最少量化在实验研究产生的放射性废物管理中的实施

通过源项的引入控制、实践正当化、安全与防护最优化、废物产生的课题化管理、分类收集分别处理等措施的实施，落实废物最少量化在核科研中的实施，减少对环境的危害，降低废物处理处置费用，促进核技术的发展应用。     

废气余热驱动制冷管的制冷特性研究

本文研究了一种应用于工程车司机驾驶室的新型制冷管的制冷性能.本文对以分子筛-水为吸附工质对的制冷管内的水充注量进行了研究,建立了相关的试验装置,测量了制冷管内部的动态压力变化和温度变化以及制冷量.试验表明,制冷管内制冷剂水的充灌量对制冷管的性能影响很大.     

废石充填采矿法在新桥矿的实践

新桥矿通过合理利用井下矸石及露天部分废石进行充填，解决了矿山充填原料的不足，降低了生产成本。清洁了矿山环境，保障了矿山可持续发展。     

ICP-AES法测定废水中七种元素

取废水 5 0ml,加入 1mlHNO3 ,在电炉上消化之后 ,过滤进 5 0ml比色管中 ,直接用ICP -AES法对Cu、Pb、Fe、Mn、As、Be等元素进行定量分析     

Characterization of Clay Particle Surfaces for Contaminant Sorption in Soil Barriers Using Flow Microcalorimetry

Clays such as kaolinite and bentonite are widely used in various industries as sorbents. The sorptive characteristics of clays are exploited when they are used in contaminant barrier systems. To use clays effectively, their surface characteristics need to be known; especially, when they are used for contaminant sorption. Available surface area of clay minerals and the characteristics that depend on it are very sensitive to environmental changes such as those that can be induced by changes in the composition of pore fluid. Flow microcalorimetry with a down-stream concentration was used to determine the heats and amounts of adsorption of acids and bases on the clays. Test results presented herein revealed that both kaolinite and bentonite exhibit significantly different adsorption isotherms and heat of wetting under high pH and low pH conditions. Kaolinite has the capacity to adsorb both acidic and basic molecules almost equally. However, it has a tendency to adsorb more base than acid because of its stronger complexation capacity with acids than with bases. On the other hand, bentonite has a tendency to adsorb more acidic than basic molecules per gram. These results also indicate that both kaolinite and bentonite have different heats of wetting characteristics. As the concentrations of the acids and bases increase, the heat of wetting of kaolinite decreases while that of bentonite increases.     

Constructive heuristics for the Mixed Capacity Arc Routing Problem under Time Restrictions with Intermediate Facilities

The Mixed Capacity Arc Routing Problem under Time Restrictions with Intermediate Facilities (MCARPTIF) is an extension of the Arc Routing Problem under Capacity and Length Restrictions with Intermediate Facilities (CLARPIF) with application in municipal waste collection. This paper evaluates four constructive heuristics capable of computing feasible solutions for the MCARPTIF with a primary objective to either minimise total cost or to minimise the fleet size. The heuristics were adapted from Path-Scanning and Improved-Merge for the Mixed Capacitated Arc Routing Problem, and compared against two Route-First-Cluster-Second heuristics for the MCARPTIF. The objective was to identify the best performing heuristic for application purposes. In practice, the CARP is often solved for real-time or near real-time decision support. Computational time required by the heuristics was thus also evaluated. Identifying the best heuristic proved difficult due to a lack of realistic MCARPTIF benchmark sets, with the two CLARPIF sets predominantly solved in the literature not resembling actual waste collection instances. Route-First-Cluster-Second heuristics, linked with a new vehicle reduction heuristic performed the worst on the two CLARPIF sets, yet performed the best on new waste collection sets taken from the literature and introduced in this paper. Improved-Merge performed the best on two existing CLARPIF sets and on a realistic set with Intermediate-Facilities incident with the vehicle depot, but struggled on all other sets and in minimising fleet size. Path-Scanning was the most robust heuristic, performing reasonably well on all benchmark sets and both objectives. Results further show that due to the high computational time of one of the Route-First-Cluster-Second heuristics, which was only exposed on realistically sized sets, the slightly worse version is the best alternative when real-time support is required for waste collection applications.     

Introducing a proper hydrogen liquefaction concept for using wasted heat of thermal power plants-case study: Parand gas power plant

A hydrogen liquefaction concept with an innovative configuration and a capacity of 4 kg·s^-1 (345.6 t·d^-1) is developed. The concept involves an ammonia absorption refrigeration system for the pre-cooling of hydrogen and MR streams from 25 ℃ to -30 ℃. The ammonia absorption refrigeration system is fed by exhaust gases of the Parand gas power plant that are normally dissipated to the environment with a temperature of 546 ℃. The simulation is performed by Aspen HYSYS V9.0, using two separate equations of state for simulating hydrogen and MR streams to gain more accurate results especially for ortho-para conversion. Results show that conversion enthalpy estimated by Aspen HYSYS, fits very well to the experimental data. Determining the important independent variables and composition of MRs are done using trial and error procedure, a functional and straightforward method for complicated systems. The minimum temperature limit in the cooling section is lowered, and an ortho-para converter is implemented in this section. The proposed concept performs well from energy aspects and leads to COP and SEC equal to 0.271 and 4.54 kW·h·kg^-1, respectively. The main advantage of this study is in the low SEC, eliminating the losses of the distribution network, and improving the ability of the hydrogen liquefaction for energy storage in off-peak times.     

