离子静电水处理技术在循环冷却水中的应用

简要介绍了离子静电水处理技术杀菌、灭藻、防垢阻垢的机理，及在循环冷却水系统中的应用情况。     

Design and control of an olefin metathesis reactive distillation column

This paper considers the design and control of a reactive distillation column in which one reactant is consumed and two products are formed (A?B+C). The volatilities are α_B>α_A>α_C, i.e. the reactant is intermediate boiling between the two products. The metathesis of 2-pentene is considered as the demonstrative example. The column has a single feed of the intermediate boiling reactant. The distillate contains mostly light component and the bottoms mostly heavy.Three designs are considered: the base case (low-conversion/low-pressure), a low-conversion/high-pressure case and a high-conversion/high-pressure case. The base design is obtained from the literature, and the other two steady-state designs are optimized with respect to the total annual cost. All the designs are found to be openloop stable. Five control structures are studied for the base design. Then the best two structures are applied to the remaining two designs. This category of reactive distillation exhibits less challenging problems than other categories since it uses a single feed, which eliminates the need for the control structure to perfectly balance two fresh feeds.Simulation results demonstrate that effective dynamic control is provided by a control structure that uses two temperatures to maintain the purities of both product streams. No internal composition measurement is required. This structure is found to be robust and stable and rejects loads and tracks setpoints very well.     

Neutral poly(3,4-ethylenedioxythiophene-2,5-diyl)s: preparation by organometallic polycondensation and their unique p-doping behavior

Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C₆(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C₆(Ni) was soluble in organic solvents and ¹H NMR data indicated that it had an M_n of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave M_n and M_w of about 1700 and 2400, respectively. PEDOTh-C₆(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl₃. Electrochemical oxidation of PEDOTh-C₆(Ni) started at about −0.40 V vs Ag⁺/Ag and gave a peak at 0.20 V vs Ag⁺/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C₆(Ni), both in solutions and in a solid state, led to weakening of the original π-π^∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C₆(Ni) caused not only a decrease in the intensity of ¹H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm⁻³; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data.     

电流模式n阶传输函数的OA-OTA实现

提出了一种新的实现任意 n阶电流模式传输函数的网络结构。该电路仅含运算放大器 (OA)和运算跨导放大器 (OTA)有源器件 ,因而适于全集成。适当设置 OTA的跨导值能实现任意高阶传输函数 ,且传输函数的系数可独立调整。文中推导了滤波器的设计公式 ,并给出了截止频率为 1 0 0 k Hz的三阶巴特沃斯低通滤波器实例 ,PSPICE仿真结果表明所提电路及设计公式是正确的     

湛江发电厂一号机振动的原因分析及处理

对湛江发电厂1号机4号轴瓦振动大的问题进行分析,认为其主要原因为:低压缸变形大导致动静碰摩,轴承座及盘车箱下部脱空引起刚度降低,轴承座的固有频率与工频相近等。对此,采取了相应的处理措施,实施后4号轴瓦振动得到有效解决。     

对完善公司物资供应管理体系的思考

针对经“债转股”和资产重组成立的北京东方石油化工有限公司物资供应管理特点和存在的问题，从供应管理模式、采购方式、采购过程监控、信息化管理、物资储备、人员结构等6个方面，分析了目前供应管理存在的问题和不足，并针对问题通过对物资供应管理体制的分析和思考，提出对策，为新的物资供应体制的建立提供参考。     

原油轻烃反吹色谱分析

利用程序升温进样(PTV)和切割反吹色谱分析技术对原油C₁₅及以前的轻烃组分分析方法进行了研究。通过对压力(P₁,P₂)、变压时间和变压速率等进行优化选择,在切除中—重质烃类物质、保护分析柱的同时实现了轻烃组分的快速分离分析,几个难分离物质对的分离度都优于GB/T18430.1—2001和美国1998ASTM:D5134—98的要求,分析结果稳定可靠,轻烃指纹参数和正常色谱分析结果有很好的可比性。应用此方法对准噶尔盆地部分原油样品进行了分析,轻烃地球化学参数特征清晰地反映了油样的同源性和运移方向。      

重型车床专用喷吸钻的设计

主要介绍了喷吸钻装置的工作原理、结构设计和使用特点,并对其运行的可靠性作简要分析.此喷吸钻的设计目的主要是为了解决大型轴类(轧辊类)工件的深孔加工问题,提高实际生产中的深孔加工效率.     

利用自生气的油气田开发开采工艺技术概况

油气田开发工艺技术中使用的自生气有N2、O2、CO2、ClO2和混合气五大类型，来源于化学反应和微生物的代谢产物。自生N2主要来自亚硝酸盐和铵盐的氧化还原反应。自生O2则来自过硫酸盐和过氧化物的高温分解。白生CO2来自碳酸盐与酸的反应及含氮类有机物的高温分解。自生混合气包括高能气体和生物气，高能气体是火药或炸药爆燃产生的混合气，生物气是微生物代谢产生的混合气。自生气工作液在油气田现场已应用于固井、射孔、解堵、压裂、调剖和三次采油等广阔的领域。本文概述油气田开发开采中利用五大类自生气的19项工艺技术。参43.