Organosoluble and light-colored fluorinated polyimides derived from 2,3-bis(4-amino-2-trifluoromethylphenoxy)naphthalene and aromatic dianhydrides

A novel fluorinated bis(ether amine) monomer, 2,3-bis(4-amino-2-trifluoromethylphenoxy)naphthalene, was prepared through the nucleophilic aromatic substitution reaction of 2-chloro-5-nitrobenzotrifluoride and 2,3-dihydroxynaphthalene in the presence of potassium carbonate, followed by catalytic reduction with hydrazine and Pd/C. A series of new fluorine-containing polyimides having inherent viscosities of 0.54 to 1.10 dl/g were synthesized from the diamine with various commercially available aromatic dianhydrides using a standard two-stage process with thermal imidization of poly(amic acid) films. These polyimides were highly soluble in a variety of organic solvents, and most of them afforded transparent, light-colored, and tough films with good tensile strengths. These polyimides exhibited glass transition temperatures (T_gs) of 247-300 °C and showed no significant decomposition below 500 °C under either nitrogen or air atmosphere. Except for the polyimide derived from pyromellitic dianhydride, the polyimide films were almost colorless, with an ultraviolet-visible absorption cutoff wavelength below 400 nm and low b∗ values (a yellowness index) of 10.7-41.9. These polyimides had dielectric constants of 3.09 to 3.65 (1 MHz) and moisture absorptions in the range of 0.2-0.3 wt%.     

高入纤功率光纤通信系统的可靠性研究

掺铒光纤放大器(EDFA)和拉曼放大器(FRA)的使用,使得光纤通信系统中的入纤功率有了很大的提高.较高的入纤功率不仅会在光纤中引起各种非线性效应,对光脉冲的传输产生影响,也会对光纤本身的可靠性产生影响,为此介绍了高入纤功率对光纤系统的影响,分析了其产生的机理,并提出了应对措施.     

无线光接入技术

无线光通信系统以其高带宽、低成本和安装迅捷等优势成为非常有竞争力的光接入新技术。对无线光通信系统的关键技术、主要优势和存在的问题及国内外相关产品的发展状况和主要特点进行了论述和介绍。     

碲酸盐系统玻璃组成和结构对非线性光学性能的影响

碲酸盐系统重金属氧化物玻璃是一种优秀的非线性光学玻璃材料，具有较大的三阶非线性光学效应、超快光学响应、较宽红外透过范围、较好稳定性以及广泛应用前景。碲酸盐系统玻璃中的中间离子和网络外离子的加入会改变组成网络的配位多面体组成、键性和能带结构，进而影响玻璃的非线性光学性能。探讨了碲酸盐系统玻璃的网络结构，阐述了玻璃组成、结构以及纳米簇和非线性光学性能之间的相互关系。     

电力光通信网浅谈

介绍了电力通信中SDH光传输网在业务分布、光缆连接结构方面的特点,并结合这些特点探讨了网络合理组织、保护技术和设备选择的方案。     

The Role of Network Topologies in the Optical Core of IP-over-WDM Networks with Static Wavelength Routing

In this paper, we present a performance analysis of network topologies for the optical core of IP-over-WDM networks with static wavelength routing. The performance analysis is focused on regular degree four topologies, and, for comparison purposes, degree three topologies are also considered. It is shown that the increase of the nodal degree from three (degree three topology with smallest diameter) to four (degree four topology with smallest diameter) improves the network performance if a larger number of wavelengths per link is available. However, the influence of wavelength interchange on the nodal degree gain is small. The performance of regular degree four topologies with smallest diameter is also compared with the performance of mesh–torus topologies (which are also degree four topologies), and it is shown that the blocking probability of degree four topologies with smallest diameter is about two orders of magnitude lower than the blocking probability of mesh–torus topologies. It is also presented a performance comparison of WDM-based networks with nodal degrees ranging from two to five and it is shown that the increase of the nodal degree from two to three leads to high nodal degree gains, while de increase of the nodal degree from four to five leads to low nodal degree gains. These results show that degree three and degree four topologies are very attractive for use in the optical core of IP-over-WDM networks.     

分数阶傅立叶变换的多种定义形式及其光学实现系统分析

分数阶傅立叶变换是经典傅立叶变换的广义形式,它同时从时间域和频率域(或空间域)揭示信号特征。本文系统地分析了分数阶傅立叶变换三种定义形式及其所对应的光学实现系统的组成和原理,说明了光学信息处理系统实现分数阶傅立叶变换的有效性.     

自由空间光通信终端机中ATP系统设计

自由空间光通信将成为未来通信一种可行且非常具有吸引力的通信手段。光束的捕获、跟踪和对准是自由空间光通信中必须解决的关键技术之一。本文介绍了自由空间光通信终端机中ATP系统的工作原理 ,详细论述了实现ATP系统功能的硬件和软件的设计 ,并给出了该系统性能测试的结果。     

用于大功率红外传输的特种光纤

评述了红外传输光纤中的氧化物光纤、氟化物光纤、硫族化物光纤、晶体光纤、空芯光纤、液芯光纤等国内外研制和应用的现状和特点.     

PbZr0.52Ti0.48O3薄膜红外椭圆偏振光谱研究

用磁控溅射法在Pt/Ti/SiO2 /Si衬底上制备了PbZr0 .52 Ti0 .4 8O3(PZT)薄膜 .XRD结果表明经过退火后的PZT薄膜呈现多晶结构 .通过红外椭圆偏振光谱仪测量了λ为 2 .5～ 12 .6 μm范围内PZT薄膜的椭偏光谱 ,采用经典色散模型拟合获得PZT薄膜的红外光学常数 ,同时拟合得到未经处理的PZT薄膜和退火后PZT薄膜的厚度分别为 45 4.2nm和 45 0 .3nm .最后通过拟合计算得到结晶PZT薄膜的静态电荷值为 |q|=1.76 9± 0 .0 2 4.这说明在磁控溅射法制备的PZT薄膜中 ,电荷的转移是不完全的 .