火烧油层技术在庙5块低渗透稠油油藏中的应用

方法在物理模拟的基础上，利用数值模拟及油藏工程方法，对影响火烧油层的技术参数进行了优选研究，并对影响火驱成败的油藏地质参数、注气参数进行了分析。目的寻找适合庙５块低渗透稠油油藏的开采方法。结果提出了庙５块火驱的最佳开采方式、点火参数及注气参数；庙５块火驱生产后，平均单井日产液由０１ｔ上升到５６ｔ，平均单井日产油由０１ｔ上升到３５ｔ，生产２６ｄ后由于压风机供风不足被迫停止火驱注气；从数模结果看：火驱最终采收率可达３９８％。结论火烧油层是一种潜力很大的稠油开采方法，但其物理、化学反应机理复杂，火烧前缘难以控制；庙５块火驱初期虽然见到了一定的生产效果，但没有取得经济效益     

鼓风引射式燃气燃烧器的计算

提出鼓风式射式燃气燃烧器的基本计算公式与计算结果，并进行结构尺寸与工况分析，确定各种因素对其的影响程度。     

Entropy,Free Volume,and Cooperative Relaxation

The high frequency end of the relaxation spectrum for polymer molecules involves the rotation of the segmental bonds. This fast relaxation process, however, cannot take place easily in the condensed state crowded by the densely packed conformers, necessitating the slower cooperatively synchronous relaxation. As the temperature is lowered, the domain of cooperativity grows towards the infinite size at the Kauzmann zero entropy temperature, though actually the system deviates from the equilibrium as the glass transition intervenes typically at 50 K above that temperature. The excess enthalpy and entropy drop faster than predicted by the rotational isomeric states which would reach zero only at 0 K. The real ΔC_P is greater than that of the RIS value. The actual volume in excess of the crystalline lattice volume, however, points towards zero at 0 K. Thus, a polymer with higher T_g typically exhibits a lower density and modulus in the glassy state. Since the configurational entropy associated with the free volume is proportional to the logarithm of the latter, the Kauzmann temperature can be scaled by ln M, where M is the algebraic average of the conformer molecular weight. The temperature dependence of the most dominant, i.e., the largest equilibrium domain size will result in the Adam-Gibbs and Vogel equations for the characteristic relaxation time. The cooperative domain distribution leads to the relaxation spectrum that follows a power law. The relationship between the characteristic relaxation time and the rate of physical aging is derived.     

铝－锂合金中δ’（Al＿3Li）沉淀相时效粗化行为及体积分数的测定

对经固溶处理的二种Ａｌ－Ｌｉ合金（１．９４ｗｔ．％Ｌｉ和２．７５ｗｔ．％Ｌｉ）的时效过程进行了研究。结果表明：δ’的生长速率遵从Ｏｓｔｗａｒｄ粗化动力学。１．９４ｗｔ．％Ｌｉ合金δ’产生于时效过程中，而２．７５ｗｔ．％Ｌｉ合金的δ’产生于时效的前期阶段。前者的表现体积分数明显大于根据相图估算的数伍，真实体积分数则与此值接近；后者的体积分数低于根据相图估算的数值，这可能归咎于δ’固相线的位置、统计学误差及Ｌｉ更易在时效过程中贫化。     

用试井方法确定注水后地层渗透率的变化

大港油田已进入开发中后期，高含水油田占73％，开发初期的一些参数已不适合现在开发的需要。研究出一套用试井方法确定注水以后地层渗透率变化的方法，对大港油田的增储上产具有重要意义。     

河道溃堤与溃堤波的一、二维耦合计算数值模拟

建立了一维河道溃堤与二维溃堤波耦合计算的水力模型、其中，河道的计算采用一维明渠非恒定流Saint—Venant方程组，求解的过程与溃口的数值模拟耦合；溃堤按渐溃计算，将溃口模拟为梯形，随时间线性增大；溃堤波的计算采用在有限体积无结构网格上建立的TVD—MUSCL格式．模拟算例表明，建立的河道溃堤与溃堤波的一、二维耦合计算水力模型模拟结果比较接近真实溃堤过程．     

Analysis of supersaturation and nucleation in a moving solution droplet with flowing supercritical carbon dioxide

A supercritical antisolvent (SAS) process is employed for production of solid nanoparticles from atomized droplets of dilute solution in a flowing supercritical carbon dioxide (SC CO₂) stream by attaining extremely high, very rapid, and uniform supersaturation. This is facilitated by a two‐way mass transfer of CO₂ and solvent, to and from the droplet respectively, rendering rapid reduction in equilibrium solubility of the solid solute in the ternary solution. The present work analyses the degree of supersaturation and nucleation kinetics in a single droplet of cholesterol solution in acetone during its flight in a flowing SC CO₂ stream. Both temperature and composition are assumed to be uniform within the droplet, and their variations with time are calculated by balancing the heat and mass transfer fluxes to and from the droplet. The equilibrium solubility of cholesterol with CO₂ dissolution has been predicted as being directly proportional to the Partial Molar Volume Fraction (PMVF) of acetone in the binary (CO₂–acetone) system. The degree of supersaturation has been simulated up to the time required to attain almost zero cholesterol solubility in the droplet for evaluating the rate of nucleation and the size of the stable critical nuclei formed. The effects of process parameters have been analysed in the pressure range of 7.1–35.0 MPa, temperature range of 313–333 K, SC CO₂ flow rate of 0.1136–1.136 mol s^?1, the ratio of the volumetric flow rates of CO₂‐to‐solution in the range of 100–1000, and the initial mole fraction of cholesterol in acetone solution in the range of 0.0025–0.010. The results confirm an extremely high and rapid increase in degree of supersaturation, very high nucleation rates and stable critical nucleus diameter of the order of a nanometre. Copyright © 2005 Society of Chemical Industry     

乳化酸+硝酸粉末酸压技术在泥灰岩储层中的应用

华北油田泥灰岩储层曾进行多种类型的酸化增产改造工艺,但均未取得理想效果。经过对泥灰岩地层进行大量的油藏地质、室内试验研究以及工程、地质技术人员的反复论证,优选出一种切实可行的酸压改造措施——前置液+高温乳化酸+固体硝酸酸压工艺。经过现场应用,收到了较好的增产效果,为华北油田泥灰岩储层改造措施找到了突破口。     

高压注水管柱受力分析

进行高压注水管柱受力分析的目的就是根据注水条件研究注水管柱在不同过程中的各类效应，以及这些效应对管柱产生的受力和变形规律，从而明确注水管柱的工作状态，保障注水管柱有效合理地工作。较详细地分析了高压注水管柱在锚定、坐封以及注水3个过程中的受力状态和变形情况，并分析了高压注水管柱在不同过程中受到的各种效应的影响，推导出注水管柱在不同过程中的应力及变形的计算公式，并给出了算例。     

In the theory of blast waves

The behavior of the blast wave from an exploding spherical volume is investigated mathematically over the entire range of blast-wave propagation. The computational method uses analytical results for a similar problem for a point explosion with counter pressure and the theory of an asymptotically equivalent point explosion. The asymptotic solution of the gas-dynamic equations away from the explosion site is matched to the initial conditions of blast-wave formation due to the disintegration of the detonation shock upon its arrival at the boundary of the exploding volume. The spatial distribution of the blast-front pressure is found for combustible gaseous systems and solid explosives. The theoretical results obtained agree quantitatively with available experimental measurements. __________ Translated from Fizika Goreniya i Vzryva, Vol. 42, No. 4, pp. 93–99, July–August, 2006.