanadium was reduced to V³⁺ after reduction in H₂ at temperatures up to 923 K. Upon reduction, the vanadyl oxygen was removed and the three remaining V–O bonds are lengthened by 0.2 Å. The vanadate species are rapidly reoxidized when exposed to O₂, with the amount of oxygen uptake matching well with the amount removed during reduction. In-situ Raman spectroscopy during reoxidation in ¹⁸O₂ showed that significant scrambling occurs between gas phase oxygen and surface oxygen species during the reoxidation of the vanadate species.