Emission of trace toxic metals during pulverized fuel combustion of Czech coals

A study of the trace elements emission (As, Se, Cd, Co, Cr, Cu, Zn, Hg, Tl, Pb, Ni, Sn, Sb, V, Mn and Fe) from pulverized coal combustion has been made at six heating and power stations situated in the Czech Republic. The amount of chlorine in coal has considerable influence on volatilization of some elements such as Zn, Cu, Pb, Hg and Tl, which is explained by the formation of thermodynamically stable compounds of these elements with chlorine. Generally, the affinities for Cl follows the order Tl > Cu > Zn > Pb > Co > Mn > Sn > Hg. The experimental data indicates enrichment of some of the trace toxic elements in the emissions (Cu, Zn, As, Se, Cd, Sn, Sb, Hg and Pb) and good agreement was obtained by thermodynamic equilibrium calculations with a few exceptions. In the case of Fe, Mn, Co, Cr and Sn calculated values are overestimated in the bottom ash and there are zero predicted amounts of these elements in the fly ash. In comparison, the results from experiments show up to 80% of these elements retained in fly ash. This implies that there exist additional steps leading to the enrichment by Fe, Mn, Co, Cr and Sn of small particles. Such mechanisms could include the ejection during devolatilization of small inorganic particles from the coal of bottom ash particles, or disintegration of the char containing these metals to small particles of fly ash. On the other hand, there are slightly overestimated or similar values of relative enrichment factors for As, V, Cu, Cd, Sb, Tl and Pb in the fly ashes and zero predicted values for bottom ashes. Our experimental results show about 5% or less of these elements are retained in bottom ashes, so they probably remain in the bottom ash inside unburned parts of coal. Copyright © 2003 John Wiley & Sons, Ltd.     

40kg试验焦炉的研制

文章介绍了40kg试验焦炉，分析和比较了试验焦炉与生产焦炉的差异，指出它们之间的模拟条件是炭化室宽度、煤料堆密度、炼焦速度和单向传热。     

本钢炼焦煤最佳配比分析

结合本钢的生产实际，对炼焦煤的最佳配比作了比较具体的分析，同时对资源，质量、成本也作了比较详细的调查，并提出了本钢焦化厂最佳配煤比方案，由此可看出，最大限度地降低采购成本，继续开发合理的配煤比例，具有广阔的前景。     

新疆三塘湖盆地侏罗系煤有机地球化学特征

有机地球化学和有机岩石学研究结果表明，新疆三塘湖盆地侏罗系煤中富集孢子体和角质体（３．０％～６．０％，全岩体积百分比），对煤中氯仿沥青“Ａ”组成中较高的总烃馏分（３０％～５０％）和饱芳比（０．６～３．０）产生了影响。煤的聚集环境是影响煤的显微组分组成及生油特性的关键因素。三塘湖盆地侏罗系煤属于“晚生晚排”叠加有“早生早排”类型的烃源岩。     

锚网支护在综采工作面开切眼中的应用

介绍了平煤集团一矿在戊8— 310 40综合机械化采煤工作面开切眼实施煤巷锚网支护的基本情况。总结了经验 ,为同类条件下的锚网支护设计提供了依据。     

Apparent versus true density for the volume-to-weight transformation in coal blends

This work reviews the procedures involved in the conversion of the petrographic characterization data of blended coals into weight percentages of the single coals in the blends, the selection of the most suitable parameter for describing the density of the coals being critical. First, the fundamentals of the volume-to-weight transformation of the petrographic data were developed by means of mathematical formulae. This part of the procedure highlighted the need to use a density value adapted to the resolving power of the optical microscope. It was found that mercury penetration at 5 MPa, as determined by mercury porosimetry, was best suited for this purpose. A literature survey of published coal density data revealed that the use of correlations between coal density and rank was not an accurate enough procedure to deal with the relatively low corrections involved in the transformation of petrographic data. In the end, three binary blends were prepared from six carefully selected coals and polished particulate blocks of these blends were petrographically analysed to determine their compositions on a volume per cent basis. The best fit of these volume percentages with the weight percentages used in the formulation of the blends was found for a density correction based on mercury penetration at 5 MPa, in agreement with the empirical analysis.     

山西煤焦流通市场化改革建议

本文分析了山西在推进煤炭流通市场化过程中面临的机遇及现行体制弊端,提出建立更加适合市场经济的煤焦流通体制的若干建议。     

LLL1030新型煤泥离心脱水机的设计与结构

阐述了筛篮倾角为20°的LLL1030新型煤泥离心脱水机的结构和主要技术特征,在综合分析国内、外主要设备类型的基础上,对该新型煤泥离心脱水机的主要参数进行了设计。给出了设计思路,并从分离因数、筛篮倾角、物料在脱水区的停留时间、生产能力、功率消耗和电机选用等多方面进行了相应的分析。     

煤燃烧系统中碳黑的研究进展

碳黑对人类健康和环境辐射平衡有重要的影响.火焰中的碳黑,可以增强辐射换热效果,碳黑也影响氮氧化物的生成和排放.当煤不完全燃烧时,煤的挥发分在高温时发生二级反应,形成碳黑.介绍了研究碳黑的3种模型和3种实验方法.     

引渤济锡海水输送工程

引渤济锡海水输送工程是内蒙古锡林郭勒盟恢复草原生态和实施以发展电力和煤化工为主体的褐煤开发战略的基础工程。该工程是从渤海引海水，通过辽宁省的葫芦岛市、朝阳市和内蒙古的赤峰市到锡林浩特，本阶段设计年输海水3．65亿甜。该工程将与锡林格勒盟地区待建的煤化工、海洋化工、生态工程形成新型的循环经济发展产业链。长距离输送海水是一个世界性的新课题。现研究了长距离海水输送的特点，提出了应对海水强腐蚀、海生物附着所引起的污损问题和输送过程中防泄漏和渗漏问题的工程措施，采用一条夹砂玻璃钢管管线结合隧洞和一座在线调节水库的输送海水方案，包括：设9座泵站，设计总扬程1147m海水水头，线路全长607km左右，其中玻璃钢管全长290km，直径3．2km，隧洞全长317km，输海水总成本为4．1元／m左右。引渤济锡海水输送工程的建立，标志着我国海水综合利用进入一个新的历史阶段，工程本身具有下述特点：输送海水流量、距离、扬程综合指标，世界第一；内径3．2m夹砂玻璃钢管是国内目前采用的最大管径的玻璃钢管。此外，引渤济锡海水输送工程的建设不仅能够促进锡林郭勒盟地区经济的持续发展，而且具有下述重大战略意义：一是通过“盐田置换”方式促进环渤海经济区建设；二是为发展制盐工业提供了新的发展模式；三是为我国开发内蒙古、新疆维吾尔自治区巨大的煤炭资源、恢复生态系统提供了一条新的思路。