CODcr分析方法探讨

本文主要阐述在CODcr分析过程中,通过大量的试验研究,确定氧化物质K2Cr2O7的最佳浓度,以及催化剂硫酸银的最佳用量。     

Fenton试剂降低采油污水CODCr的研究与应用

针对辽河油区超稠油采油污水的特点，采用Fenton试剂催化氧化，对采油污水处理进行研究。实验研究及现场应用结果表明，此方法对污水的CODCr具有良好的去除效果。处理后污水经过简单生化，进一步降解污染物，能够实现稳定迭标排放，且具有能耗低、运行成本低和操作简单等特点。     

柯克亚地区天然气的成因

柯克亚地区天然气的成因众说纷纭。通过对天然气的地球化学特征的详细分析,发现柯克亚天然气碳同位素相对较重,与塔里木盆地下古生界海相天然气的碳同位素组成区别较大,并明确指出柯克亚地区的气源不是单一来源,而具有混源特征。绝大多数天然气的成熟度在1.8%~2.2%之间,也混有一些成熟度在0.9%~1.2%的源岩形成的天然气,推测天然气主要来源于石炭系—二叠系源岩,部分来源于侏罗系源岩。     

LNG冷量优化集成利用技术

我国将相继在沿海地区建成多个LNG接收站，每年将进口数以千万吨计的LNG，同时携带数着巨额冷量，而这些冷量可用于发电、空气分离、制造干冰、低温冷库等众多领域。基于国外LNG冷量利用现状，指出我国即将展开和实施此项技术还存在着：过程火用损较大，缺乏系统、全面的LNG冷量利用技术的研发指导机制，以及宏观调控力度薄弱等问题，进而提出了发展LNG冷量的集成利用方案，可为此类技术的研发利用提供新思路。以福建即将进口的LNG为例，模拟了空气分离与干冰制备的集成工艺流程，结果表明：福建每年进口的260×10⁴t LNG可以冷却290×10⁴t空气，相当于60000 m³/h的氧气制备规模，还可以生产100×10⁴t的干冰，其过程火用损较小；其剩余的高温位冷量可应用于低温冻结库或冰灯等项目，这对主体装置的实施效果和过程火用损的影响较小。该技术的优点在于可灵活控制冷却空气的液化率，基本不用冷却循环水，流程简单，设备投资少，能耗低等。     

几种涉密网主机系统保护及审计技术的比较

论文比较详细地阐述了涉密网主机系统所面临的安全隐患,提出了涉密网主机安全防护所要解决的几个技术问题,并就可能实现的技术方法进行了探讨和比较。     

Fatigue crack propagation of multiple coplanar cracks with the coupled extended finite element/fast marching method

A numerical technique for modeling fatigue crack propagation of multiple coplanar cracks is presented. The proposed method couples the extended finite element method (X-FEM) [Int. J. Numer. Meth. Engng. 48 (11) (2000) 1549] to the fast marching method (FMM) [Level Set Methods & Fast Marching Methods: Evolving Interfaces in Computational Geometry, Fluid Mechanics, Computer Vision, and Materials Science, Cambridge University Press, Cambridge, UK, 1999]. The entire crack geometry, including one or more cracks, is represented by a single signed distance (level set) function. Merging of distinct cracks is handled naturally by the FMM with no collision detection or mesh reconstruction required. The FMM in conjunction with the Paris crack growth law is used to advance the crack front. In the X-FEM, a discontinuous function and the two-dimensional asymptotic crack-tip displacement fields are added to the finite element approximation to account for the crack using the notion of partition of unity [Comput. Meth. Appl. Mech. Engng. 139 (1996) 289]. This enables the domain to be modeled by a single fixed finite element mesh with no explicit meshing of the crack surfaces. In an earlier study [Engng. Fract. Mech. 70 (1) (2003) 29], the methodology, algorithm, and implementation for three-dimensional crack propagation of single cracks was introduced. In this paper, simulations for multiple planar cracks are presented, with crack merging and fatigue growth carried out without any user-intervention or remeshing.     

Niobium-containing catalysts—the state of the art

This review article is devoted to the materials containing niobium, which have been discovered or developed in the past few years and exhibit the potential application in heterogeneous catalysis. Niobium oxides and mixed oxides as well as sulfides, nitrides (oxynitrides), carbides (oxycarbides), and phosphates are considered. Among the catalytic processes in which Nb-containing materials were tested, liquid and gas phase oxidation is described in details, and the role of niobium in the prevention of the catalyst from SO₂ poisoning is mentioned.     

WC/Cu复合材料制备及其高温性能

用机械合金化法结合冷变形，制备了WC／Cu复合材料，研究了冷变形后复合材料的组织特征和高温退火时韵性能变化。结果表明：烧结后的材料经冷变形，组织呈显著纤维状，WC颗粒弥散分布，密度明显提高，达到理论密度的99．2％；复合材料经600～900℃高温退火，强度和硬度略有下降，塑性则有大幅提高；900℃退火时未发生明显的再结晶，界面结合良好；所制备的WC／Cu复合材料有优良的综合性能。     

区域水土特性参数时空变异分布特征及相关分析

作者应用地质统计学原理与方法,在山东簸箕李引黄灌区开展大尺度区域水土特性参数时空变异性的研究,描述农田排水、地下水、表层土壤中含盐量的空间与时间变化分布趋势和特征,分析其间存在的相关关系。结果表明,在一个完整的水文循环年内,研究区域的水土特性参数之间具有相近的空间变异分布状态和特点,但却表现出不同的时间变异分布趋势与特征。农田排水和表层土壤的含盐量随季节变化的分布状态在灌区上、下游相对稳定,在中游却变化明显;地下水的盐分浓度在整个灌区的分布状况没有呈现出明显的时间变异性。在春季至初夏时段内,农田排水中含盐量的增加似乎对地下水水质的影响较小,而对表层土壤积盐状况影响较大。研究成果为灌区制定合理的水资源利用与农田水土管理策略提供了理论依据。     

Optimal Control of the Primary Drying Stage of Freeze Drying of Solutions in Vials Using Variational Calculus

The problem of operating freeze drying of pharmaceutical products in vials placed in trays of a freeze dryer to remove free water (in frozen state) at a minimum time was formulated as an optimal control problem. Two different types of freeze dryer designs were considered. In type I freeze dryer design, upper and lower plate temperatures were controlled together, while in type II freeze dryer design, upper and lower plate temperatures were controlled independently. The heat input to the material being dried and the drying chamber pressure were considered as control variables. Constraints were placed on the system state variables by the melting and scorch temperatures during primary drying stage. Necessary conditions of optimality for the primary drying stage of freeze drying process in vials are derived and presented. Furthermore, an approach for constructing the optimal control policies that would minimize the drying time for the primary drying stage was given. In order to analyze optimal control policy for the primary drying stage of the freeze-drying process in vials, a rigorous multi-dimensional unsteady state mathematical model was used. The theoretical approach presented in this work was applied in the freeze drying of skim milk. Significant reductions in the drying times of primary drying stage of freeze drying process in vials were obtained, as compared to the drying times obtained from conventional operational policies.