微生物絮凝剂的研究及发展前景

对微生物絮凝剂的现状与发展趋势做了全面综述,包括合成絮凝剂的微生物种类,微生物絮凝剂的絮凝机理及其影响因素,微生物絮凝剂的提取方法等,并阐述了微生物絮凝剂的性质、特点等.     

Extraction of rice brain oil using supercritical carbon dioxide and propane

Extraction of rice bran lipids was performed using supercritical carbon dioxide (SC−CO₂) and liquid propane. To provide a basis for extraction efficiency, accelerated solvent extraction with hexane was performed at 100°C and 10.34 MPa. Extraction pressure was varied for propane and SC−CO₂ extractions. Also, the role of temperature in SC−CO₂ extraction efficiency was investigated at 45,65, and 85°C. For the SC−CO₂ experiments, extraction efficiencies were proportional to pressure and inversely proportional to temperature, and the maximal yield of oil achieved using SC−CO₂ was 0.222±0.013 kg of oil extracted per kg of rice bran for conditions of 45°C and 35 MPa. The maximal yield achieved with propane was 0.224±0.016 kg of oil per kg of rice bran at 0.76 MPa and ambient temperature. The maximum extraction efficiencies of both SC−CO₂ and propane were found to be significantly different from the hexane extraction baseline yield, which was 0.261±0.005 kg oil extracted per kg of rice bran. A simulated economic analysis was performed on the possibility of using SC−CO₂ and propane extraction technologies to remove oil from rice bran generated in Mississippi. Although the economic analysis was based on the maximal extraction efficiency for each technology, neither process resulted in a positive rate of return on investment.     

Enzyme catalyzed durable and authentic oriental lacquer: a natural microgel-printable coating by polysaccharide–glycoprotein–phenolic lipid complexes

The chemistry and technology of oriental lacquer, proof of long-term durability by a laboratory test, and morphological features of the closely packed shell (polysaccharides–glycoproteins)–core (polymerized urushiol) microgel particles, which are chiefly responsible for degradation due to efflorescence outdoors, are described. The dimerization mechanism of urushiol was demonstrated by separation of over 20 urushiol dimer derivatives. Physiological dimerization of urushiol in the lacquer is very much influenced by the humidity in drying, and the interaction of semiquinone radicals with metal ions, hydrophilic polysaccharides and amphipathic glycoproteins contained in the lacquer. A mechanism for renewable oriental lacquer is proposed, involving harmony of technology and nature within the lacquer tree plantations in south-east Asia. A brief review of studies of lacquer chemistry and synthetic coatings is given.     

Feeding rats with liposomes or fish oil differently affects their lipid metabolism

Two n‐3 polyunsaturated fatty acid (PUFA)‐rich diets differing in their chemical and physical forms were given to rats during 2 wk. Liposomes [phospholipids (PL) organized in bilayer structures] made from a natural marine lipid extract or a mixture of fats containing fish oil [similar fatty acids esterified in triacylglycerols (TAG)] were used. The influence of n‐3 PUFA dietary sources on plasma parameters, i.e. TAG, cholesterol and PL concentrations, was investigated. A similar hypotriglyceridemic effect of n‐3 PUFA from liposomes or fish oil was observed. In contrast, feeding rats with liposomes led to different PL and cholesterol patterns. In the plasma of rats fed liposomes, total cholesterol amounts were positively correlated with PL levels. Liposome and fish oil feedings caused a marked increase in the amounts of n‐3 PUFA, which occurred mainly at the expense of n‐6 PUFA. However, the enrichment in n‐3 PUFA in the different plasma lipid classes differed substantially when ingested in the form of fish oil or liposomes. These results were interpreted in terms of different lipid bioavailability and metabolic fate during the digestive steps and in the liver, with the dietary source.     

