全文获取类型
收费全文 | 292篇 |
免费 | 25篇 |
国内免费 | 15篇 |
专业分类
电工技术 | 1篇 |
综合类 | 8篇 |
化学工业 | 88篇 |
金属工艺 | 8篇 |
机械仪表 | 5篇 |
建筑科学 | 29篇 |
矿业工程 | 2篇 |
能源动力 | 66篇 |
轻工业 | 22篇 |
石油天然气 | 11篇 |
武器工业 | 1篇 |
无线电 | 18篇 |
一般工业技术 | 35篇 |
冶金工业 | 2篇 |
原子能技术 | 11篇 |
自动化技术 | 25篇 |
出版年
2024年 | 3篇 |
2023年 | 36篇 |
2022年 | 34篇 |
2021年 | 36篇 |
2020年 | 36篇 |
2019年 | 15篇 |
2018年 | 12篇 |
2017年 | 12篇 |
2016年 | 5篇 |
2015年 | 6篇 |
2014年 | 12篇 |
2013年 | 8篇 |
2012年 | 9篇 |
2011年 | 13篇 |
2010年 | 8篇 |
2009年 | 13篇 |
2008年 | 9篇 |
2007年 | 10篇 |
2006年 | 5篇 |
2005年 | 7篇 |
2004年 | 4篇 |
2003年 | 9篇 |
2002年 | 7篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1998年 | 5篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1978年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有332条查询结果,搜索用时 15 毫秒
1.
Wei-Fei Hu Shuo Chen Hong-Chao Hao Hong Jiang 《American Institute of Chemical Engineers》2022,68(11):e17879
Herein, we propose a novel method to enhance the photoreactivity of an MOF catalyst by grafting isocyanate bonds ( NCO) and sulfhydryl-complexed copper ( SCu) onto ZIF-8 (NIF-SCu). The grafting process intercalated interlayer bands between the conduction and valence bands of ZIF-8, thereby providing a “ladder” for facile electron transition. The extreme improvement in the photoreactivity of NIF-SCu could be attributed to the enhancement in light responses in the range of 350–450 nm by NCO groups and the widening of the visible light range of the MOF by SCu groups. The formation of staggered energy levels in NIF-SCu could also narrow the band gap, lower the resistance, and facilitate the transfer of photogenerated carriers, thereby generating electrons with strong reduction potential in the SCu conduction band. This study provides a new strategy for improving or even endowing the photoactivity of environmental functional materials with wide bandgaps. 相似文献
2.
Waheed Iqbal Mariam Batool Arslan Hameed Saghir Abbas Muhammad Arif Nadeem 《International Journal of Hydrogen Energy》2021,46(49):25050-25059
Transition metal oxyhydroxides have been used as promising electrocatalysts for water splitting however, their catalytic activity is restricted due to low surface area and poor conductivity. Herein, we report novel composite FeOOH@ZIF-12/graphene composite as electrocatalyst for water oxidation, whereby ZIF-12 provide extra surface for the FeOOH dispersion whilst graphene act as excellent electron mediator. The composite shows a low overpotential value of 291 mV to attain a current density of 10 mA cm?2 and a low Tafel slope value of 78 mV dec?1. The catalyst offers a maximum current density of 101 mA cm?2, while it gives a turnover frequency (TOF) value of 0.031 s?1 at an overpotential of 291 mV only. The excellent activity and remarkable stability of composite is attributed to highly conductive and porous support. 相似文献
3.
4.
TMS320C67系列EMIF与异步FIFO存储器的接口设计 总被引:4,自引:0,他引:4
介绍了TI公司TMS320C67系列DSP的EMIF(外部存储器接口)与异步FIFO(先进先出)存储器的硬件接口设计,着重描述了用EDMA(扩展的直接存储器访问)方式读取FIFO存储器数据的软件设计流程,最后说明了在选择FIFO存储器时应注意的问题.由于EMIF的强大功能,不仅具有很高的数据吞吐率,而且可以与不同类型的同步、异步器件进行无缝连接,使硬件接口电路简单,调试方便.运用EDMA的方式进行数据传输,由EDMA控制器完成DSP存储空间内的数据搬移,这样可以最大限度地节省CPU的资源,提高整个系统的运算速度. 相似文献
5.
ABSTRACT Cadmium as a highly toxic metal is released into the environment through paper production, metal processing, phosphate fertilizers, insecticides, and treatment of wastewater. Cadmium also inhibits the body activities and is very toxic for kidney and other organisms. In the current study, zinc-based metal–organic framework, zeolitic imidazolate framework (ZIF)-8, was synthesized and modified by dimethylethylenediamine (ZIF-8-mmen) for the removal of cadmium. To optimize the experiments, response surface methodology was applied with three variables including pH, adsorbent dosage, and contact time using central composite design. The optimum conditions for pH, dosage, and time were 2, 0.1 g, and 89 min, respectively, with removal efficiency of 85.38%. The Langmuir isotherm (q m = 1000 mg/g) indicates the monolayer adsorption. The kinetic studies reveal that the Lagergren model was predominant and cadmium was not chemisorbed. Thermodynamic parameters show spontaneous, endothermic, and physisorption processes. 相似文献
6.
