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41.
The photoluminescence properties of BiTaO4∶Pr3+ and BiTaO4 at room temperature were studied, and the infrared transmission and diffusion reflection spectra of BiTaO4 were measured. The photoluminescence spectrum of BiTaO4 peaks at about 420, 440 and 465 nm. There has an obvious excitation band from 330 to 370 nm. The photoluminescence spectrum of BiTaO4∶Pr3+ consists of the characteristic emission of Pr3+, and its main peak is at 606 nm from 3P0→3H6 transition of Pr3+. Its excitation spectrum consists of the wide band with maximum at 325 nm, the wide band in the range of 375~430 nm, and the characteristic excitation of Pr3+. The bands at 325 nm and 375~430 nm may be from the absorption of the charge transfer transition of the tantalate group and defect energy levels in its forbidden band, respectively. There is energy transfer from host to Pr3+. Because both the host density and photoluminescence peak intensity of BiTaO4∶Pr3+ are superior to PbWO4, BiTaO4∶Pr3+ may be a potential heavy scintillator. 相似文献
42.
In this paper, any two of the three anticorrosion agents, that is emulsifier (OP-10), soluble glass (Na2O·nSiO2) and glycerin (C3H8O3), were treated simultaneously on the surface of amorphous (a-) MgNi+5% Ml2Mg17 (Ml denotes the lanthanum-rich mish metal) electrode and the electrolyte. Effect of the synergistic anticorrosion treatment on charging/discharging cycle stability of the electrode was investigated. Contrasted with single treatment method, the cycling stability of the electrodes was further improved. The desirable synergistic anticorrosion method was that the electrode was treated by the soluble glass, and that OP-10 was added into the electrolyte. The cyclic voltammogram (CV) results of the electrode show clearly that the anticorrosion agent can change the electrochemical activity and mechanism of the electrode. The concentration of the anticorrosion agent in the electrolyte treated by the synergistic anticorrosion method was also investigated. The appropriate concentration of the anticorrosion agents in the electrolyte is 0.143%. 相似文献
43.
D.W. McKee 《Carbon》1985,23(6)
The behavior of a number of rare earth oxides as catalysts for the oxidation of graphite in air has been investigated by the methods of thermal analysis. Of the oxides studied, only CeO2 showed significant activity in accelerating the gasification of graphite by oxygen between 500 and 1000°C. Cerium salts, which decompose to a finely dispersed oxide phase at low temperatures, e.g. Ce (III) nitrate and ammonium Ce (IV) nitrate, were found to be very active catalysts. The catalytic effect may be due to a redox process involving the cyclic conversion of the oxide from the Ce (IV) to the Ce (III) oxidation state, or the oxide particles may provide sites for the dissociative chemisorption of oxygen. 相似文献
44.
Colour Centres and Energy Transfer in BaF2-xClx:Eu2+ Phosphors 总被引:1,自引:1,他引:0
The optical absorption spectra of BaF2-xClx:Eu2 after ultraviolet (UV) light excitation were investigated.The differences between the absorption spectra after and before excitation (DAS) were observed.The DAS increase at both the high and the low energy side of F band in BaF2-xClx:Eu2 after 245 nm UV light excitation.The bleach effect of UV light and the absorption of electrons in the valence band may account for the former and the formation of Fa centres (association of F(Cl-) centres), whose absorption band matches the HeNe laser better, may explain the latter.In the write-in process, the transfer of electrons is via tunneling.In the readout process, the transfer of electrons captured in F(F-) and Fa centres is more likely via tunneling, and that of F(Cl-) centres is more likely via conduction band. 相似文献
45.
