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61.
High‐abrasion furnace black (HAF, grade N330)–filled powdered styrene butadiene rubber [P(SBR/HAF)] was prepared and the particle size distribution, mixing behavior in a laboratory mixer, and mechanical properties of P(SBR/HAF) were studied. A carbon black–rubber latex coagulation method was developed for preparing carbon black–filled free‐flowing, noncontact staining SBR powders, with particle diameter less than 0.9 mm, under the following conditions: carbon black content > 40 phr, emulsifier/carbon black ratio > 0.02, and coating resin content > 2.5 phr. Over the experimental range, the mixing torque τα of P(SBR/HAF) was not as sensitive to carbon black content and mixing temperature as that of HAF‐filled bale SBR (SBR/HAF), whereas the temperature build‐up ΔT showed little dependency on carbon black content. Compared with SBR/HAF, P(SBR/HAF) showed a 20–30% mixing energy reduction with high carbon black content (>30 phr), which confers to powdered SBR good prospects for internal mixing. Carbon black and the rubber matrix formed a macroscopic homogenization in P(SBR/HAF), and the incorporation step is not obvious in the internal mixing processing results in these special mixing behaviors of P(SBR/HAF). A novel mixing model of carbon black–filled powdered rubber, during the mixing process in an internal mixer, was proposed based on the special mixing behaviors. P(SBR/HAF) vulcanizate showed better mechanical properties than those of SBR/HAF, dependent primarily on the absence of free carbon black and a fine dispersion of filler on the rubber matrix attributed to the proper preparation conditions of noncontact staining carbon black–filled powdered SBR. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2494–2508, 2004 相似文献
62.
用动态剪切模量估算NR与SBR硫化胶的化学交联密度 总被引:2,自引:2,他引:2
用美国Monsanto公司的橡胶加工过程分析仪测定NR和SBR硫化胶或混炼胶料的动态剪切模量(G'),进而根据G_N ̄0=g×2X_0RT和Ge=g'×2X_(ph)RT估算其硫化胶的化学交联密度(X_ch),结果发现:NR/过氧化二异丙苯体系硫化胶和混炼胶料的G'是不同的,但用G'估算的X_ch与用化学分析法测定的结果基本相近;对SBR/促进剂TMTD体系,用这种方法估算的X_(ch)接近用应力-应变法和NMR法的估算值;对NR/促进剂TMTM体系,用G'估算的X_(ch)与用溶胀法获得的数据基本接近。用G'估算X_(ch)法,十分简单、方便。 相似文献
63.
Alumina supported vanadia catalysts (V/Al) for selective oxidehydrogenation of ethylbenzene with CO2 were prepared by impregnation method. During preparation the effect of promoters and calcined temperature was investigated,
it was found these two items had a strong influence on the activity of V/Al catalysts. Dehydrogenation reaction with CO2 was happened in the fixed-bed reactor at 450 °C. Results showed that 15.2% ethylbenzene conversion and 99.2% styrene selectivity
were acquired when V2K/Al catalyst was used. 相似文献
64.
以过硫酸铵为引发剂,十二烷基硫酸钠为乳化剂,采用种子聚合工艺,合成了偏氯乙烯质量分数为23%~43%的羧基偏氯乙烯丁苯胶乳。通过电镜观察到所合成的胶乳粒子具有核-壳结构。通过测定胶闰子表面层的羧基数量,研究了羧基的分布,结果表明,羧酸种类对羧基在胶乳粒子中及在聚合体系中的分布有重要影响,该胶乳作为地毯背衬粘合剂,具有粘合力高,极限氧指数高的特点,是一种较好的阻燃性粘合剂。 相似文献
65.
66.
苯乙烯是重要的有机化工原料,在高分子材料生产等方面具有非常广泛的应用价值。本文介绍了乙苯脱氢、乙苯共氧化和甲苯氧化偶联等多种苯乙烯的生产技术方法,同时介绍了苯乙烯的回收技术及其进展。 相似文献
67.
Concentrated inverse emulsion polymerization was used for making chromatography columns (based on crosslinked polystyrene divinylbenzene (PS‐DVB)) with pore sizes less than 10 μm. According to DSC‐thermal gravimetry thermograms, it was confirmed that the residual monomer concentration after polymerization process is negligible. For application of these columns in chiral chromatography, the β‐cyclodextrin is chemically fixed on the PS‐DVB resin pore surface. The presence of hydroxyl groups in the PS‐DVB resin after chemical modification was confirmed by FTIR spectroscopy. By chemical modification of the PS‐DVB resin, thermal stability increased up to 446°C. The structure of columns was analyzed by scanning electron microscopy (SEM). SEM evaluations showed that the porous structure of PS‐DVB resin was maintained intact after the chemical modification with β‐cyclodextrin. According to X‐ray data, presence of the crystalline domain that is related to β‐cyclodextrin is confirmed.© 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 857–863, 2006 相似文献
68.
固相接枝共聚法制备PP—g—PS 总被引:4,自引:0,他引:4
用固相接枝共聚方法制备了聚丙烯接枝苯乙烯(PP-g-PS),详细地考察了聚丙烯与引发剂的品种、反应温度、苯乙烯及引发剂的浓度等因素对接枝率和接枝效率的影响。研究结果表明:PP-g-PS具有较高的接技率,应用于聚丙烯/聚苯乙烯(PP/PS)共混物中,能降低分散相PS的粒径,提高PP/PS的相容性。 相似文献
69.
70.
POE-g-MAH及其在增韧尼龙6中的应用 总被引:1,自引:0,他引:1
利用熔融接枝法制备了马来酸酐接枝乙烯-辛烯共聚物(POE-g—MAH),探讨了各个因素对POE-g—MAH接枝率和熔体流动速率(MFR)的影响,并得出了最佳配方、最佳工艺条件。将POE与接枝产物POE-g—MAH同时作为弹性体改性PA6时,体系的缺口冲击强度较纯尼龙提高近9倍,而其他力学性能改变不大。 相似文献