Synthesis of tetramethyl-p-silphenylenesiloxanedimethylsiloxane triblock copolymer by employing living anionic polymerization

Dimethylsiloxane-tetramethyl-p-silphenylenesiloxane-dimethylsiloxane (DMS-TMPS-DMS) triblock copolymer was synthesized by employing living anionic polymerization of hexamethylcyclotrisiloxane (D₃). Two synthetic methods were carried out for the polymerization. One of those methods was the anionic polymerization of D₃ initiated at the silanolate anion which was prepared from the terminal hydroxyl group of silanol-terminated TMPS prepolymer by reaction with n-butyllithium (method 1). The other was the coupling reaction of vinyl-terminated TMPS prepolymer with hydrosilyl-terminated DMS prepolymer obtained from the anionic polymerization of D₃ by using diphenylmethylsilanolate anion as initiator (method 2). In method 1, DMS contents of the copolymers ranged from 25.8 to 72.5 wt% and the values agreed with the ratio of D₃ to TMPS prepolymer. The weight-average molecular weights ranged from 1.36×10⁴ to 19.4×10⁴ and were close to the predicted values calculated from the $\text{M}\text{?}{}_{\mathrm{v}}$ of the TMPS prepolymer and the amount of D₃ added. In the case of method 2, weight-average molecular weights ranged from 19.5×10⁴ to 24.2×10⁴. The high molecular weight copolymer could thus be obtained by method 2. Intrinsic viscosity values of the triblock copolymers agreed with calculated values obtained by considering the copolymer as a binary mixture of these homopolymers. Differential scanning calorimetry and thermogravimetry were carried out on the triblock copolymers. The equilibrium melting temperatures of each of the copolymers were very close to that of poly-TMPS (160°C). The glass transition temperature and heat of fusion were decreased as the DMS content was increased. The thermogravimetric curves for the copolymers indicated that the thermal stability of the triblock copolymer was intermediate between the DMS and TMPS homopolymers.     

Effects of the solvent polarity on the atom transfer radical polymerization of methyl methacrylate initiated by 4‐(chloromethyl)phenyltrimethoxysilane

The controllability of the atom transfer radical polymerization of methyl methacrylate in the polar solvent N,N‐dimethylformamide and the nonpolar solvent xylene with 4‐(chloromethyl)phenyltrimethoxysilane as an initiator and with CuCl/2,2′‐bipyridine and CuCl/4,4′‐di(5‐nonyl)‐2,2′‐bipyridine as catalyst systems was studied. Gel permeation chromatography analysis established that in the nonpolar solvent xylene, much better control of the molecular weight and polydispersity of poly(methyl methacrylate) was achieved with the CuCl/4,4′‐di(5‐nonyl)‐2,2′‐bipyridine catalyst system than with the CuCl/2,2′‐bipyridine as catalyst system. In the polar solvent N,N‐dimethylformamide, unlike in xylene, the polymerization was more controllable with the CuCl/2,2′‐bipyridine catalyst system than with the CuCl/4,4′‐di(5‐nonyl)‐2,2′‐bipyridine catalyst system. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2751–2754, 2007     

定向结晶传递过程的分形研究述评

概述了研究定向结晶过程传递问题的分形方法，并对各类数学模型进行了分析，探讨了进一步研究的方向和途径。     

Optimal linear filter design for systems with correlation in the measurement matrices and noises: recursive algorithm and applications

This paper addresses the optimal least-squares linear estimation problem for a class of discrete-time stochastic systems with random parameter matrices and correlated additive noises. The system presents the following main features: (1) one-step correlated and cross-correlated random parameter matrices in the observation equation are assumed; (2) the process and measurement noises are one-step autocorrelated and two-step cross-correlated. Using an innovation approach and these correlation assumptions, a recursive algorithm with a simple computational procedure is derived for the optimal linear filter. As a significant application of the proposed results, the optimal recursive filtering problem in multi-sensor systems with missing measurements and random delays can be addressed. Numerical simulation examples are used to demonstrate the feasibility of the proposed filtering algorithm, which is also compared with other filters that have been proposed.     

