全文获取类型
收费全文 | 2320篇 |
免费 | 101篇 |
国内免费 | 34篇 |
专业分类
电工技术 | 12篇 |
综合类 | 80篇 |
化学工业 | 1698篇 |
金属工艺 | 8篇 |
机械仪表 | 10篇 |
建筑科学 | 40篇 |
矿业工程 | 3篇 |
能源动力 | 8篇 |
轻工业 | 75篇 |
石油天然气 | 273篇 |
武器工业 | 1篇 |
无线电 | 10篇 |
一般工业技术 | 205篇 |
冶金工业 | 11篇 |
原子能技术 | 12篇 |
自动化技术 | 9篇 |
出版年
2024年 | 4篇 |
2023年 | 13篇 |
2022年 | 11篇 |
2021年 | 37篇 |
2020年 | 21篇 |
2019年 | 30篇 |
2018年 | 40篇 |
2017年 | 31篇 |
2016年 | 53篇 |
2015年 | 36篇 |
2014年 | 80篇 |
2013年 | 75篇 |
2012年 | 138篇 |
2011年 | 119篇 |
2010年 | 104篇 |
2009年 | 90篇 |
2008年 | 96篇 |
2007年 | 144篇 |
2006年 | 151篇 |
2005年 | 142篇 |
2004年 | 97篇 |
2003年 | 106篇 |
2002年 | 135篇 |
2001年 | 139篇 |
2000年 | 115篇 |
1999年 | 100篇 |
1998年 | 85篇 |
1997年 | 50篇 |
1996年 | 34篇 |
1995年 | 37篇 |
1994年 | 33篇 |
1993年 | 29篇 |
1992年 | 14篇 |
1991年 | 16篇 |
1990年 | 10篇 |
1989年 | 4篇 |
1988年 | 8篇 |
1987年 | 2篇 |
1985年 | 4篇 |
1984年 | 6篇 |
1983年 | 7篇 |
1982年 | 9篇 |
排序方式: 共有2455条查询结果,搜索用时 332 毫秒
11.
A ternary blend system comprising poly(cyclohexyl methacrylate) (PCHMA), poly(α‐methyl styrene) (PαMS) and poly(4‐methyl styrene) (P4MS) was investigated by thermal analysis, optical and scanning electron microscopy. Ternary phase behaviour was compared with the behaviour for the three constituent binary pairs. This study showed that the ternary blends of PCHMA/PαMS/P4MS in most compositions were miscible, with an apparent glass transition temperature (Tg) and distinct cloud‐point transitions, which were located at lower temperatures than their binary counterparts. However, in a closed‐loop range of compositions roughly near the centre of the triangular phase diagram, some ternary blends displayed phase separation with heterogeneity domains of about 1 µm. Therefore, it is properly concluded that ternary PCHMA/PαMS/P4M is partially miscible with a small closed‐loop immisciblity range, even though all the constituent binary pairs are fully miscible. Thermodynamic backgrounds leading to decreased miscibility and greater heterogeneity in a ternary polymer system in comparison with the binary counterparts are discussed. © 2003 Society of Chemical Industry 相似文献
12.
液晶基元直接横挂于主链上的液晶共聚物的合成与研究 总被引:1,自引:0,他引:1
以含液晶基元的单体2,5-双(4-甲氧基苯甲酰氧基)苯乙与苯乙烯通过自由基共聚合反应,首次合成了一系列含液晶性和非液晶性两种序列结构的共聚物。采用DSC、偏光显微镜和X衍射方法研究了共聚物的液晶行为,发现单体和共聚物(只有CP-5和CP-6)有很好的热致液晶性。随共聚物中介晶单体单元含量的增加,共聚物玻璃化转变温度T和热分解温度T呈规律变化。 相似文献
13.
高分子材料辐射接枝苯乙烯的研究进展 总被引:6,自引:0,他引:6
对各高分子材料辐射接枝苯乙烯的动力学,接枝方法及接枝材料的应用进行了综述,讨论限辐射剂量,剂量率,温度,后效应,溶剂,添加剂和高分子材料厚度及结晶性等方面对接枝反应的影响。 相似文献
14.
A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the Tm and Tc of microPCMs were in the range of 29.8–31.0oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006 相似文献
15.
16.
