纺织类高校高分子材料工程专业人才培养模式的思考

随着高分子科学与其它学科的交叉、渗透和融合,我国高分子材料工程专业的人才培养呈现迅猛发展的态势。由于大多数纺织类高校高分子专业设置时间较短,专业教育的积淀不够,培养的高分子专业毕业生普遍不具备竞争优势。面对这种形势,如何审时度势、与时俱进地改革人才培养模式,增强高分子专业人才的竞争力,是纺织类高校共同关注的问题。根据大多数纺织类高校的特点,提出高分子材料工程专业人才培养定位为工程技术型人才,侧重于纺织行业中高分子材料的技术和产品开发、生产与经营管理等。在专业课程设置中更多地体现纺织专业的特色,同时在生产实践环节应强化与纺织专业的结合。     

Carburization of ferrochromium metals in chromium ore fines containing coal during voluminal reduction by microwave heating

Chromium ore fines containing coal (COFCC) can be rapidly heated by microwave to conduct the voluminal reduction, which lays a foundation of getting sponge ferrochromium powders with a lower content of C. Under the conditions of COFCC with n(O):n(C) (molar ratio) as 1.00:0.84 and n(SiO₂):n(CaO) as 1.00:0.39, the samples were heated by 10 kW microwave power to reach the given temperatures and held for different times respectively. The results show that the low-C-Cr ferrochromium metal phase in the reduced materials forms before the high-C-Cr ferrochromium metal phase does. With increasing temperature the C content of ferrochromium metals is in a positive correlation with the content of Cr. The C content of ferrochromium metal in reduced materials is 0–10.07% with an average value of 4.68%. With the increase of holding time the Cr content in ferrochromium metals is in a negative correlation with the content of C, while the content of Fe changes in the contrary way. In the microwave field the kinetic conditions of carburization are closely related with the temperature of microwave heating, holding time and carbon fitting ratio. Foundation item: Project(50474083) supported by the National Natural Science Foundation of China; Project supported by the Baoshan Iron & Steel Co. Ltd. of China     

Hydrogen sorption properties of nanocrystalline Mg2FeH6-based complex and catalytic effect of TiO2

The diversities of hydrogen sorption properties of Mg₂FeH₆-based complexes with and without TiO₂ were investigated. Mg₂FeH₆-based complexes with and without TiO₂ were synthesized respectively by reactive mechanical alloying, and hydrogen sorption properties of the complexes were examined by Sieverts-type apparatus. The results show that the sample without TiO₂ releases 4.43 % (mass fraction) hydrogen in 1.5 ks at 653 K under 0.1 MPa H₂ pressure and absorbs 90% of the total 4.43 % (mass fraction) hydrogen absorbed in 85 s at 623 K under 4.0 MPa H₂ pressure. But for the sample with TiO₂ addition under the same condition, it only needs 400 s to release all of the stored hydrogen and 60 s to absorb 90% of the total hydrogen absorbed. The activation energies for desorption process of the samples with and without TiO₂ are determined to be 71.2 and 80.3 kJ/(mol·K), respectively. The improvement in hydrogen sorption rate and and reduction in activation energy can be attributed to the addition of TiO₂.     

Reserve estimation of an open pit mine under price uncertainty by real option approach

Reserve estimation is a key to find the correct NPV in a mining project. The most important factor in reserve estimation is the metal price. Metal price fluctuations in recent years were exaggerated, and imposed a high degree of uncertainty to the re-serve estimation, and in consequence to the whole mine planning procedure. Real option approach is an efficient method of deci-sion making in the uncertain conditions. This approach has been used for evaluation of defined natural resources projects until now. This study considering the metal price uncertainty used real option approach to prepare a methodology for reserve estimation in open pit mines. This study was done on a copper cylindrical deposit, but the achieved methodology can be adjusted for all kinds of deposits. This methodology was comprehensively described through the examples in such a manner that can be used by the mine planners.     

