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101.
The reactions of water vapor and oxygen with liquid uranium were studied by modulated molecular-beam mass spectrometric methods. Equivalent pressures of the reactant fluxes on the surface ranged from 6×10
–6
to 2×10–4
torr. Temperatures up to 1570 K were investigated. The metal surface was kept clean during reaction by mechanical removal of the oxide formed with a tungsten needle. For the clean liquid uranium surface, a water reaction probability of 0.4 was deduced both from measurement of the reaction-product hydrogen signal and by the temperature dependence of the scattered reactant signal. Based solely on the latter measure, a reaction probability of 0.6 was estimated for oxygen. The reaction probabilities on the clean surface were temperatureindependent. They decreased as the coverage of the surface by islands of oxide increased and, for water, appeared to approach a value of 0.08 for a surface completely covered with an oxide estimated to be 500 Å thick. Bombardment of the surface during reaction with argon ions produced an increase in the reactivity on solid uranium but had a negligible effect on the reaction probability for the liquid. 相似文献
102.
混合溶剂对Ru(Ⅳ)萃取的研究 总被引:2,自引:0,他引:2
一、前言 在一定浓度盐酸介质中,Ru(Ⅳ)以RuCl_6~(2-)络阴离子状态存在,可被C类溶剂TOA(三辛胺)以离子缔合机制定量地萃入有机相。由实验得到在相同条件下,TOA对Ru(Ⅳ)的萃取率随稀释剂介电常数的增加而下降。 相似文献
103.
Z. Bukowski K. Gofryk T. Plackowski D. Kaczorowski 《Journal of Alloys and Compounds》2005,400(1-2):33-36
Single crystals of UNi0.5Sb2 were investigated by means of Seebeck coefficient and Hall effect measurements in the temperature range 5–300 K. The results corroborated the occurrence of two magnetic phase transitions: from para- to antiferromagnetic state at TN = 161.5 K and a spin-reorientation near Tt = 64 K. The first-order character of the latter feature was proved by studying in detail the electrical resistivity and the magnetic susceptibility of single-crystalline UNi0.5Sb2 in the vicinity of Tt. 相似文献
104.
通过萃取复型观察和对衍射花样的标定,研究了深层渗碳过程中析出碳化物的形态和分布。实验结果表明:渗碳过程中析出的形态较好的碳化物,象点状、球状和椭球状碳化物均为钼的碳化物;而形态较差的针状、网状则为(Cr、Fe)7C3和(Fe,M)3C。并对其形成机理进行了初步探讨。 相似文献
105.
Influence of molybdenum on passivation of polarised stainless steels in a chloride environment 总被引:2,自引:0,他引:2
Polarised specimens of AISI 304L and 316L stainless steels (SS) were studied using X-ray photoelectron spectroscopy in conjunction with Ar+-ion sputtering. A 5% NaCl test solution was used at room temperature. The polarised passive films formed consist mainly of chromium oxide and hydroxide and a small proportion of iron oxides. The composition of the films depend strongly on the potential. Chloride and molybdenum ions appear when the AISI 316L SS alloy is polarised at a potential close to pitting potential. 相似文献
106.
107.
108.
The corrosion inhibition of cold rolled steel in 0.5 M sulphuric acid in the presence of o-phenanthroline and sodium chloride (NaCl) has been investigated by using weight loss and electrochemical techniques. The experimental data suggest that the inhibition efficiency increases with increasing NaCl concentration in the presence of 0.0002 M o-phenanthroline, but decreases with increasing temperature. A synergistic effect is observed when o-phenanthroline and chloride ions are used together to prevent cold rolled steel corrosion in 0.5 M sulphuric acid. The polarization curves showed that the complex of o-phenanthroline and NaCl acts as a mixed type inhibitor. The experimental results suggested that the presence of chloride ions in the solution stabilized the adsorption of o-phenanthroline molecules on the metal surface and improved the inhibition efficiency of o-phenanthroline. The adsorption of the complex accords with the Langmuir adsorption isotherm. Some thermodynamic parameters such as adsorption heat, adsorption entropy and adsorption free energy have been calculated by employing thermodynamic equations. Kinetic parameters such as apparent activation energy and pre-exponential factor have been calculated and discussed. 相似文献
109.
The extraction of TiO~(2+),VO~(2+),VO_2~+ and MoO_2~(2+)by HDEHP,HEHEHP and HDTMPP was studiedrespectively.The orders of extraction ability for the three extractant systems are as follows:for TiO~(2+),VO~(2+):HDEHP>HEHEHP>HDTMPP;for VO_2~+, MoO_2~(2+):HDEHP< HEHEHP< HDTMPP.The experimental results were discussed from the point of view of extractant structures. 相似文献
110.
Characterization and wear behavior of modified silicon nitride 总被引:3,自引:0,他引:3
E. Carrasquero A. Bellosi M.H. Staia 《International Journal of Refractory Metals and Hard Materials》2005,23(4-6):391-397
Silicon nitride-based materials are applied to many tribological components because of their superior thermal and mechanical properties and corrosion resistance. The purpose of this study is to investigate the wear performance of modified silicon nitride which contained 3 wt.% La2O3 and 3 wt.% Y2O3. The relationships between microstructure and mechanical properties have been also addressed. Vickers microhardness and toughness were measured, the later being determined by means of the direct crack measurement method (DCM). Scanning electron microscopy technique (SEM) coupled with energy dispersive X-ray spectroscopy (EDS) was used for the morphological characterization of the samples as well as for the characterization of the wear scars. Wear properties were studied under a load of 10 N by using the ball-on-disk tribometer. AISI 52100 steel balls and balls of WC + 6% Co (6 mm diameter) were used as static counterparts, respectively. Steady state friction coefficients of 0.66 and 0.62 were measured for the tribological pairs WC + 6 % Co/Si3N4 and AISI 52100/Si3N4, respectively. The wear mechanism was determined in each case, and comparison between the wear performance of the traditional and modified silicon nitride is also presented. 相似文献