A series of short fibre reinforced styrene butadiene rubber (SBR) composites were prepared by incorporating sisal fibres of
different lengths and different concentrations. The vulcanization behaviour and the properties of the vulcanizates were measured
by the relevant ASTM procedures. The processing characteristics such as green strength and mill shrinkage were improved by
the addition of fibres. The properties like tensile strength, tear strength, moduli at 10% and 20% elongations were found
to be maximum for composites containing longitudinally oriented fibres of length 6 mm. Mixes containing 35 phr loading of
fibres and bonding agent showed better mechanical performance than others. The failure behaviour of tensile and tear specimens
have been analysed by scanning electron microscopy techniques.
Paper presented at the poster session of MRSI AGM VI, Kharagpur, 1995 相似文献
17.
用两亲聚合物制备大颗粒苯丙乳液 总被引:10,自引:0,他引:10
分别以两亲聚合物P(C9-AA)和P(DCPD-St-α-St-AA)作乳化荆,研究了制备大颗粒(约1μm)及具有一定稳定性的苯丙乳液的方法,讨论了乳化剂,温度及引发剂用量对乳液性能的影响。结果表明,以P(C9-AA)作乳化剂时,引发剂用量为单体质量的1.2%,90℃时可以合成性能良好的苯丙乳液;以P(DCPD-St-α-St-AA)作乳化荆时,引发剂用量为单体质量的1.2%,80℃时可以合成性能良好的苯丙乳液。 相似文献
18.
Jozef P H Linssen Anneloes L G M Janssens Hanneke C E Reitsma Wender L P Bredie Jacques P Roozen 《Journal of the science of food and agriculture》1993,61(4):457-462
Taste recognition threshold concentrations (TRTC) of styrene were determined in samples of oil-in-water emulsions (30–300 g kg?1 oil) and yoghurts (1–30 g kg?1 fat), spiked with styrene. The observed TRTC increased linearly with increasing fat content and ranged from 0–3 to 2–1 mg kg?1 for the emulsions and from 36 to 171 g kg?1 for the yoghurts. Styrene equilibrium partition coefficients between emulsions and their respective vapour phases were determined. The concentrations of styrene in the continuous aqueous phase of the emulsions and yoghurts were calculated at the TRTC. The styrene concentrations in the continuous phase had constant values of about 15 g kg?1 indicating that perception of styrene for oil-in–water emulsions is determined by the aqueous phase of the emulsion. The concentrations of styrene in the vapor phases above the emulsions and yoghurts were also calculated and were found to be constant at the TRTC. This relationship probably resulted from the equilibrium of distribution of styrene between the respective phases. Commercial yoghurt packed in polystyrene beakers contained styrene levels in the range 2–11 g kg?1, much lower then the TRTC reported. 相似文献
19.
Radiation polymerization of acrylonitrile in a viscous system with styrene was performed at ambient temperature by using γ‐rays. It is found that the overall rate of polymerization was accelerated after critical conversion due to the gel effect. As the molar fraction of styrene in monomer feed (fSt) is increased, both the total polymer conversion and molar fraction of acrylonitrile in the copolymer feed (FAN) were decreased. The monomer reactivity ratios for acrylonitrile and styerne were determined to be r1 (AN) = 0.25 and r2 (St) = 2.0, respectively. The copolymers obtained were characterized by Fourier transformed infrared spectra (FTIR), X‐ray diffraction (XRD), scanning electron microscopy (SEM), 1H‐NMR, and pyrolysis mass spectrometry (PMS). It was found that the slight addition of styrene to acrylonitrile strongly changes crystallinity, morphology, and thermal decomposition of the resulting polymer. 1H‐NMR measurment of AN/St copolymer showed the appearance of aromatic proton signals and shifted the resonance of the methylene proton to lower chemical shifts. The mass spectra of AN/St copolymers showed fragments of pyrolysates corresponding to oligonitriles with styrene end groups. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 268–275, 2002; DOI 10.1002/app.10324 相似文献
20.
This research studies the effects of RuO4 exposure on various samples of poly(styrene) (PS). Transmission electron energy-loss spectroscopy (EELS) shows a decrease in the 7 eV π-π∗ transition characteristic of aromatic rings in PS indicating that RuO4 covalently alters aromatic character. Imaging and selected-area electron diffraction show that a layer of RuO2 solid forms on the surface of bulk PS specimens exposed to RuO4. High-resolution TEM imaging (HREM) shows that RuO2 nanocrystals consistently condense on specimen surfaces, independent of the chemical nature of the specimen below. These nanocrystals modulate contrast at length scales on the order of 2-5 nm in TEM images and limit resolution at nanometer length scales. 相似文献