Impacts of new technologies on media usage and social behaviour in domestic environments

Technological infrastructure at home is changing continuously and is becoming increasingly interconnected. Media devices, including the TV set, provide access to the Internet and offer manifold opportunities to consume media on demand. Additionally, personal devices, such as smartphones, also enable flexible consumption and sharing of media. Questions about how these technologies change the user's media usage and how these changes affect the social structure of a household, however, remain largely unanswered. In order to gain insight into the adoption of new technologies into daily routines, we explored these changes in respect of people's media usage in a qualitative long-term Living Lab study. We will present findings regarding personal routines, flexible integration of new devices into existing practices, influences on households as social systems and related issues in device access and collective use. We will highlight potentials and conflicts regarding device shifts and roles; restrictions in device access; social influences in the living room; and individual changes in media consumption.     

Living cationic polymerization of isobutyl vinyl ether (II): Photoinduced living cationic polymerization in a mixed solvent of toluene and diethyl ether

A new method of preparation of living cationic polymer of isobutyl vinyl ether via photoinduced polymerization in the presence of diphenyliodonium iodide (DPII, initiator) and zinc iodide in a mixed solvent of toluene/diethyl ether, which was irradiated at ?78°C for short period, was completed within 15 min. The reaction was allowed for further reaction in the dark until monomer was fully consumed. It was found that increase in the conversion of monomer to polymer during the irradiation is very limited. Confirmation of the linear dependence of number‐average molar mass of resulting polymer on % conversion together with the fact that polymerization proceeds until monomer consumption, and controllability of number‐average molar mass of resulting polymer, depending on the molar ratio of monomer and initiator, strongly suggests the living nature of this polymerization, unless reaction temperature becomes higher than 0°C, i.e., the absence of chain breaking process. The narrow molar mass distribution, whose polydispersity index values are less than 1.2, reveals that the rate of initiation where irradiation is usually completed within 15 min is much faster than that of propagation in cationic nature in this system. Effect of some major factors, such as solvent polarity and temperature, on the living nature of the polymerization was also investigated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3581–3586, 2006     

表面改性活性炭对饮用水中THMs吸附性能研究

通过对活性炭的表面改性，并对氯化消毒后的高色度水进行吸附处理，可使其三氯甲烷（THMs)的含量降低到44μg/dm^3，达到国家生活饮用水质标准。     

北京市雨水收集利用蓄水池容积计算与分析

基于北京市1984—2013年的日降雨资料,以北京林业大学林业楼及其周边绿地为研究区,设置3种用水情景(冲厕、绿地灌溉及冲厕+绿地灌溉),采用连续模拟法,分别绘制3种用水情景下雨水收集利用工程的雨水截留率、自来水替代率、供水保证率以及效益费用比变化曲线,并通过综合分析这些曲线的变化特征确定雨水蓄水池最佳设计容积(60~82 m3)。同时采用设计暴雨法计算1~5年不同重现期的蓄水池设计容积(77~248 m3)。结果表明,连续模拟法计算过程相对复杂,但可用于综合衡量雨水收集利用工程的雨洪管理效益,以及缓解水资源短缺效益、供水可靠性及经济可行性分析。     

Using sketches and storyboards to assess impact of age difference in user experience

We compared two versions of a touch-screen digital thermostat using a framework encompassing several user experience (UX) characteristics, and here describe how the implementation of certain design factors (specialists, praises, tooltips and increased interactivity) was done on mixed-fidelity prototypes of the user interface. We illustrate how the experimental comparison, involving 20 university students and 20 older adults, revealed important differences in UX, including perceived ease of use, behavioral intentions, enjoyment, quality, satisfaction, trust and usability, measured mainly through established questionnaires.Analysis revealed that using that kind of artifacts is a very cost effective way to elicit interesting and useful results; many UX variables are significantly affected by design factors and by age differences, as expected; effects of design factors go well beyond usability and therefore could not be caught by running an investigation focused only on usability.Age difference matters: older adults do not respond to addition of specialists, praises and tooltips as younger users do. We argue that potential benefits of these design choices are outweigh by the increase in complexity of the user interface.From a methodological viewpoint we suggest using a particular array of UX characteristics and metrics when testing mixed-fidelity prototypes. Not all the metrics that we adopted were equally useful, and in particular perceived usability, subjective mental effort, and emotions did not help us highlighting differences.     

基于模糊自适应遗传算法的数据校正方法

针对数据校正中的非线性数据分类还比较困难的问题,提出表上作业法,结合遗传算法同时进行数据协调与过失误差侦破.并将模糊数据协调模型中的三角形约束引入遗传算法界定其变异上下限,还对交叉算子进行自适应改进,从而形成了基于模糊自适应的数据校正方法并用该方法对一个稳态多组分精馏过程进行大量仿真试验,结果表明了算法的有效性.