Thermodynamic modeling of native point defects and dopants of GaN semiconductors

A thermodynamic modeling of GaN was carried out to describe the thermodynamic behavior of native defects, dopants, and carriers (free electrons and holes) in GaN semiconductors. The compound energy model (CEM) was used. An unintentionally doped GaN was taken as an example. Oxygen was introduced into the model as the unintentionally doped impurity, according to the practical experimental phenomena. The energies of component compounds in the model were defined based on the results of the ab initio calculations and adjusted to fit experimental data. The thermodynamic properties of the defects and the oxygen doped were calculated to show the facility of the model.     

纤维混凝土在水工建筑工程中的应用(上)

概述改性混凝土垢发展情况，介绍纤维混凝土在国内外水工建筑物上的应用实例，提出钢纤维增强钢筋混凝土水工建筑结构强度计算方法。包括受弯构件正截面强度，斜截面抗剪强度的计算；重点介绍了网状钢纤维增强混凝土（FOC）在水工建筑物上的应用，包括在渡槽，闸门，小型拦河坝，轻型岸型等工程上的应用实例，T新梁正斜截面的强度计算，板材承载力计算的方法。     

大港白水头地区低阻油气层测井评价

在对白水头地区低阻油层的地质特征、物性特征及成因环境进行了分析研究后 ,应用测井曲线特征集法 ,把白水头油田常规油气层、低阻油气层、油水同层、水层等看成是独立的地质事件 ,建立了它们与测井曲线特征之间的对应关系 ,利用这种关系对未知地质事件进行了预测划分。最后根据所建模型定量计算储层各种参数 ,收到了良好的地质效果 ,表明测井曲线特征集法对于识别多成因的低阻油层是一种有效方法     

45钢表面超音速电弧喷涂Ti-Al涂层的组织与性能研究

采用自行开发研制的超音速电弧喷设备，在45钢表面制成了钛铝合金复合涂层。并利用金相显微镜、X射线衍射仪、扫描电镜、电子探针，对涂层的成分、相结构、显微组织及其结合强度、显微硬度进行了研究。结果表明，利用超音速电弧喷涂设备，可以在45钢表面形成 度高、孔隙率低，结合强度较好和硬度高的Ti-Al合金涂层。     

Immobilization and activation of vanadium(III) and titanium(III) single‐site catalysts for ethylene polymerization using MgCl2‐based supports

Significant increases in the activity of vanadium(III) amidinate catalysts for ethylene polymerization have been obtained by immobilization on a MgCl₂‐based support prepared by reaction of AlEt₃ with a MgCl₂/ethanol adduct. Catalyst immobilization and activation on this type of support prevents the rapid decay in activity observed under homogeneous polymerization conditions with unsupported catalysts. Stable polymerization activity is also observed with analogous titanium(III) complexes. Polyethylene with narrow molecular weight distribution and spherical particle morphology is obtained without reactor fouling. Copyright © 2005 Society of Chemical Industry     

Low density polyethylene and grafted lignin polyblends using epoxy‐functionalized compatibilizer: mechanical and thermal properties

Lignin was graft copolymerized with methyl methacrylate using manganic pyrophosphate as initiator. This modified lignin was then blended (up to 50 wt%) with low density polyethylene (LDPE) using a small quantity of poly[ethylene‐co‐(glycidyl methacrylate)] (PEGMA) compatibilizer. The mechanical properties of the blend were substantially improved by using modified lignin in contrast to untreated lignin. Differential scanning calorimetry studies showed loss of crystallinity of the LDPE phase owing to the interaction between the blend components. Thermogravimetric analysis showed higher thermal stability of modified lignin in the domain of blend processing. This suggested that there is scope for useful utilization of lignin, which could also lead to the development of eco‐friendly products. Copyright © 2005 Society of Chemical Industry     

氨氮监测中样品蒸馏预处理对结果的影响分析

氨氮监测采用预蒸馏处理后，比色测定结果明显偏低。在样品预蒸馏处理过程中，硼酸作为吸收液，使显色时溶液pH值偏低，导致显色不充分是其主要影响因素。通过采取增加显色剂加入量的方法，解决了显色pH值偏低的问题，得到满意的测定结果。     

薄板坯连铸连轧流程Ti微合金化高强钢开发与应用

在薄板坯连铸连轧流程上，经过对Ti微合金化技术研究，有效解决了Ti微合金化强度性能波动大的问题，开发出屈服强度450～700MPa高强钢。对试制钢组织性能和工业应用分析研究，表明该产品通板性能良好，通板强度差30MPa左右；成形性能良好，d=0时冷弯测试全部合格；同时还具有良好焊接性能，焊接后，强度波动较小，均在母材部位断开；试制钢显微组织为珠光体和铁素体，晶粒均匀细小，平均尺寸为4～8／μm；实物质量满足集装箱和汽车制造行业要求，具有广阔市场前景。     

Amorphous diffusion bonding of steel pipe and its impact toughness

An iron-based amorphous foil (FeNiCrSiB) was used as an interlayer for the amorphous diffusion bonding of low carbon steel pipes under argon flux. The microstructure and mechanical properties of the joint were analyzed using an electron probe micro-analyzer (EPMA), tensile test, bending test and impact test. The results show that the joint microstructure resembles that of the base metal and no precipitates form at the joint. Melting point depressants (B, Si) diffuse far away from the joint and the base metal element is homogenous across the joint. The joint impact toughness is greater than the base metal toughness and the mechanical properties of the joint are similar around the pipe.     

Atmospheric corrosion of reference metals in Antarctic sites

This paper presents the results obtained at three Antarctic test sites participating in the “Ibero-American Map of Atmospheric Corrosiveness” (MICAT), a project on atmospheric corrosion carried out during the period 1988–1994 at some 70 sites distributed across 12 countries of the Latin-American region, Spain and Portugal. The three Antarctic sites are located near the coastline.The singular climatic characteristics of Antarctic regions are related with the purity of the air, the absence of rainfall and the formation of ice on the metallic surface during an important part of the exposure time. However, electrochemical activity is possible below ice layers. This situation affects the structure and morphology of corrosion product films and the resulting corrosion rates of metallic surfaces.