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C. G. Gwie R. J. Griffiths D. T. Cooney M. L. Johns D. I. Wilson 《Journal of the American Oil Chemists' Society》2006,83(12):1053-1062
The spray-freezing of two food fats, tripalmitin (PPP) and cocoa butter (CB) and mixtures thereof, has been modeled experimentally
using a novel single droplet freezing apparatus configured so that temperature profiles or samples for microstructure analysis
can be obtained. For 2 mm diameter droplets suspended in a cold air flow at temperatures around 2–15°C, initial cooling rates
were on the order of 10 K s−1 and the temperature profiles could be correlated directly to DSC data collected at 20 K min−1, indicating that minimal supercooling of the materials occurred in the droplet form. Microstructure analysis confirmed that
PPP crystallized preferentially in mixtures, and that the surface structure was very sensitive to storage conditions. The
bulk structure was much less sensitive, and the internal microstructure of the PPP droplets revealed distinct nucleation sites,
which were absent from the CB: These persisted in the mixtures up to 50 wt%. X-ray analysis indicated that the fats crystallized
in their more stable forms, namely, β for PPP and Form V/V1 in CB. 相似文献
13.
陈志刚 《制冷与空调(四川)》2003,17(2):25-28
水是食品材料中最重要的成分。本文介绍了食品中水的性质以及水对食品相变的影响,并从水活性、水的吸附性以及水的增塑性三方面描述了水在食品相变中所起的作用。另外,还着重分析了水对食品冻结温度的影响。 相似文献
14.
丁集矿副井井架基础沉降变形分析 总被引:1,自引:1,他引:0
按井筒冻结施工的进度,选择合适的周期进行沉降变形观测,根据大量的实测资料对冻结施工前后丁集矿副井井架基础的沉降变形规律进行了分析,并预测其沉降变形趋势。 相似文献
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16.
A. Andreev L. Prahov M. Gabrovska A. Eliyas V. Ivanova 《Applied catalysis. B, Environmental》1996,8(4):365-373
The catalytic activity of a wide range of transition metal oxides in oxidation of sulphide ions by air in aqueous medium was studied. Some specific features of the reaction mechanism on some of the studied oxides were considered. The transition metal oxides are promising catalysts for practical application. Some of these oxides will allow the preparation of catalysts possessing activity comparable to that of the cobalt phthalocyanine based catalysts, popular in industrial practice. 相似文献
17.
国产活性炭在合成气净化中的应用 总被引:1,自引:0,他引:1
选择国产K01活性炭脱除羰基铁、镍,以达到保护铑催化剂并减少副产物的目的。1年的实际应用结果表明:国产K01活性炭能够替代进口活性炭在合成气净化中应用。 相似文献
18.
Directional solidification studies of gelatinized corn starch-water mixtures were undertaken in order to examine, in situ, the freezing behavior of this food model. The solidification rate was controlled by varying sample cell velocity as it moved from a 25°C hot stage to a -25°C cold stage. While freezing at cell velocities ≤7.5 μm/sec, starch granules were alternately pushed or entrapped by the advancing solid-liquid interface producing a segregated structure consisting of alternating high-starch and low-starch bands. At a cell velocity of 10 μm/sec, the frozen product was homogeneous. The relationship between the solid-liquid interface velocity and segregation behavior was quantified and compared to an existing model of particle-interface interactions. 相似文献
19.
Comparative studies on Ar and He closed-cycle MHD power plants combined with fossil fuel are performed. The sizes of a regenerative heat exchanger and a boiler are expected to be smaller for He than for Ar. The pressure loss of a working gas in a regenerative heat exchanger is reduced for He. The purification subsystem for He is expected to be more compact and economical than that for Ar; but a larger compressor is required for He than for Ar. 相似文献
20.
In the design process of the photocatalytic oxidation (PCO) reactor using TiO2-coated foam nickels, the optimum of catalyst film thickness, light intensity and flow velocity were considered. A model was developed to study the effect of catalyst film thickness on photocatalytic degradation of formaldehyde by a TiO2-coated foam nickel at continuous flow mode. In this model, external mass transfer and internal molecule diffusion-reaction were considered. A first-order kinetics equation was used to account for the photocatalytic reaction. Two exponential equations were employed to describe the distribution of light intensities in foam nickels and catalyst films, respectively. Validated with experimental data, the model can be used to predict the optimal thickness of catalyst films. A method for determining appropriate light intensities was proposed and discussed. The appropriate light intensity can be obtained by giving a margin, regarded as an excess coefficient, to the light intensity calculated based on the assumption of complete use of excited electron–hole pairs. The excess coefficient needs to be determined experimentally. In addition, the optimal flow velocity of PCO reactors could be consistent with the required one by changing the windward area of foam nickels. Based on the theoretical analyses, a novel PCO reactor containing 15 parallel-connected cells was designed. Each reaction cell was composed of an UV lamp and a TiO2-coated tubular foam nickel. The performance of the reactor was tested by degrading gaseous formaldehyde at an indoor concentration level. The results showed that the reactor had low pressure loss and good degradation capability. 相似文献