Yongsheng Liu Hidetoshi Kita Kazuhiro Tanaka Kota Imawaka Shunsuke Tanaka Takahiko Takewaki 《应用聚合物科学杂志》2021,138(16):50251
The mixed matrix membranes (MMMs) consisting zeolitic-imidazolate framework-8 (ZIF-8) nanoparticles in a polymer have been of considerable interest in separation applications. The fillers used are mostly synthesized using the solvothermal method. In this study, the ZIF-8 nanoparticles were synthesized using a solvent-less and salt-free mechanochemical method and were added to 6FDA-TrMPD polyimide to prepare MMMs. The single gas permeation of C3H6 and C3H8 through the MMMs was investigated. The C3H6 permeability and C3H6/C3H8 ideal selectivity of a 20 wt% mechano-synthesized ZIF-8/6FDA-TrMPD MMM were 70% and 32% higher than those of the neat polymer membrane at 0.1 MPa and 308 K, respectively. The C3H6/C3H8 separation performance of the mechano-synthesized ZIF-8 MMM was similar to that of the conventional solvothermal-synthesized ZIF-8 MMM. This separation performance was in good agreement with the Maxwell model. Temperature and pressure dependence analyses confirmed that the mechano-synthesized ZIF-8 nanoparticles acted as molecular sieves in the MMMs for the C3H6 and C3H8 permeation. 相似文献
7.
Xing Yang Xianghua Wu Zhaoyang Chen Wenqiong Li Qi-Jun Sun Zeping Guo Xiaoguang Liang Yun He 《应用聚合物科学杂志》2021,138(20):50431
Coupling with electrospinning technique, metal–organic-frameworks (MOFs)-derived porous carbon fibers exhibit a great potential application in the adsorption of volatile organic compounds (VOCs) because of their huge surface area, high porosity, as well as sufficient heteroatom-doped active sites. In this work, the hierarchically porous N-doped carbon nanofibers are obtained after the pyrolysis of zeolite imidazole framework-8 and polyacrylonitrile (ZIF-8/PAN) composite fibers synthesized by electrospinning method. The N-doped carbon nanofibers fabricated in N2 atmosphere (N-CF-N2) present an enhanced adsorption capacity of 694 mg/g for benzene because of the synergistic effect of the hierarchically porous structure and the abundant N-species-containing active sites. It is also interesting that the N-doped hierarchical carbon nanofibers fabricated in Ar atmosphere (N-CF-Ar) exhibit a low benzene adsorption as compared with the N-CF-N2, which can be attributed to the porous structure damage caused by the bombardment of heavy Ar atoms on the pore shells during the pyrolysis. These results not only show a promising application of the as-fabricated N-CF-N2 in adsorption of VOCs for air purification due to its merit of cost-efficient, large-scale production, and excellent adsorption capacity, but also expand the potential of electrospinning technology and composite fibers in volatile organic gas adsorption. 相似文献
8.
基于McBSP实现DSPs与串行AD/DA的接口设计 总被引:2,自引:0,他引:2
重点介绍了利用DSPs的多通道缓冲串口McBSP实现与A/D、D/A串行接口的设计.TI公司TMS320C67x系列DSPs的McBSP有两种配置方式,一种是配置成串口的模式,一种是配置成通用I/O的模式,本文分别用这两种模式进行了A/D和D/A接口的设计,其硬件及软件的实现方法简单、方便,可节省程序代码空间和CPU运行时间. 相似文献
9.
目的 Ki67分数是乳腺癌预后评估的重要指标,计算该分数的关键步骤是检测阴性与阳性癌细胞核。人工检测面临疲劳与主观差异的问题。卷积神经网络有望实现高质量、自动化的细胞核检测,然而需要病理专家为其标注细胞核。为了减轻标注的工作量,不少研究者提出以中心点标注训练卷积神经网络。然而这些方法采用过于复杂的卷积神经网络和后处理流程,未能充分提高易用性和效率、发挥卷积神经网络的质量。对此,提出CentroidNet模型,旨在提高中心点检测的质量、效率和易用性。方法 CentroidNet模型在图像上放置均匀排布的锚点,为每个锚点预测一个候选点,一部分候选点通过基于阈值的筛选策略成为预测点。本文提出最近锚点匹配策略用于生成训练标签,既保证了端到端推理,又规避了其他一对一标签匹配算法所具有的标签抖动问题。本文建议锚点间距应尽可能接近训练集答案点间最短距离的第一百分位数,并指出这样的锚点间距能够在前景标签数、坐标回归难度与效率之间取得良好的平衡。本文在设计卷积神经网络的结构时,没有采纳广为使用的U-Net或特征金字塔(feature pyramid network, FPN)中的多级上采样与旁路连接,反... 相似文献
10.
Optimal design for generalized linear models has primarily focused on univariate data. Often experiments are performed that have multiple dependent responses described by regression type models, and it is of interest and of value to design the experiment for all these responses. This requires a multivariate distribution underlying a pre-chosen model for the data. Here, we consider the design of experiments for bivariate binary data which are dependent. We explore Copula functions which provide a rich and flexible class of structures to derive joint distributions for bivariate binary data. We present methods for deriving optimal experimental designs for dependent bivariate binary data using Copulas, and demonstrate that, by including the dependence between responses in the design process, more efficient parameter estimates are obtained than by the usual practice of simply designing for a single variable only. Further, we investigate the robustness of designs with respect to initial parameter estimates and Copula function, and also show the performance of compound criteria within this bivariate binary setting. 相似文献