高活性微生物絮凝剂处理靛蓝印染废水的动力学研究

从筛选到的絮凝剂产生菌中构建出比单一菌群产生更高活性絮凝剂的复合菌群--复合1(BAFRT4 CYGS1).为降低培养成本,接种复合1至啤酒废水培养基中,产生了絮凝活性为96.8%的微生物絮凝剂(MBF).所产MBF对靛蓝印染废水有良好的处理效果,CODCr去除率和脱色率最高分别达79.2%和87.6%.研究了复合1所产MBF在优化工艺条件下处理靛蓝印染废水的絮凝过程,并得出了MBF去除CODCr和脱色的经验动力学方程.     

污泥调理剂

综述了污泥调理中常用的化学调理剂及其各自的优缺点,着重介绍了因具有安全、无毒、可生物降解、无二次污染等独特的性质而倍受人们的关注的生物絮凝剂。     

Accurate determination of hexanal in beef bouillons by headspace solid‐phase microextraction gas‐chromatography mass‐spectrometry

Lipid oxidation has great impact on the quality of food products through flavor and taste deterioration, reduction in nutritive value, and potential toxicity of the oxidized food components. Flavor and taste deterioration can be easily perceived and it represents one of the major causes of consumer complaints in the food industry. The deterioration of sensory properties is due to the decomposition products of hydroperoxides that easily isomerize and degrade into volatile compounds. Volatile products are responsible for flavor and taste deterioration. In this study, we present the development of the solid‐phase microextraction gas chromatography‐mass spectrometry (SPME‐GC‐MS) technique to quantify low amounts (μg/g range) of secondary oxidation products, i.e. hexanal. The optimization of SPME parameters is a difficult task because of the possibility of further formation of volatile products during analysis. Different parameters such as type of fiber, exposure time of the fiber to the sample headspace and the optimal temperature of absorption have also been investigated. The complete validation of the method was achieved by the determination of linearity, limits of detection and quantification and repeatability. We demonstrated that the SPME method is a valuable tool for the quantification of low amounts of secondary oxidation products such as hexanal. Therefore, this technique can be used to detect early formation of volatiles.     

微生物絮凝剂在废水处理中的应用

总结了传统絮凝剂在废水处理中存在的问题以及微生物絮凝剂在废水处理中的优越性,结合实例分析了微生物絮凝剂在现代废水处理中的具体应用,探讨了目前微生物絮凝剂研究的几个发展方向。     

Aerobic biodegradation of di-n-butyl phthalate by Xiangjiang River sediment and microflora analysis

Di-n-butyl phthalate (DBP), one of phthalate acid esters (PAEs), was investigated to determine its biodegradation rate using Xiangjiang River sediment and find potential DBP degraders in the enrichment culture of the sediment. The sediment sample was incubated with an initial concentration of DBP of 100 mg/L for 5 d. The biodegradation rate of DBP was detected using HPLC and the degraded products were analyzed by GC/MS. Subsequently, the microbial diversity of the enrichment culture was analyzed by polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP). The results reveal that almost 100% of DBP is degraded after merely 3 d, generating two main degraded products: mono-butyl phthalate (MBP) and 9-octadecenoic acid. After a six-month enrichment period under the pressure of DBP, the dominant family in the final enrichment culture is clustered with the Comamonas sp., the remaining are affiliated with Sphingomonas sp., Hydrogenophaga sp., Rhizobium sp., and Acidovorax sp. The results show the potential of these bacteria to be used in the bioremediation of DBP in the environment.     

厌氧附着膜膨胀床处理生活废水的研究

文章利用厌氧附着膜膨胀床（AAFEB）反应器处理生活废水。选择合适的活性污泥和活性炭载体,在60d内反应器启动挂膜完成。实验表明,此反应器能够有效的去除生活废水中的有机物,出水水质良好,反应器运行稳定。通过稳定床层膨胀率在10％-20％,研究水力停留时间（HRT）和温度对CODCr去除率的影响,得到该反应器的最佳工艺条件为,HRT8h,温度控制在28℃,在此工艺条件下,CODCr的去除率在85％以上,BOD5的去除率在73％以上,且SS的去除率在75％以上。