Investigation of the MSFR core physics and fuel cycle characteristics

The adoption of Th fuel in fast reactors is being reconsidered due to the potential favorable impact on actinide waste management and resource availability. A closed Th cycle leads to an actinide inventory with lower radiotoxicity and heat load for the first several thousands of years. Due to the typically low TRansUranic (TRU) Conversion Ratio (CR), Th can also be advantageous to expedite the consumption of legacy TRU. One of the main obstacles to the implementation of Th is the highly radioactive recycled fuel which requires remote handling under heavy shielding, inevitably penalizing economics and challenging conventional pin-based fuel manufacturing. From this perspective, the development of liquid-fuelled reactors, with Molten Salt Reactors regarded as the most promising, appears particularly attractive as fuel handling would be greatly simplified. The present paper investigates the fuel cycle performances of the reference GEN-IV Molten Salt Fast Reactor (MSFR) in terms of isotope evolution, radiotoxicity generation and safety-related parameters. Similarly to most MSR concepts proposed in the past, the MSFR is based on the fluoride molten salt technology, but it features the novelty of a fast neutron spectrum. Calculations are performed using state-of-the-art equilibrium-cycle methodologies, i.e., the ERANOS-based EQL3D procedure developed at the Paul Scherrer Institut and extended to the simulation of the MSFR. Selected results have been benchmarked with the Monte Carlo code PSG2/SERPENT. These results have also been used for the assessment of a diffusion module based on the COMSOL multi-physics toolkit, which is the subject of current studies aimed at efficiently simulating the peculiar MSFR transient behavior.     

Experimental study on foam glass prepared by hydrothermal hot pressing-calcination technique using waste glass and fly ash

Foam glass is a lightweight and high-strength building and decoration material with superior performance in heat insulation, sound absorption, moisture resistance and fire protection. The use of waste glass powder and fly ash to prepare foam glass is one of the most important ways to utilize solid waste as a resource. In this study, waste glass powder and fly ash were used as raw materials to prepare foam glass by a hydrothermal hot pressing–calcination method. The effects of fly ash content (0 wt%, 10 wt%, 20 wt%, 30 wt%), heating rate (1 °C/min, 3 °C/min, 5 °C/min, 8 °C/min, 10 °C/min) and calcination temperature (600 °C, 700 °C, 750 °C, 800 °C, 850 °C, 900 °C) on the microscopic morphology, density, compressive strength, porosity and other properties of the foam glass samples were studied. Their microstructure and morphology were analyzed by thermogravimetric analysis–mass spectrometry, X-ray diffraction, scanning electron microscopy and Fourier transform infrared spectroscopy. At a fly ash content of 10 wt%, the heating rate was 5 °C/min, the calcination temperature was 800 °C, the foam glass density was 0.3 g/cm³, the compressive strength was 1.65 MPa, the total porosity was 75.5%, and the effective thermal conductivity was 0.206 W/m·K. The effective thermal conductivity models of the composite materials were used to verify the experimental data. The relationship between the thermal conductivity of foam glass materials and the related influencing factors was investigated.     

Partial replacement of metakaolin with red ceramic waste in geopolymer

Metakaolin was incrementally replaced (33.3%, 50% and 66.6%) by red ceramic waste in geopolymer formulation to study the effect on geopolymerisation and its resultant properties. The geopolymer binders composed of two calcined aluminosilicates (viz. Metakaolin and Red ceramic waste), NaOH and sodium silicate. In the experimental compositions, metakaolin was replaced gradually up to 66.6% in the clay fraction, the Si/Al increased from 3.36 to 5.16 and Na/Al increased from 0.93 to 1.38. The FTIR spectroscopic studies of geopolymer pastes along with XRD analysis indicated that the red ceramic waste partly reacts with alkali and takes part in geopolymer formation. Replacement of 33.3% metakaolin by the red ceramic waste in geopolymer binder did not reduce the compressive strength with respect to the pure metakaolin geopolymer here. Additional replacement resulted in a drastic decrease in the compressive strength of the geopolymer binder. However, the compressive strength of geopolymer mortars revealed interesting synergy between the amount of binder and particle packing in the mortar. Despite having a lower amount of binder phase, mortars with 33% and 50% red ceramic waste exhibited maximum compressive strength values. This has been attributed to improved particle packing through incorporation of red ceramic waste particles.