Continuous precipitation of calcium sulfate dihydrate from waste sulfuric acid and lime

Precipitation of calcium sulfate dihydrate, gypsum, from (i) a pure sulfuric acid/lime suspension and (ii) a waste sulfuric acid/lime suspension in a continuous pilot plant in the temperature range from 40 °C to 80 °C was studied. It was observed that in the case of waste sulfuric acid with a high content of Mg²⁺ and Fe²⁺ ions, several hours after the beginning of the precipitation, partial dissolution of the product and modification of the crystals from needle‐ and plate‐like to agglomerated structures occurred. It is suggested that the secondary changes occur due to the increased concentration of Mg²⁺ and Fe²⁺ ions in the reactor. Below 60 °C, and above 70 °C plate‐like and needle‐like single crystals respectively were formed. The mean size (d₅₀) of the crystals was found to increase with increasing temperature and decrease with the initial concentration of lime. Gypsum produced between 70 °C and 80 °C is suitable for further processing for construction plaster. In a precipitation process with pure sulfuric acid only single perfect needle‐like crystals occurred. Copyright © 2005 Society of Chemical Industry     

锂离子电池有机电解液成膜添加剂的研究现状

文章综述了锂离子电池有机电解液成膜添加剂的作用原理，具体介绍了CO2、SO2、VC化合物、卤化物、有机铜盐以及马来酐等添加剂的研究现状。     

矿山岩土工程系统环境质量评价指标体系

矿山现行的环境影响评价及其提交的环境影响报告书,是将矿山开发视为单个建设项目且只注重污染物排放和简单数量分析的单要素评价.本文将矿山开发视为统一系统,充分考虑系统内矿石开采、废石场、尾矿库等岩土工程及其矿岩氧化淋滤产生的毒害物质对矿区及其区域水土环境潜在而长期的影响,建立矿山岩士工程系统环境质量评价的指标体系,以改变矿山环境评价的传统旧式,规范和监督矿山开采行为,实现矿业开发与环境保护的协调发展.     

免化学试剂-离子色谱法测定小麦粉中溴酸钾的不确定度评定

利用离子色谱法测定了小麦粉中溴酸盐,对溴酸盐测量不确定度的来源进行了分析和量化评定.实验测得:当小麦粉中的溴酸盐含量为0.42mg·kg-1时,扩展不确定度为0.08mg·kg-1(k=2).     

Hydrogen production in solid electrolyte membrane reactors (SEMRs)

In the present work, the prospects and trends of solid electrolyte membrane reactors (SEMRs) towards hydrogen production, are discussed. Initially, an overview of the principles, the properties and the techniques related to the usage of the SEMRs, are presented. In the following, a literature survey covering earlier and recent developments of the various methods (e.g. reforming or partial oxidation or dehydrogenation of hydrocarbons, steam electrolysis) employed in the SEMRs for the production of hydrogen, is performed. Finally, the current status of this research field is analyzed and future research topics are proposed.     

新型香料苹果酯-B的合成

以硫酸高铈为催化剂,通过乙酰乙酸乙酯和1,2-丙二醇反应合成了苹果酯-B,研究了各有关因素对产品收率的影响。实验表明,硫酸高铈是合成苹果酯-B的良好催化剂,在酯醇物质的量比为1∶1.25、催化剂用量为0.3g/0.1mol乙酰乙酸乙酯、环己烷10mL、反应时间2h的条件下,苹果酯-B的收率可达91.5%。     

硫酸钙氨法制取硫酸钾新工艺的实验研究

利用K2 +2 ,Ca2 +/ /SO2 -4 ,Cl2 -2 ,NH3—H2 O混合体系相图作为工艺指导 ,进行硫酸钙制取硫酸钾工艺的相图研究和分析 ,确定实验优选因素及水平并进行正交实验 ,根据实验结果进行极差分析 ,得出新的结论。合适的工艺条件为 :氨浓度为 40 % ,配料比n( 2KCl) :n(CaSO4 ·2H2 O)为 1:1,反应温度为 5℃ ,反应时间为 1h。     

离子束辅助沉积制备高功率激光薄膜的研究

综述了离子束辅助沉积技术在高功率激光薄膜制备中的应用研究进展.指出该技术在制备高激光损伤阈值的薄膜中存在的问题,即出现过高的堆积密度,会给薄膜带来杂质缺陷、化学计量比缺陷、损伤缺陷、晶界缺陷,制备薄膜的残余应力存在着压应力增加的趋势,会改变薄膜的晶体结构等.并指出了该研究领域的研究方向.     

硫酸锆、碳酸锆的性质、应用及生产技术综述

综述了硫酸锆，碳酸锆产品的性质，生产技术及应用，收集整理了国内外部分厂家和公司该产品的化学指标与生产技术；介绍了“分步液相沉淀法”生产工艺，与“一步法”生产工艺相比，其具有流程短，投入少，操作简单，制造成本低等优点。     

SDS/正戊醇/水体系的液晶研究

在 2 5℃测定了十二烷基硫酸钠 (SDS) /正戊醇 /水三元体系的相平衡 ,确定了液晶区域的边界范围。在液晶区域内选取一系列样品点 ,用差示扫描量热法 (DSC)和2 HNMR与液晶照片对照 ,研究了该体系的液晶结构特点。结果表明 :在恒定温度下 ,该体系存在着两个液晶区域 ,并且随含水量的增加 ,液晶结构发生变化。当组成固定时 ,体系的液晶相结构随温度升高也发生变化