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101.
HouDianguo 《中国炼油与石油化工》2003,(2):51-56
Reduction of sulfur content in FCC gasoline was studied in a fixed fluid bed (FFB) unit by using metal-modified LV-23 FCC catalyst. The results showed that the sulfur content in FCC gasoline could be reduced with LV-23 catalyst modified with zinc, palladium, zinc-palladium, zinc-cobalt, and zinc-nickel. Among these metals or metal combinations, palladium-containing catalyst was the most effective. Desulfufization of the heavy fraction of FCC gasoline was more effective than full-range gasoline under the same conditions with palladium-containing catalysts. A high reaction temperature was favorable to desulfurization, but it would reduce the yield of liquid product. After desulfurization reaction, the olefm content of product gasoline decreased while the aromatic and iso-alkane contents increased. Removal of thiophene and benzothiophene is higher. 相似文献
102.
吸水膨胀型膨润土/交联聚丙烯酰胺颗粒堵剂 总被引:9,自引:0,他引:9
使丙烯酰胺、少量N,N-亚甲基双丙烯酰胺在钙膨润土存在下进行水溶液引发接枝共聚合,聚合产物经造粒、粉碎、筛分,得到粒径0.5~1.0mm的颗粒堵剂。根据颗粒堵剂吸水量大小确定丙烯酰胺与膨润土最佳质量比为7:1,引发剂最佳用量为500g/t,交联剂最佳用量为300g/t,吸水量与这3个参数之间的关系曲线都经过最大值,颗粒堵剂在去离子水中的吸水量为560~650mL/g。该堵剂已大规模生产,在胜利、中原油田许多采油厂已用于调剖、堵水和调驱施工,在青海、江苏、大港、冀东等油田也已开始使用。在胜利东辛采油厂的一个井组,连续3个月在3口井注入该堵剂共27t,使井口压力上升3MPa,产油量大幅度增加。表l参l。 相似文献
103.
DJG-1阳离子絮凝剂合成的影响因素 总被引:1,自引:0,他引:1
DJG-1阳离子絮凝剂的合成步骤为:玉米淀粉与丙烯酰胺在硝酸铈铵引发下接枝,得A;A与醇在酸催化下发生酯化反应得B;甲醛与二甲胺反应得N-羟甲基胺(C);在C中加入酸使pH值为4左右。得酸性范围内的N-羟甲基胺(C′)。B与C′发生曼尼希反应得D(叔胺盐);D发生烷基化反应E(季铵盐);E与四苯硼钠反应生成白色沉淀。室内试验分析了DJG-1阳离子絮凝剂合成的影响因素。评价了DJG-1的水处理效果并与硫酸铝进行了对比。实验结果表明,DJG-1阳离子絮凝剂合成的影响因素包括引发剂的选用,活化时间,投料比,反应时间与温度及溶液pH值等。用DJG-1絮凝剂混凝处理钻井废水时,絮凝沉淀的速度比用硫酸铝处理时大得多,废水处理效率高,但DJG-1絮凝剂与硫酸铝复合使用经济效益更好,且硫酸铝用量为300mg/L时,DJG-1的最佳用量为3-4mg/L。 相似文献
104.
超滤膜的改性研究及应用 总被引:14,自引:0,他引:14
随着超滤膜技术的发展,人们对超滤膜提出了各种各样的特性要求,其中解决膜表面的污染问题变得越来越紧迫.超滤膜改性,尤其是在膜表面引入亲水性基团是解决问题的关键.本文从这点出发,结合自身的工作,总结了近年高分子超滤膜改性方面的研究进展,包括表面活性剂在膜表面的吸附改性、等离子体改性、辐照改性、高分子合金和表面化学反应等几种改性方法. 相似文献
105.
随着单井蒸汽吞吐周期的增加,加剧了油层纵向和平面上的非均质性。汽驱井组油层存在高渗透带或孔道,注入蒸汽上升,从稠油顶部跨越,会出现越顶现象,造成提早汽窜,注蒸汽驱的波及效率进一步降低。针对此问题,开发了稠油注汽井用高温调剖封窜剂。室内研究结果表明,研制的高温调副封窜剂HD、HT具有较好的高温成胶性能和强度。现场应用孤东油田的9口井,有效8口,有效率88.9%,累计增油726.8t。 相似文献
106.
Prediction of the effects on dynamic response due to distributed structural modification with additional degrees of freedom 总被引:1,自引:0,他引:1
Huajiang Hang Krishna Shankar Joseph C.S. Lai 《Mechanical Systems and Signal Processing》2008,22(8):1809-1825
The aim of this study is to investigate means of efficiently assessing the effects of distributed structural modification on the dynamic properties of a complex structure. The dynamic properties of the modified structure can be determined by experimental testing or numerical simulation, both of which are complex, expensive and time-consuming. Assuming that the original dynamic characteristics are already established and that the modification is a relatively simple attachment, the modified dynamic properties may be determined numerically without solving the equations of motion of the full-modified structure. The frequency response functions (FRFs) of the modified structure can be computed by coupling the original FRFs and a delta dynamic stiffness matrix for the modification introduced. The validity of this approach is investigated by applying it to a cantilever beam to which a smaller beam is attached as modification. The original FRFs were obtained experimentally as well as numerically. The delta dynamic stiffness matrix was determined numerically by modeling the attachment and part of the original structure including the attachment points. The FRFs of the modified beam were then computed. Good agreement is obtained by comparing the results to the FRFs of the modified beam determined experimentally as well as by numerical modeling of the complete modified structure. 相似文献
107.
拒水粉是一种新型建筑防水材料,被称之为神奇的粉末。本文就如何利用粉体表面改性技术制备拒水粉,从理论上和具体的实验方法上作了详尽的说明。 相似文献
108.
Poly(4-methylstyrene)-graft-poly(ethylene oxide)s were prepared via polymerisation of ethylene oxide on to poly(4-methylstyrene)s functionalised with hydroxyl groups. In this way, many ‘comb-like’ polymers having different hydrophobic backbone length, hydrophilic branch length and frequency of branches were synthesised. These polymers were tested as dispersants in coal-water mixtures in order to correlate the dispersing properties of this class of polymers with the investigated parameters. 相似文献
109.
着重讨论了贵定石灰石矿边坡1220~1180m水平在I号剖面左右深层不稳定地段的边坡治理方案。推荐方案强调多台阶同时回采,以推迟靠帮,进而推迟可能的表层滑坡治理。还讨论了护坡矿壁回收及该矿其他不稳定地段边坡治理等问题。 相似文献
110.
Olgica Gruji 《Journal of the Institute of Brewing》1998,104(5):249-253
This paper presents data on barley micromalting with addition of the CELLUCLAST enzyme complex. This is a commercial, multicarbohydrase with distinct β-glucanase and proteinase activities. The enzyme was added to steeping and germination phases, in different quantities (0.05%; 0.75% and 0.1% of initial barley). The enzyme was added to different malting phases: to the 2nd and 3rd steep water, at the beginning of germination on the 1st day by spraying, on the 2nd day of germination and in combination of addition to 3rd steeping water and in germination start (50% of total quantity of each). CELLUCLAST enzyme had a significant effect on reduction of wort viscosity, extract difference, wort filterability and protein breakdown, depending on the quantity of added enzyme and the malting phase to which it was added. There was no negative effect on other malt quality parameters. The best values of cytolytic breakdown parameters (viscosity, extract difference, filtration rate) were obtained with addition of 0.075% of CELLUCLAST, on the first day of germination. 相似文献