平湖油气田古近系花港组低阻油层成因与识别分析

低阻油气层是一种非常规储层 ,其油气层电阻率与邻近水层电阻率接近 ,或有时低于水层的电阻率。通过对花港组H5砂层组的岩石类型、颗粒大小、粘土矿物的成分及其分布、孔隙结构、润湿性、地层水矿化度进行研究 ,表明该砂层组低阻的原因主要是由于高束缚水饱和度及高地层水矿化度引起的。     

Positively Thermo‐Sensitive Monodisperse Core–Shell Microspheres

In this paper, we report on a novel family of monodisperse thermo‐sensitive core–shell hydrogel microspheres that is featured with high monodispersity and positively thermo‐responsive volume phase transition characteristics with tunable swelling kinetics, i.e., the particle swelling is induced by an increase rather than a decrease in temperature. The microspheres were fabricated in a three‐step process. In the first step, monodisperse poly(acrylamide‐co‐styrene) seeds were prepared by emulsifier‐free emulsion polymerization. In the second step, poly(acrylamide) or poly[acrylamide‐co‐(butyl methacrylate)] shells were fabricated on the microsphere seeds by free radical polymerization. In the third step, the core–shell microspheres with poly‐ (acrylamide)/poly(acrylic acid) based interpenetrating polymer network (IPN) shells were finished by a method of sequential IPN synthesis. The proposed monodisperse core–shell microspheres provide a new mode of the phase transition behavior for thermo‐sensitive “smart” or “intelligent” monodisperse micro‐actuators that is highly attractive for targeting drug delivery systems, chemical separations, sensors, and so on.     

The bioconversion of tunisian phosphorite usingAspergillus niger

It is well known that the production of phosphoric fertilizers by traditional methods is connected with certain environmental problems, particularly related to use of acids during the decomposition of natural phosphates. A basic problem is also the fact that only 15 – 20% of the phosphorus contained in superphosphates is assimilated by plants.The development of methods to process natural phosphates without acid precipitation has potential advantages and in this respect biotechnological processing of natural phosphates in order to obtain organo-mineral fertilizers is very promising. The possibility of bioconverting the phosphorus of natural phosphates by usingAspergillus niger fungi through their deep incubation has been investigated. The investigations aim to achieve a high degree of P₂O₅ extraction from the phosphates with conversion from a non-utilizable to a utilizable form. The influence of the fungal strain, the kind of nutritive medium and the time of incubation of the process of biological mobilization of the phosphate rock is examined.It was established that the time of incubation, the kind of micro-organisms of theAspergillus niger group, as well as the kind of nutritive medium, influence significantly the process of bioconversion and the conversion of phosphorus from non-utilizable to water-soluble and utilizable for plants form. A maximum degree 90% of phosphorus extraction in the form of water-soluble and citrate-soluble has been reached for 10-day incubation. Physicochemical examinations have been carried out and they have proved that, as a result of the produced organic acids, a process of decomposition of the initial Tunisian phosphorite takes place.     

金刚石薄膜中晶粒尺寸的研究

扫描电子显微研究表明，化学汽相沉积的金刚石薄膜中晶粒大小比较均匀。但随着沉积时间和薄膜厚度的增加，晶粒逐渐变大，且每一层内，存在少量的大金刚石颗粒，讨论了晶粒尺寸变化和大晶粒形成的原因和机制。     

CaF_2-CaO-MgO-Al_2O_3-SiO_2电渣渣系高温力学性能的研究

本文针对结晶器与铸锭作相对移动的电渣重熔过程中对渣系的高温强度及塑性的要求,对10种CaF_2-CaO-MgO-Al_2O_3-SiO_2渣组成进行了渣的高温强度及塑性的测定,建立了渣组成—渣的岩相结构—渣高温强度及塑性间的对应关系,并选择出较合适的成分范围为CaF_2 35～60％,CaO 10～25％,Al_2O_3 10～20％,SiO_25～15％,MgO≈5％。对其中一个成分的渣进行了电渣热穿孔熔铸中空锭生产实验,并取得了良好的表面质量。     

松香及其衍生物在浮选分离中的应用

介绍了松香的来源、化学组成及理化性质；讨论了松香及其衍生物在非硫化物矿浮选分离、有色金属离子的浮选分离以及从水溶液中浮选分离有机物等方面的应用情况。     

钙—铈氟碳酸盐矿物中BmSn型新多型的发现及其微结构研究

利用Philips CM-12分析型透射电镜对四川昌北大型稀土矿床中钙铈氟碳酸盐矿物进行了研究。除证实氟碳钙铈矿(BS)存在3R和6R2种多型外,首次发现和研究了氟碳钙铈矿(BS)存在4H、12H、18R、24R、30R和36R6种新多型;伦琴矿(BS_2)1种6R新多型和B_2S新规则混层矿物2H、12R和24R3种中新多型。电子衍射和晶格象分析表明:该类矿物中众多新多型的产生,主要是由于矿物结构单元层沿(?)轴有序堆垛和[CO_3]的定向周期性变化所致。     

低电阻率气层测井评价方法

粘土矿物成份是造成气层电阻率低的主要原因。用灰色静态模型计算孔隙度，用BP神经网络计算束缚水饱和度等参数。与岩心分析结果比较，储层参数计算结果精度有所提高。用储层参数建立气层和水层的判别式，判别结果与试油有较好的一致性。综合数字处理结果建立了气层产能评价模型，处理结果与试油结果比较，符合率82％。     

热解样品分析中重量的变化及其影响

热解除油是目前室内岩心分析中样品除油的主要方法之一，但由于热解温度较高，会对样品中粘土矿物的结构水和层间水产生较大的影响。本文结合粘土矿物的吸水特性，通过对大量的实验测定结果分析后认为：经过热解处理后的样品，在测定过程中受粘土矿物（主要是伊利石和蒙脱石）层间水变化的影响，会引起样品重量及样品孔隙空间体积的变化，从而对物性分析中孔隙度测定结果产生较大的影响。     

Paste Residence Time in a Spouted Bed Dryer. II: Effect of Spout Operational Conditions

Residence time distributions for an aqueous solution of 10% sodium chloride in a spouted bed dryer of inert particles were determined using the stimulus-response technique. Glass and polyethylene beads with diameters 2.6 and 3.4 mm were used as inert bodies in a cylindrical column of 14.0 cm diameter and 60° conical base. The effects of inert bodies load, air, and paste flow rates on the mean residence times and RTD were determined following 2³ factorial designs. The RTD could be correlated to the perfect mixing cell model with R² varying from 0.8684 to 0.9815. The mean residence times in CSBD varied from 10.8 to 13.9 and 10.7 to 13.3 min for glass and polyethylene beads, respectively. For both inert particles, mean residence times increased with bed height and decreased with paste feed rates. Also, terms of interaction among the factors were significant in some cases, showing a complex behavior of paste residence times. Equations obtained by response surface regression could predict mean residence times on glass and polyethylene beads with deviations lower than ±10%.