核孔膜生产线膜微孔制备工艺实验研究

本文介绍核孔膜生产线,重点描述了膜微孔制备工艺的实验研究。对于PC和PES膜,已得到32种工况下的扩孔公式,其形式为D=A+Bt,其中D——孔径,t——扩孔时间,A,B为特定工艺参数下的常数值.通过实验。得到了膜孔密度N与300~#核反应堆功率P、热柱辐照位置L的经验公式,即N=6.97×10~5×10~3×101~(1.18L).在本生产线上可生产最大幅面为3 140mm×240mm,孔径为0.04～10 μm的多系列多规格的核孔膜产品。     

低速爆轰管对黑火药的点传火性能研究

文章采用中心点火管结构的实验装置研究了黑火药的点传火性能。用低速爆轰 (L VD)中心点火管来点燃黑火药时 ,1# ～ 3# 大粒黑药的传火速度为 70 0 m· s-1～ 80 0 m· s-1数量级 ,燃烧波宽度在 3.1ms～ 3.5 ms,最大压力峰值 :1# 为 36 .4 MPa,2 # 为 2 4 .0 MPa,3# 为 38.0 MPa。用普通中心点火管点燃黑火药时 ,2 # 、3# 和钝化 2 # 大粒黑的传火速度分别为 6 1.2 m· s-1、6 8.2 m·s-1和 4 0 .1m· s-1,最大燃烧波宽度分别为 9.2 ms、6 .3ms和 9.5 ms。燃烧波表明 ,L VD中心传火管与普通中心传火管相比较 ,在传火管的不同位置处 ,前者的 P- t曲线一致性远高于后者。     

Porous elastomeric beads from crosslinked emulsions

The production of porous polymeric particles is attractive for a large number of applications and can be achieved by various techniques. Although numerous production schemes exist for glassy polymers, difficulties arise for soft, rubbery materials that need a chemical crosslinking step, such as elastomers. This is particularly true for poly(dimethylsiloxane) (PDMS), which shows the lowest glass‐transition temperature among the polymers. Recent studies suggest in situ hydrogen bubble formation or vacuum drying of water droplets dispersed in the polymer matrix in order to generate porous PDMS structures. In this work we report early results based on the chemical crosslinking of water in PDMS emulsion droplets in a mechanically stirred thermostated water vessel. This approach is shown to lead to high porosity PDMS beads (ca. 10^?3 m particle diameter) with an open structure whose properties (diameter and porosity) are strongly influenced by the starting composition (solvent, surfactant, and polymer types and ratios), as well as the operating parameters (agitation and temperature). The possible uses of these derived beads are discussed. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 967–971, 2002     

色心激光器及其发展

色心激光器由于其特殊的调谐范围及单频、窄线宽的工作特点,可作为高分辨率的分光仪的理想窄带光源而用于分子振动一转动跃迁的研究,在光纤通信、超高速现象的研究等方面也有其独特的应用。本文叙述色心的构造及其特点,色心激光器的泵浦及泵浦的最佳化,调谐方式及新调谐范围的进展,单频、窄线宽运行的实现、激光脉冲的压缩等。最后指出色心激光器的发展方向和可能的应用。     

Asymmetric alumina membranes electrochemically formed in oxalic acid solution

Alumina membranes were fabricated by anodizing aluminium metal in 0.15 M oxalic acid. The growth kinetics of the porous layer were investigated in the temperature range –1 to 16 °C using linear potential scans up to 70 V. The faradaic efficiencies of metal oxidation and of porous layer formation, determined by applying Faraday's law, were found to be independent of both temperature and electrical charge. SEM analysis of the metal-side and solution-side surfaces revealed different morphologies. After dissolution of the barrier layer in phosphoric acid, the metal-side surface showed circular pores whose size of about 90 nm was found to be uniform and independent of temperature. The pore population was also practically independent of temperature and a value of about 4 × 10¹³ pores m^–2 was determined. On the solution-side surface the presence of a deposit partially occluding the mouths of pores was observed. This coating could be removed by chemical etching in NaOH or thermal treatment at 870 °C, where decomposition of oxalate occurs. This supports the hypothesis that the deposit consists of an aluminium salt containing oxalate anions precipitated from the solution. The results show that it is possible to control the morphological characteristics of the anodic alumina membranes by careful choice of experimental conditions.     

Advances in Microporous and Mesoporous Solids—Highlights of Recent Progress

This report highlights developments in the fields of microporous and mesoporous materials that were published mostly during the year 2002. Selected examples are provided to illustrate new zeolite structures, porous coordination materials, mesoporous solids with new compositions, controlled morphologies, and increased hydrothermal and thermal stabilities, as well as porous solids with tunable pore openings or other structural features that can be dynamically modified. A number of applications are discussed, including stabilization of reactive guests, separations, electronic materials, and sensors.     

利用数据中心构建数字化钻井施工模式

世界石油钻井技术不断向信息化、智能化方向发展,为适应钻井技术的发展,构建了数字化钻井施工模式框架。从井场信息采集设施、井场网络环境、井场信息采集处理软件、井场工程监测软件等方面阐述了数字化钻井队的构建方法,从钻井数据库设计、数据流向及数据加载、数据发布等方面阐述了钻井数据中心的构成,从钻井设计系统、钻井远程监测系统、井眼轨迹控制系统以及专家系统等方面描述了钻井辅助决策平台主要功能。除了理论研究之外,还简要介绍了研究成果在现场的应用情况。这些研究成果是国内"数字油田"建设的基础,必将促进钻井行业的信息技术发展。     

WCDMA的MBMS技术

主要介绍了基于WCDMA的MBMS技术,给出了其网络架构和技术难点,并对其应用给无线网络带来的影响作了一定深度的探讨。     

在线安全预警和决策支持系统的软件构架与实现

安全预警和决策支持（EWSC）系统作为未来控制中心自动化系统的重要功能，一方面需要对能量管理系统（EMS）成熟功能进行封装，另一方面需要适应自动化系统功能演变的需要。提出了一种基于多代理系统（MAS）的软件开发范式，用于开发EWSC系统的软件构架。该系统具有一个松散、开放的可插入式结构。其中核心框架是负责系统通信和任务调度的协调层，是相对固定的;其余部分为独立模块，由一系列相对独立的决策分析和人机表达智能体组成，可以独立开发，方便地嵌入系统。在该框架下系统各个模块层次分明，具有很强的解耦性，并且可以实现把历史遗留系统集成到新的环境中。基于文中所提出的软件构架的在线EWSC系统已在某省级电网投运。     

部分可渗透直立圆柱的消波作用研究

本文导出了线性波浪作用于上部可渗透的直立刚性圆柱体上的水动力的解析解。在线性有势流的假定下，用特征函数展开方法求出了内部和外部流场的解。给出了不同波浪要素及结构尺寸参数下的数值结果。由结果可知，提高可渗透性可以有效消减波幅。