丹江口大坝加高工程施工期的度汛方式探讨

南水北调中线工程是为了解决京、津、华北地区水资源紧缺而实施的战略性工程,丹江口大坝加高工程是中线工程的关键性工程之一.丹江口大坝初期工程在大坝加高施工期间仍然承担着汉江中下游防洪任务,妥善解决好丹江口大坝加高工程建设的顺利进行与初期工程的防汛度汛、正常运行管理关系,意义重大.现根据丹江口大坝加高工程施工期的度汛条件、度汛标准以及建设工期的要求等,对丹江口大坝加高施工期的度汛技术方案进行了探讨.     

锰锌铁氧体纳米粉体的液相制备及磁性能

以δ-FeOOH为前驱体,用氨水调节溶液的pH值,分别采用(1)90℃水浴加热动态转化、(2)沸腾回流动态转化,(3)90℃静态转化及(4)200℃水热法四种方法合成了锰锌铁氧体纳米粉体.采用X射线衍射仪(XRD),透射电子显微镜(TEM)、振动样品磁强计(VSM)和X射线荧光光谱仪(XRF)等方法对粉体进行了表征,对四种液相法制备的锰锌铁氧体纳米粉体的结构和性能等进行了对比和分析.结果表明,四种方法中沸腾回流相转化法得到的产物具有磁性能较好、形状较规则、粒径可控等优点.     

N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠的合成及性能研究

用 N,N′-二羟乙基乙二胺、氯乙酸钠合成了 N,N′-二羟乙基乙二胺二乙酸钠(中间体),中间体再与硬脂酰氯反应制备了一种新型 Gemini 两性表面活性剂 N,N′-二(β-十八酰氧基)乙基乙二胺二乙酸钠。对产物合成条件进行了考察,优化的反应条件为:n(硬脂酰氯):n(中间体)=2.5,溶剂 V(水):V(氯仿)=1:2,pH=9.0～10.0,反应温度15～20℃,反应时间5 h。通过红外光谱和质谱分析确定了产物结构,并测试了产物的表面性能。结果表明,在25℃时,该产物的临界胶束浓度为0.24 mmol/L,临界胶束浓度下的表面张力为35.7 mN/m;即时泡沫高度为250 mm,5 min 后泡沫高度为220 mm;乳化时间为22.48 min(甲苯-水物系)和4.65 min(正己烷-水物系),亲水-亲油平衡值为5.4,等电点为 pH 3.3～6.5。     

Effect of fluoropolymer antidripping agent on the microstructure and properties of polyesters

Poly(ethylene terephthalate) (PET) is of excellent mechanical properties and melt processability and is widely used as raw material for textile fibers. However, the flame retardant properties of PET were rather poor, and both reactive and additive phosphorus- and halogen-containing compounds have been employed to enhance the reaction-to-fire properties while the meltdripping behaviour during burning hasn’t been handled properly with the flame retardants. In this work, fluoropolymer was blended with both pure PET (pPET) and reactive phosphorus-containing flame retarded copolyester (fPET), and the flame retardance and char formation and mechanical properties of the resulted pPET and fPET blends were investigated. The tensile strengths of modified pPET samples were worsen whereas those of modified fPET samples were improved at low concentrations. The initial thermal degradation in nitrogen was accelerated remarkably for the two polyesters with fluoropolymer. The oxygen indices of the all modified samples were reduced while char formation and meltdripping suppression were encouraged. The apparent melt viscosity and elasticity for the two polyesters were gained much with antidripping agent. Therefore, fluoropolymer improved char formation of the two polyesters based on the gaseous phase mechanism while the partial suppression of meltdripping behavior and the decrease of mechanical properties mainly originated from the increase of melt viscosity via fibrillation for pPET.     

Mechanical properties and thermal stability of rice husk ash filled epoxy foams

Mechanical properties and thermal stability of epoxy foams filled with white and black rice husk ash were studied. Epoxy foams were prepared from a commercial system and filled with different amounts of both the ashes (0, 6.8, 12.8, 18.0, and 22.7 wt %). The incorporation of both the ashes modified the final morphology of the foam, decreasing the average cell size and increasing the number of cells per volume unit. For all filler percentages used, the specific modulus and strength results showed that the white ash is more effective as reinforcing agent than the black ash. The initial degradation temperature was not affected by the content and type of ash used as the filler. The integral procedure decomposition temperature, weight loss, and char residue results were related to the ash type and atmosphere used in the thermogravimetric analysis. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

ARCGIS环境下基于DEM的流域特征提取

研究选取位于陕西省延安城南12 km处的万花乡向阳沟小流域。采用1∶10000大比例尺的比例尺5 m分辨率的DEM作为基本的地形数据,应用ESR I公司开发的ARCG IS地理信息系统软件进行流域特征的提取。经分析得到了研究区域河网特征以及研究区其它常用的流域特征信息,与实际河流水系特征基本吻合,认为应用DEM划分的流域结果是合理的。     

安琪果酒酵母生长特性研究

对安琪果酒酵母生长特性进行了研究。实验表明，果酒酵母的最适生长温度为30℃，最适生长pH值为7，适宜的碳源为1％的蔗糖或1％的葡萄糖，适宜氮源为1％的酵母膏或1％的蛋白胨，其耐酒精能力较强，可达到18％Vol。     

Inside Front Cover: Three‐Dimensionally Ordered Gold Nanocrystal/Silica Superlattice Thin Films Synthesized via Sol–Gel Self‐Assembly (Adv. Funct. Mater. 7/2006)

The synthesis of three‐dimensionally ordered, transparent gold‐nanocrystal (NC)/silica superlattice thin films using the self‐assembly (by spin‐coating) of water‐soluble gold nanocrystal micelles and soluble silica is reported by Fan and co‐workers on p. 891. The robust, 3D NC/silica superlattice films are of interest for the development of collective optical and electronic phenomena, and, importantly, for the integration of NC arrays into device architectures. Nanocrystals and their ordered arrays hold many important applications in fields such as catalysis, surface‐enhanced Raman spectroscopy based sensors, memory storage, and electronic and optical nanodevices. Herein, a simple and general method to synthesize ordered, three‐dimensional, transparent gold nanocrystal/silica superlattice thin films by self‐assembly of gold nanocrystal micelles with silica or organosilsesquioxane by spin‐coating is reported. The self‐assembly process is conducted under acidic sol–gel conditions (ca. pH 2), ensuring spin‐solution homogeneity and stability and facilitating the formation of ordered and transparent gold nanocrystal/silica films. The monodisperse nanocrystals are organized within inorganic host matrices as a face‐centered cubic mesostructure, and characterized by transmission electron spectroscopy and X‐ray diffraction.     

The Influence of Medium on Low-Voltage Circuit Breaker Arcs

This paper mainly focuses on the influence of three kinds of media： air, air-10%PA （Nylon） and air-10% POM （polyoxymethylene） on low-voltage circuit breaker arcs. A threedimensional （3-D） model of arc motioa under the effect of external magnetic field is built based on magnetohydrodynamics （MHD） equations. By adopting the commercial computational fluid dynamics （CFD） package based on the control-volume method, the above MHD equations are solved. For the media of air-10%PA and air-10%POM, the distributions of stationary temperature and electrical potential and the transient motion processes are compared with those of air arc. The research shows that both air-10%PA and air -10% POM can cool the arc plasma and the former is more effective. Both of them can increase the stationary voltage as well. Moreover, the presence of the two mixtures can accelerate the arc motion toward the quenching area and ensures the arc quenched in time.