智能材料二维问题的状态空间解

抛弃任何有关位移或应力模式的人为假设,引入状态空间理论,从压电、压磁智能材料和电磁耦合弹性介质材料二维问题的基本方程出发,建立了压电、压磁智能材料和弹性介质二维问题的状态变量方程,得到状态变量空间解,此解形式简单、便于应用.     

金属离子对红球菌腈水合酶活力的影响

不同金属离子对红球菌（Rhodococcus sp．）TCCC 28001的生长及其腈水合酶的酶活有着不同程度的影响．菌株TCCC 28001产生的腈水合酶是钴型,且Co^2＋对该腈水合酶诱导激活的最适浓度为10×10^-5mol／L．选择酵母粉中含有且含量波动较大的5种金属离子,考察了在添加10×10^-5 mol／L Co^2＋诱导激活下,5种金属离子对酶活的影响．结果表明：Fe^2＋,Mn^2＋,Mo^6＋,Cu^2＋4种金属离子具有促进作用,Zn^2＋产生轻微抑制作用．6×10^-5mol／L Fe^2＋的促进效果显著,使菌株TCCC 28001的酶活从453U／mL增加到1941U／mL,提高了328％．     

单晶AlN纳米线的合成和光致发光特性研究

在无催化剂和模板条件。利用直流电孤放电等离子方法直接氮化金属铝合成纤锌矿结构的单晶AIN纳米线．分别用X光射线衍射（XRD）和场发射扫描电镜（FESEM）对AIN纳米线的结构和形貌进行表征,并测量了AIN纳米线的光致发光谱（PL）．结果表明,A1N纳米线的长度超过100μm,直径大约200nm,具有较高的长径比;在AIN纳米线的PL谱中,中心在506nm的发射带源于氮空位相关的深能级缺陷．     

熟料粒度对骨粉/磷酸钙生物骨水泥结构与性能的影响

采用新方法首次将动物骨中的鱼骨引入到磷酸三钙和磷酸氢钙等原料体系中通过高温烧结制备磷酸钙基生物骨水泥（CPC）,以柠檬酸和柠檬酸钠的缓冲液为固化液、按一定的液固比制备固化试样,通过扫描电子显微分析（SEM）和力学性能测试等方法,研究了熟料粒度对其固化试样结构与抗压强度的影响.结果表明：制备过程中骨水泥粉末的粒度对其固化试样的微观结构及其抗压强度有着较为显著的影响,通过调整骨水泥粉末的粒度可达到优化其固化试样的微观结构和改善其力学性能的目的.     

焊接方法优化设计系统的研究

在分析专家系统应用于焊接领域的基础上,根据焊接工艺设计的原理及通常焊接方法的选择原则,研究了焊接工艺设计的特点,提出了系统的设计思想,确定了系统总体框架及模块功能,利用VB实现了建立焊接方法优化设计的系统．采用本系统可以提高焊接工艺人员编制WPS的效率,为生产企业节省资金、缩短技术准备周期,解脱技术人员的繁重劳动,采用该焊接方法优化设计系统还可以增强企业的竞争力．     

一个新的环型三核铜配合物的晶体结构研究

用2-羟基-1,3-丙二胺（L）与高氯酸铜反应得到了一个三核铜金属杂环配合物[Cu3（L^-）3]（ClO4^-）3,用X-射线晶体结构分析方法表征了其结构．该晶体属三斜晶系,P-1空间群,晶胞参数a=1．0491（2）nm,b=1．0808（2）nm,c=1．2467（2）nm,a=74．451（3）°,β=70．635（3）°,γ=63．661（3）°,V=1．1829（3）nm^3,Z=4,R=0．0587,wR=0．1363．在配合物的阳离子中,三个铜离子均与相邻配体上的两个氮原子和两个桥联氧原子配位形成四配位平面四方形构型,且通过与三个配体2-羟基-1,3-丙二胺上的桥联氧原子连接形成一个由Cu^2＋和氧原子交错联接的六元杂环结构．