咪唑啉型缓蚀剂的合成及其缓蚀机理的研究

以棕榈酸、二乙烯三胺、马来酸酐为原料合成了一种咪唑啉型缓蚀剂YQ-01,与YQ-02复配后得到能有效抑制二氧化碳腐蚀的缓蚀体系YQ-03。应用静态挂片失重法、电化学极化曲线、X射线光电子能谱分析研究了YQ-03抑制二氧化碳腐蚀的电化学特征,分析了腐蚀前、后及加入缓蚀体系YQ-03后A3钢的表面产物,探讨了YQ-03的缓蚀机理。结果表明,由主剂YQ-01和助剂YQ-02组成的复配缓蚀体系有良好的协同作用,腐蚀产物膜有3层,能有效抑制饱和CO2的高矿化度盐水对A3钢的腐蚀。     

并联机床的历史、现状及展望

本文介绍了并联机床的基本概念、分类方法及其基本特性，详细地阐述了并联机床在国内外的发展历史、研究状况以及关键基础零部件的发展状况，在此基础上，分析了并联机床结构上的优缺点，表明了并联机床走向实用化所面临的一些问题，本文的最后对并联机床的发展趋势作了展望。     

提高6063铝合金导热性能的途径探讨

采用试验的方法探讨了镁硅质量比、微量稀土及热处理制度对6063铝合金导热性能的影响。研究结果表明：6063铝合金采用1．73的Mg、Si质量比，加入0．3％稀土，经挤压后在250℃进行退火，然后随炉冷却，热导率比原来提高了9．5％。     

Temperature and grain size dependence of superplasticity in a Zn−0.3wt.%Al alloy

The superplastic deformation behavior of quasi-single phase Zn-0.3 wt. %Al was investigated. A series of load relaxation and tensile tests was conducted at various temperatures ranging from RT (20 °C) to 200 °C. The recently proposed internal variable theory of structural superplasticity was applied. The flow curves obtained from load relaxation tests were shown to consist of contributions from interface sliding (IS) and accommodating plastic deformation. In the case of quasi-single phase Zn-0.3 wt.% Al alloy with an average agrain size of 1 μm, the IS behavior could be described as a viscous flow process characterized by a power index of M_g=0.5. A large elongation of about 1400% was obtained at room temperature and the strain rate sensitivity parameter was about 0.4. Although relatively large-grained (10 μm) single phase alloy showed a high value of strain rate sensitivity comparable to that of fine-grained alloy at very low strain rate range, IS was not expected from the analysis based on the internal variable theory of structural superplasticity at room temperature. As the temperature increased above 100 °C, however, the contribution from IS was observed at a very low strain rate range. A high elongation of ∼400% was obtained in a specimen of 10-μm-grain-size at 200 °C under a strain rate of 2×10⁻⁴/sec. Jointly appointed at Center for Advanced Aerospace Materials (CAAM)     

Analytical study of surface and bulk oxidation of Astroloy

Nickel-base alloys, such as Astroloy, used for aeronautical turbine disks, are sensitive to time-dependent cracking in environments containing oxygen. The mosaic structure of the alloy consisting islands (200 nm average size) surrounded by the -phase (100 nm thick) induces complex oxidation phenomena. Various analytical approaches allow the delineation of all the steps from segregation to oxidation occurring on the surface of such a duplex structure. The protection of Astroloy by its outer oxide layer against oxygen penetration was studied also, using alternative ¹⁶O₂ then ¹⁸O₂ oxidation. In association with STEM studies, it is shown that the outer oxide scale is not a real barrier against oxygen penetration and that inner precipitation of chronium (+ aluminium and titanium)-enriched oxides, takes place especially in the structure.     

中高锰钢耐磨堆焊层的自强化机理

针对高锰钢堆焊可焊性差的问题,利用接触疲劳试验分析了Mn元素在Fe-Mn合金中的作用.阐述了中高锰钢耐磨堆焊层的自强化机理.高锰钢的自强化以加工硬化为主,而中锰钢的自强化以应变诱发马氏体相变强化为主.这种特殊的强化机制能够显著提高堆焊层的使用寿命.通过相变热力学分析,对获得中锰钢堆焊层成分的方法进行了设计.利用动载磨料磨损试验验证了中高锰钢的自强化机理.     

THEORETICAL ANALYSIS AND DESIGN／CALCULATION FORMULAE FOR HYDRAULIC IMPACT MECHANISM

ＴＨＥＯＲＥＴＩＣＡＬＡＮＡＬＹＳＩＳＡＮＤＤＥＳＩＧＮ／ＣＡＬＣＵＬＡＴＩＯＮ　ＦＯＲＭＵＬＡＥＦＯＲ　ＨＹＤＲＡＵＬＩＣＩＭＰＡＣＴＭＥＣＨＡＮＩＳＭＨｅ；Ｑｉｎｇｈｕａ（ＤｅｐａｒｔｍｅｎｔｏｆＭｅｃｈａｎｉｃａｌＥｎｇｉｎｅｅｒｉｎｇ，Ｃｅｎ...     

钛金属与汽车工业研讨会纪要

综述了介孔材料的合成方法、分类、形成机理、形貌控制和应用。目前各种形状如球形、棒状、片状、螺旋形和绳形等形状的介孔材料已经采用溶胶．凝胶、自组装、微乳、反胶束和超声等方法合成出来。按化学组成介孔材料分为硅基和非硅介孔材料，硅基介孔材料已被很好地研究，相反，非硅介孔材料虽然有着广泛的应用前景但研究不多。介孔材料的几种形成机理已经被提出，主要包括液晶模板和协同组装机理。作者也采用化学超声和反胶束方法制备出新奇的介孔二氧化钛粉末和薄膜材料，其光催化活性明显高于普通二氧化钛粉末和薄膜材料。     

渐开线零齿差机构啮合原理与强度条件

零齿差机构的突出问题是齿轮的干涉与强度。在导出避免干涉的条件后，建立新的强度公式，给出各项检验指标，并提出切齿过程中保证精度的具体措施。     

杯盖内衬塑料注射模设计

分析了磁化杯盖内衬塑件的工艺特点 ,介绍了适合于该塑件注射成型的特殊模具结构设计 ,同时说明了模具的工作过程。