低温吸附法脱除一氧化碳中甲烷的实验研究

在液氮温度下,采用吸附剂CNA X进行低温脱甲烷动态吸附实验,结果表明CNA X在液氮温度下可以将一氧化碳中0 1%左右的甲烷脱除到10×10-6。     

Fabrication and Characterization of Two‐Photon Polymerized Features in Colloidal Crystals

The fabrication and characterization of two‐photon polymerized features written within and outside of colloidal crystals is presented. Two‐photon polymerization (TPP) response diagrams are introduced and developed to map the polymerization and damage thresholds for features written via modulated beam rastering. The use of tris[4‐(7‐benzothiazol‐2‐yl‐9,9‐diethylfluoren‐2‐yl)phenyl]amine (AF‐350) as an initiator for TPP is demonstrated for the first time and TPP response diagrams illustrate the polymerization window. These diagrams also demonstrate that the polymerization behavior within and outside of colloidal crystals is similar and electron microscopy reveals nearly identical resolution. Fluorescence confocal microscopy further enables visualization of non‐self‐supporting, three‐dimensional TPP features within self‐assembled photonic crystals. Finally, microspot spectroscopy is collected from a two‐photon feature written within a colloidal crystal and this is compared with simulation.     

压力计探测液面法探讨

针对油田地质特征复杂，易结蜡，测试中易出现假液面等情况，为准确快速测得液面资料，提出压力计测试液面法。该方法可作为回声仪测液面方法的有效补充。     

液晶电控效应的实验研究

详细阐述了液晶的电光效应,介绍了利用分光光度计测量液晶透射比的方法。通过改变加在液晶盒上的电压大小及其频率高低,详细测量了液晶的透射比。通过做图分析了液晶的电控双折射效应,得出液晶的透射比随所加电压的大小和频率的高低而变化,以及液晶的阈值电压随频率的增高而减小的规律,这对液晶器件的设计与研究均具有一定的参考价值。     

双自由度后坐保险机构的计算机动态仿真

在Workin Model 3D软件上对引信的双自由度后坐保险机构进行了有关计算机仿真计算，并结合具体实例进行了优化设计。     

掺杂铁电纳米粉的液晶的电光特性

铁电纳米粒子悬浮在向列相液晶母体中，增强介电各向异性，而且对施加的电场信号敏感。本文也展示了纳米粒子对所述复合材料可实现的总的相变的作用。这种方法也许可应用于设计新型显示材料。     

电控平行排列液晶光栅的光衍射特性研究

对电控平行液晶光栅的理论进行了分析,并配以结构原理图。通过对平行排列及90°扭曲排列液晶指向矢的计算,得出液晶盒中相应的折射率、相位差与电压之间的关系图,两者经比较证明平行排列更具适用性,并在实验中观测到了平行排列液晶光栅衍射特性与电压的关系。     

棒状液晶分子相变问题的机械旋转模型研究

综述一种关于棒状液晶材料的分子结构与液晶相的相关关系的研究成果。介绍了有关液晶分子的机械旋转模型。该模型将液晶分子视作一种高速旋转的转子,通过分子参数计算,对液晶材料的相变温度和分子结构之间的关系给出了一种全新的解释。最新研究表明,含氟三苯液晶材料的分子结构中存在slim和fat现象,能够对液晶材料的相变进行合理解释。该模型能够通过简单的模型方法对新型液晶材料的分子设计与合成提供有用的信息。     

液晶基元直接横挂于主链上的液晶共聚物的合成与研究

以含液晶基元的单体２，５－双（４－甲氧基苯甲酰氧基）苯乙与苯乙烯通过自由基共聚合反应，首次合成了一系列含液晶性和非液晶性两种序列结构的共聚物。采用ＤＳＣ、偏光显微镜和Ｘ衍射方法研究了共聚物的液晶行为，发现单体和共聚物（只有ＣＰ－５和ＣＰ－６）有很好的热致液晶性。随共聚物中介晶单体单元含量的增加，共聚物玻璃化转变温度Ｔ和热分解温度Ｔ呈规律变化。     

Transport of chromium(VI) through a Cyanex 921‐supported liquid membrane from HCl solutions

The transport of chromium(VI) through a flat‐sheet supported liquid membrane containing Cyanex 921 as a carrier has been investigated. The permeation of the metal is investigated as a function of various experimental variables: hydrodynamic conditions, concentration of chromium(VI) and HCl in the feed phase, carrier concentration and diluent in the membrane and strippant concentration in the stripping phase. The mass transfer coefficient and the thickness of the aqueous boundary layer were calculated from the experimental data. Furthermore, the selectivity of Cyanex 921‐based flat‐sheet supported liquid membrane towards different metal ions and the behaviour of the system against other carriers are presented. Copyright © 2003 Society of Chemical Industry