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141.
Hypnosis has been demonstrated to reduce analogue pain, and studies on the mechanisms of laboratory pain reduction have provided useful applications to clinical populations. Studies showing central nervous system activity during hypnotic procedures offer preliminary information concerning possible physiological mechanisms of hypnotic analgesia. Randomized controlled studies with clinical populations indicate that hypnosis has a reliable and significant impact on acute procedural pain and chronic pain conditions, Methodological issues of this body of research are discussed, as are methods to better integrate hypnosis into comprehensive pain treatment. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
142.
Mesoporous GaSBA-15 molecular sieves with different nSi/nGa ratios have been directly synthesized using Pluronic 123 triblock polymer as a structure-directing agent by pH-adjusting method. The mesoporous materials have been characterized using ICP-AES, XRD, N2 adsorption, 71Ga-MAS NMR, SEM and TEM. ICP-AES studies show a high amount of gallium incorporation on the silica pore walls. The structural and textural properties of calcined GaSBA-15 are characterized by XRD and N2 adsorption. 71Ga MAS NMR results demonstrate that a high amount of tetrahedral-gallium could be substituted for Si in the framework of SBA-15. TEM and FE-SEM images show the uniform pore diameter and rope-like hexagonal mesoporous structure of GaSBA-15. These GaSBA-15 materials have been used as catalysts for vapour-phase t-butylation of 1,2-dihydroxybenzene (DHB) for selective synthesis of 4-t-butylcatechol (4-TBC) under different reaction conditions. GaSBA-15(10) gave the highest 93.2% conversion of DHB and 95.7% selectivity of 4-TBC as compared with other GaSBA-15 catalysts. 相似文献
143.
144.
We describe the design and operation of a new high-pressure metal ebulliometer which can operate at pressures to at least 3 MPa in the range 220–400 K. Infinite-dilution activity coefficients are presented for the system CHF2Cl + CF3-CH, at 275 K and for the system CF3-CH2F + CH2F2, at 260, 230, and 300 K. The Wilson activity coellicient model and a virial coefficient model are applied to these systems, and the phase equilibrium conditions are calculated. The results are shown to agree well with predicted and with published measured values. The excess enthalpy is calculated and compared with results from a Peng Robinson equation of state. Vapor densities on the dew curves are given. 相似文献
145.
The influence of different alkali halides (LiF, LiCl. LiBr, NaF, NaCl, NaBr, KF, KCl and KBr) on α-chymotrypsin-catalysed plastein synthesis has been studied in aqueous medium at different substrate concentrations. The results showed an enhancing effect on the plastein synthesis enzyme action by the presence of salts, proportional to salt concentration, which was decreased when the substrate concentration was increased. Additionally, these facts allowed the ions to be classified as a function of their activation power (F? > Cl? > Br?: K+ > Na+ > Li+), which was in agreement with the interpretation of the Hofmeister lyotropic series. The influence of the several phenomena produced by the presence of salts in the plastein reaction, such as, salt-substrate interactions and water activity, as well as the presence of deactivated enzyme was also analysed. The obtained results showed that the substrate concentration is the most important factor, and the activating effect of salts could be simultaneously involved with both a structural change on the substrate conformation and a reduction of water activity into the reaction media, enhancing the catalytic capability of the α-chymotrypsin towards a peptide synthesis action. 相似文献
146.
Microwave irradiation processing (MIP) was considered as a potential method to synthesize perovskite-type oxides rapidly, cleanly and energy-efficiently. In this paper, La0.7Sr0.3MnO3+λ, a kind of promising catalyst for automobile exhaust purification, was successfully prepared by MIP in not more than 5 min. The sol–gel method was also used for comparison. All the samples were evaluated by catalytic activity tests in the simulated exhaust and characterized by XRD, BET, TEM and XRF analyses. The results showed that the integrated perovskite-type phase and uniform particle size were obtained in the microwave-treated samples. And those ones exhibited a better oxidation activity under slightly oxygen-rich condition than that by sol–gel method, which may be related to more A-site cation vacancies and larger bulk oxygen content generated in MIP. Possible formation mechanism of perovskites in MIP was also discussed. 相似文献
147.
Ames试验氯化致突变前体物在净水工艺中的去除研究 总被引:2,自引:1,他引:1
采用水样比活性作为评价指标,从Ames试验结果和致突变前体物性质两方面,探讨了不同单元净水工艺对Ames试验氯化致突变前体物的去除能力,从而为净水工艺的选择提供参考依据 相似文献
148.
以固体三氯化镧为催化剂,以环己酮缩1,2-丙二醇为探针反应,考察了缩酮反应,得到的优化条件为:环己酮0.1 mol,1,2-丙二醇0.12 mol,催化剂用量1.0 g,反应时间90 min,反应温度150℃,10 mL甲苯作带水剂,并在此条件下合成了多种缩酮。实验表明三氯化镧在缩酮反应中具有良好的催化活性,缩酮收率可达90%以上。 相似文献
149.
Latexes with intrinsic crosslink activity 总被引:1,自引:0,他引:1
In order to develop and study ‘two pack in one pot’ systems, i.e. binder systems consisting of a blend of complementary reactive latexes, epoxy- and amino-functional latexes were prepared and characterised, with atte lion especially directed to control of the number of functional groups and control of the molecular weight. The investigation is focused on the control of the molecular weight of epoxy-functional latexes and on the incorporation of amino groups in latexes by using amino-functional methacrylic monomers. To determine the reactivity of the epoxy and amino groups and to check which factors influence the crosslink reaction a number of blends were prepared from both solution and emulsion copolymers and dried at ambient temperatures. It was found that the major factors, which affect the efficiency of crosslinking, are the Tg and the molecular weight of the copolymers and, in the case of a ‘two pack in one pot system’, the rate of the polymer-polymer reaction in relation to that of the polymer-polymer interdiffusion. 相似文献
150.
Yong-Seo Park Seong-Gook Kang Alma Leticia Martinez Ayala Olga Martín-Belloso Shela Gorinstein 《LWT》2006,39(7):748-755
Fresh persimmons were subjected to two different processes: sun-drying during 1 month and dehydration at 60 °C during 12 h. To assess the effect of this process on nutritional and health-related properties of persimmons dietary fibers, minerals, trace elements, polyphenols and the total radical scavenging activities (TRSAs) were determined before and after processing. It was found that the contents of dietary fibers, minerals and trace elements in fresh and dried persimmons fruits were comparable. Total polyphenols in fresh persimmons was higher than in dried fruits (1.3 vs. 0.9 and 0.8 mg/100 g FW, respectively) and percentage of inhibition was higher than in dried fruits (70% vs. 59% and 55% and 58% vs. 53% and 46% for 1,1-diphenyl-2-picrylhydrazyl (DPPH) and 2,2′-azino-bis (3-ethylbenzthiazoline-6-sulfonic acid) [ABTS] radicals, respectively (P>0.05 in all cases). In conclusion: (1) the differences in the contents of dietary fibers, minerals and trace elements in fresh and dried persimmons are not significant; (2) the contents of polyphenols and the level of the TRSA are higher in fresh persimmons than in dried fruits; however, both variables are also high in dried persimmons; (3) when fresh fruits are not available, proper dried persimmons could be used as a valuable substitute. 相似文献