Yan Jianhui Zhang Houan Tang Siwen Li Yimin 《中国稀土学报(英文版)》2006,24(5):548-548
The oxidation behavior of 0. 8% La2O3- Mo5Si3/MoSi2 composites at 1200℃ in air was investigated. The results reveal that the oxidation resistance of the material with 0. 8% La2O3 and Mo5Si3 is impaired. The oxidation resistance is decreased with increasing Mo5Si3 content. The mass loss follows a linear law in the initial oxidation. With oxidation time prolonging, a continuous and dense oxidation scale prevents oxygen from diffusing increasing when and leads to mass change a Mo5Si3 content is less than 30%. However, the composite shows "PEST" with the addition of 40% Mo5Si3. With increasing Mo5Si3 content, the oxidation resistance of 0.8% La2O3- Mo5Si3/MoSi2 decreases. This attributes to the poor oxidation resistance of M05Si3 and the relative density decreasing of 0. 8% La2O3-Mo5Si3/MoSi2 composite. 相似文献
46.
Yu Shichang Wu Shenqing Gong Youjun Gong Yuansheng Lian Mingsheng Ye Gang Cheng Yijun 《中国稀土学报(英文版)》2006,24(1):120-120
Grain growth behavior of 5Cr21Mn9Ni4NRE steel was experimentally studied at various solid solution treatment temperatures and holding for different times. The experimental results show that the 5Cr21Mn9Ni4NRE steel has the feature of sharp austenite grain coarsening after solid solution treatment at the temperature above 1150 ℃. RE added in the steel has the benefit to restrain grain growth and increase grain growth activation energy. 相似文献
47.
A new method of studying the corrosion inhibition mechanism of rare earth metal(REM) on LC4 Al alloy with the spilt cell technique was studied. The principle and experimental method of the spilt cell technique were analyzed. By measuring the change of net-electric current between the two electrodes caused by the change of the amount of oxygen in the solution and the addition of CeCl3, the influence of corrosive performance of CeCl3 on LC4 super-power aluminum alloy in the 0.1 mol·L−1 NaCl solution was investigated. Meanwhile, the conditional changes of pH values, CeCl3 solution, additire and time of performance were also studied. Finally, the features of electrode surface were revealed by using SEM and X-ray energy-dispersive spectrometry (EDS). By combining these with other electric chemical techniques, such as potential-time curve, polarization curve et al. 相似文献
48.
Polyelectrolite hydrogels are crosslinked polymers which display high sorption capacity in water and water solutions. They are widely used in the marked of personal hygiene products, as well as in other biomedical and industrial applications. In the most industrial application they are not biodegradable and prepared starting from acrylamide.In this work, the chemical-physical analysis of a novel class of natural polymers-based microporous superabsorbent hydrogels has been presented. The main focus is the definition of the relationship between material's chemical-physical structure and its equilibrium sorption properties.The effect of the variation of the degree of crosslinking, the polyelectrolyte nature of the backbone and the hydrogel microporosity on its swelling properties has been analysed, and a good agreement with the theoretical statements has been displayed.The effect of the ionic strength and the pH of the external solution in contact with the hydrogel on its equilibrium sorption properties has also been assessed, and an high sensitivity to these variations was detected for all the tested chemical compositions and physical structures.This work have to be considered part of the efforts towards the reduction of the environmental impact of the large scale consumption industrial polymer based products. 相似文献
49.
BaMgAl10O17∶Eu2 (BAM) was prepared in the microemulsion system and its phase behavior was studied. There exists a small region in the reverse microemulsion system where the dispersed particles are of spherical form. In this way, BAM blue phosphor with good dispersion can be synthesized. The microemulsion phase diagrams of the pseudo-ternary system (Triton X-100/cosurfactant-oil-BAM brine) were first established intuitively by the dilution method. The microstructure of microemulsions was determined through eyeballing, conductance technique, and polar optical microscopy. Its phase behavior is affected by various factors, such as temperature (room temperature, 30, 40 ℃), oil, surfactants, and cosurfactants in microemulsions. According to the phase diagrams, the microemulsion system of Triton X-100/1-hexanol-hexane-BAM brine was chosen to prepare the precursor. The BAM phosphor can be obtained via sintering the precursor at a comparatively low temperature. The phosphors were characterized by XRD and vacuum ultraviolet (VUV) spectra. 相似文献
50.