二次型时频分析技术的开发与应用

基于二次型的时频分析是高分辨率时频分析技术的有效方法之一，该项技术能够有效反映时变信号的频谱特性，具有分辨率高、能量集中和跟踪瞬时频率的特点。从时变信号的特点出发，阐述了二次型时频分析技术的基本方法原理，采用正演模型分析验证了该方法的有效性，并在实际地震资料中应用于识别物源方向、划分沉积相带、预测储层结构以及相对厚度等诸多方面，均取得了较好的效果。     

β-hydroxyacyl-coa-dehydrogenase (HADH) activity of unfrozen and frozen—thawed frog (Rana esculenta) legs

The β-hydroxyacyl-CoA-dehydrogenase (HADH) activity of unfrozen and thawed frog legs was investigated. The enzyme was extracted by either immersing frog legs in phosphate buffer 0.1 M, pH 6.0 at 25°C for 15 min or pressing them between trichinoscopy glasses. The enzyme activity was assayed using acetoacetyl-CoA as substrate and measured spectrophotometrically at 340 nm. It was possible by both extraction methods to distinguish between thawed and unfrozen samples although when the juice was obtained by pressing the HADH activity of the dilution was ～ 1.5 times higher than that obtained by immersion. The HADH activity was significantly higher (P≤0·001) in frozen-thawed frogs than in unfrozen legs because during freezing there is a release of HADH. No significative differences were found in the HADH activity in samples frozen in the temperature range -10 to -196°C. HADH activity was not affected by the storage time in crushed ice up to 6 days.     

Enzymatic Browning in Apple Pulps

Enzymatic browning in Golden Delicious apple pulp was studied as related to degree of ripeness and temperature (3.5–31°C). Green apple pulp showed the highest rate of browning. This was attributable to differences in ascorbic acid (AA) content and polyphenoloxidase activity in young fruits. The rate of browning determined by CIE L* measurements followed complex temperature dependent kinetics, represented by a multiple linear effects with log time. Equal changes in L* parameter yielded straight lines in a log temperature vs log time plot. Inhibition with AA caused an initial slow rate of browning and a well defined break point associated with exhaustion of antioxidant properties of the AA. The greater the AA concentration the longer the initial period.     

动情期家兔输卵管上皮及其分泌活动的电镜观察

本实验用透射电镜和扫描电镜观察了动情期家兔输卵管上皮。证实分泌细胞和纤毛细胞都有分泌功能，共分泌三种分泌物质。本文对这些分泌物质的分泌方式、分泌活动进行了研究和探讨。另外，发现上皮基膜下方始终有一层成纤维细胞形成的胞质膜伴行，据此，对血一输卵管腔屏障的构成亦进行了讨论。     

静态水热脱铝处理对HZSM-5分子筛的结构、酸性和催化性能的影响

开发了一种静态水热脱铝的方法。HZSM-5经此法处理后,正戊烷的裂解活性增加,脱氢和芳构化性能加强。可用改变处理温度的方法来控制脱铝的程度。用XRD和吡啶吸附红外技术进行了研究。HZSM-5分子筛催化剂性能的变化用非骨架铝产生的强L酸中心来解释。     

3961连续重整催化剂性能考察

新一代高活性，高水热稳定性3961（PS－Ⅳ）型连续重整催化剂于1996年在上海石化芳烃厂400kt/a连续重整装置上首次进行工业应用试验。开工5a，催化剂跟踪分析结果表明，该剂保持了良好的物化性质和反应性能，表现为良好的比表面积稳定性和持氯能力，经过200个以上再生周期的催化剂未发现有明显的相变和金属分散度的变化。     

碱对AlMCM-41介孔分子筛合成的影响

分别用NaOH和TEAOH合成了AlMCM 4 1介孔分子筛 ,用XRD、2 7AlMASNMR、SEM、TEM、IR、N2 低温吸附和TG DTA对样品进行了表征和比较。结果表明 ,TEAOH和NaOH对AlMCM 4 1有序结构的影响不同。当硅铝原子比为 2 5或 5 0时 ,用NaOH合成的样品有序性较高 ;而当硅铝比为 15时 ,用TEAOH合成的样品有序性较高。交换成氢型AlMCM 4 1后 ,当硅铝比为 2 5或 15时 ,用TEAOH合成的样品抗水解性能优于用NaOH合成的样品 ,其酸量也较大。用TEAOH合成的样品粒度小 ,比表面积、孔径和孔体积都大于用NaOH合成的样品     

蜂胶中具有抗氧化活性的木脂素

利用柱层析方法从蜂胶中分离得到了4种呋喃骈呋喃类木脂素，利用波谱学方法鉴定为芝麻脂素（sesamin）、yangambin、（＋）－松脂素[( )-pinoresinol]和（＋）－丁香脂素[( )-syringaresinol]，其中（＋）－松脂素和（＋）－丁香脂素为首次从蜂胶中得到。利用测定小鼠肝细胞微粒体脂质过氧化抑制作用的方法，检测了所得到的4种木脂素的抗氧化活性，其IC50值范围为9.0-14.0μg/ml。     

Articulating User Needs in Collaborative Design: Towards an Activity-Theoretical Approach

This paper analyses the collaborative design ofa high-technology product, a neuromagnetometerused in the analysis of the activity of thehuman cortex. The producer, Neuromag Company istrying to transform the device from a basicresearch instrument into a means of clinicalpractice. This transition is analyzed as asimultaneous evolution of the product,producer-user network and user activities. Thenetwork is analyzed as a network of activitysystems. Each activity has a historicallyformed object and a motive of its own, as wellas a system of cultural means and expertise. Weuse these to explain and understand theinterests and points of view of the actors inrelation to the product and the contradictionsof the producer-user network. It is suggestedthat the emerging user needs of collectiveactors must be analyzed at three levels. At thefirst level, the use value of the product, itscapacity of solving the vital problems andchallenges of developing user activities, ischaracterized. The second-level analysisconcerns the creation and development of thenecessary complementary tools and services thatmake the implementation and use of the productpossible. This task presupposes collaborationbetween several communities of the innovationnetwork. The third level is the situatedpractical use of the product. In ourexperience, it is advantageous that researcherscontribute with their data to a dialogue inwhich the user needs are articulated.     

钛基Ru-La-Ti涂层阳极的电催化性能

利用热分解法制备了不同La含量的钛基Ru-La-Ti涂层阳极，并研究了所制备涂层的电催化性能。结果表明，在Ru-Ti涂层阳极中掺杂稀土元素La可以提高涂层阳极的电催化活性，且La的掺杂量存在一个最佳范围(La的摩尔分数O．2)。涂层阳极电催化活性提高的原因在于La的引入可以提高涂层的有效活性表面积。