Flexible and Autonomous Integrated System for Characterizing Metal Oxide Gas Sensor Response in Dynamic Environment

Characterization and calibration of gas sensor is a complex problem due to the dynamic behavior of gases and the limitations of current technology. This article reports a flexible, robust, and autonomous integrated system that is able to perform characterization on metal oxide-based gas sensors in dynamic environments. The system controls the concentration and flow of the relevant gases into the gas chamber and simultaneously measuring the sensor response. This feature allows the characterization of the sensor under continuous dynamic flow of gases similar to conditions on a robot or flow pipes. Several experiments have been performed on the system using hydrogen sulfide. The results provide information on the general characteristics of the sensor as well as its sensitivity. The noise levels were studied with different reference voltages. Overall, the results verify that the system is reliable and able to produce repeatable measurements.     

O,O-二乙基硫代磷酰氯高温合成工艺

研究了一种合成高质量O,O-二乙基硫代磷酰氯的新方法.该方法以五硫化二磷为起始原料,经过酯化、氯化和水解制成O,O-二乙基硫代磷酰氯.研究结果表明：反应总收率90.5%,含量99.2%,该工艺为对环境友好的绿色化学工艺.     

光存储材料CaS∶Eu,Sm的正交实验制备及表征

CaS∶Eu,Sm材料在光存储、光探测领域具有广阔应用前景,但制备过程中影响其发光性能的因素较多,彼此又有交互作用,不易获得最佳工艺参数。本文采用高温固相反应法,通过正交实验设计系统研究了灼烧温度、灼烧时间、稀土掺杂浓度、助溶剂用量对CaS：Eu,Sm发光性能影响的主次关系,经正交分析和验证实验确定了最佳工艺参数应为：Eu∶Sm∶Ca mol%=0.3∶0.3∶99.4%,1100℃灼烧0.5h,助熔剂LiF用量为7%。采用X射线粉末衍射仪、荧光分光光度计（耦合1064nm激光激励源）对样品的物相及发光性能进行了测试与表征。     

PPS/CaCO_3复合材料界面应力分布的三维有限元模拟

以碳酸钙粒子(CaCO_3)填充聚苯硫醚(PPS)粒子为研究对象,用ANSYS/LS-DYNA软件对复合材料冲击过程中界面应力分布进行了有限元分析。结果表明:在粒子的赤道处,正应力、剪切应力和等效应力均为最大,朝极点方向迅速减小,在距赤道约0.5~2.0μm之间达致最低点,然后趋于平缓或略微回升。并介绍了PPS/CaCO_3复合材料在冲击载荷下失效或断裂的主要机理。     

H2S低电耗电解制H2新方法

A new technique of lower electricity consumption electrolysis producing H2 has been developed, and the factors affecting producing H2 production were investigated. The results found that under the same electrolysis conditions, H2 production on the cathode increased with increasing electrolyte solution alkalinity; but decreased with increasing zinc ion concentration in the electrolyte solution. The results also revealed that H2 production on the cathode fluctuated with increasing electrolysis voltage, and reached a maximum when the voltage was at 0. 6 V. In a certainty range, it would be favorable to reduce the electricity consumption in H2 production with increasing electrolyte solution alkalinity; but the electricity consumption would be increase when electrolysis voltage was higher. Compared with producing H2 from H2O, the electrolysis voltage was lower by about IV, and the electricity consumption of H2 also decreased by 50% .     

硫化氢的提纯及应用

概括了介绍了硫化氢的应用及提纯工艺。     

氢氧化钡、氯化锌等产品的生产工艺改进

针对生产氯化钡、硫氢化钠等产品的化工厂的困境，在不做大量投资、不做大的改动、不改变原厂的基础上，提出了改善产品结构、革新生产工艺的方法。原有生产状况是：利用原料硫化钡、盐酸、硫化钠生产氯化钡和硫氢化钠，但氯化钡亏损，整体效益差。改进新工艺为：在原有原料中增加氧化锌，即以粗质氧化锌、硫化钡、盐酸、硫化钠为原料生产氢氧化钡、氯化锌、硫氢化钠，以效益好的氢氧化钡、氯化锌取代了氯化钡，并保存了原来效益好的硫氢化钠，整体效益大大提高。     

生物滤池去除污水处理厂臭气的应用研究

研制了一套生物过滤系统,用于处理污水处理厂生化水解池所排放的臭气。以某污水处理厂的生物滤池为研究对象,经过调试使用后,在进口段气体中H2S、NH3的质量浓度分别小于7.0、90.0 mg/m3时,其去除率分别达到90%和99%左右。并通过试验分析了运行时间、进气浓度、填料含水率、温度对除臭效率的影响。     

沉淀分离-络合滴定法测量硫化钠含量

介绍了ZnS沉淀分离-EDTA络合滴定法测量工业硫化钠中Na2S含量的原理和方法，并对该方法的准确性和重现性进行了论证．实验结果表明：该方法具有良好的重现性，重复实验的相对标准偏差为0．55％；该方法具有较高的准确性，与碘量法（国标）相比结果相差0．11％，一致性达到99．5％．     

纳米Au膜在口腔呼吸检测器中的应用

以纳米Au膜材料为核心反应器,用硫化氢气体代替口腔呼吸气来检测巯基化合物的浓度变化,实验采用桥式电路,以复射式直流检流计作为测试手段,以电流显示读数。进而以不同的Au膜粗糙度和不同的Au膜厚度分别对硫化氢的浓度进行测试,同时,对比实验数据探索吸附规律。结果表明:在良好的控制条件下,气体体积分数与测试结果成线性关系。